Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Bromargyrite is a mineral of

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Pb
Sn
`I_2`
`AGBR`

ANSWER :D
2.

Broadly speaking there are four types of stereisomers namely conformational isomers geometrical isomers, enantiomers and diastereomers.Although conformational isomers , have same configuration geometrical isomers have different atoms attached to each of the doubly bonded carbon atom, and enantiomers are due to chirality in the molecule Enantiomers are also known as optical isomers and diastereomers are those stereoisomers which are not enantiomers.In simple compound, number of stereoisomers.In chiral molecule is given by the reaction 2^n, where n is the number of dissimilar chiral carbon. Observe the following structures and answer the questions given below : The correct names for the above structure is :

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(2S, 3E)-3-penten-2-ol
(2R, 3E)-3-penten-2-ol
(2R, 3Z)-3-penten-2-ol
(2S, 3E)-3-penten-2-ol

Solution :In naming of the above compound, follow the rules for priority ORDER (E,Z) and (R,S) SYSTEM.
3.

Briquettes used in modern vertical retort process are made up of _________.

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`ZnSO_(4) (40%) ` + CLAY (60%)
`ZnO (40%) +` coke/charcoal (60%)
ZNS (40%) + coke/charcoal (60%)
ZnS (40%) + clay (60%)

Answer :B
4.

Bring out the following conversions: a. Toluene to Benzaldehyde b. Acetylene to acetaldehyde c. Formaldehyde to Methyl alcohol d. Propanoic acid to Acetic acid.

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Solution :The conversions are CARRIED out as under:

B. `underset("Acetylene")(HC-=CH)+H_(2)Ounderset(HgSO_(4))overset(H_(2)SO_(4))(to)CH_(3)-underset("Acetaldehyde")overset(O)overset(||)(C)-H`
c. `underset("Formaldehyde")(HCHO)overset(LiAlH_(4))(to)underset("Methyl alcohol")(CH_(3)OH)`
5.

Bring out the following conversion: a. Acetyl chloride to Acetaldehyde b. Ethanol to Acetaldehyde c. Acetic acid to Acetaldehyde d. 2-Butanol to 2-Butanone.

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Solution :The conversions are achieved as under:
a. `UNDERSET("Acetyl chloride")(CH_(3)COCl)+H_(2)underset("Xylene")overset(Pd-BaSO_(4))(to)underset(.Acetaldehyde")(CH_(3)CHO)+HCl`
B. `underset("ETHANOL")(CH_(3)CH_(2)OH)underset(573K)overset(Cu)(to)CH_(3)-underset("Acetaldehyde")overset(O)overset(||)(C)-H+H_(2)`
c. `underset("Acetic ACID")(CH_(3)COOH)overset(LiAlH_(4))(to)underset("Ethanol")(CH_(3)CH_(2)OH)underset(573K)overset(Cu)(to)CH_(3)-underset("Acetaldehyde")overset(O)overset(||)(C)-H`
d. `CH_(3)-underset(2-"Butanol")overset(OH)overset(|)(CH)-CH_(2)-CH_(3)underset(573K)overset(Cu)(to)CH_(3)-underset(2-"Butanone")overset(O)overset(|)(C)-CH_(2)-CH_(3)+H_(2)`
6.

Bring about the following conversions : Nitrobenzene to benzoic acid

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SOLUTION :
7.

Bring about the following conversions : Benzyl chloride to 2-phenyl ethanamine

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SOLUTION :
8.

Brine solutionon electrolysiswill give

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`NAOH `
`O_ 2 `
`Cl_ 2 `
`H_ 2`

SOLUTION :NaOH,` Cl_ 2AND H _2`.Only` O_ 2`is notobtained.
9.

Brine is electrolysed by using inert electroldes. The reaction at anode is

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`Cl^(-)(AQ) to 1//2 Cl_(2)(g) +e^(-), E_("Cell")^(@) =1.36 V`
`2H_(2)O(aq) to O_(2)(g)+4H^(+)(aq)+4e^(-), E_("Cell")^(@)=1.23 V`
`NA^(+)(aq)+e^(-)to Na(s), E_("Cell")^(@)=2.71 V`
`H^(+)(aq.) +e^(-) to 1//2 H_(2)(g), E_("Cell")^(@)=0.00 V`

SOLUTION :It is the correct ANSWER.
10.

Brine is electrolysed by using inert electrodes. The reaction at anode is ........

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`Cl_((aq))^(-) to 1/2 Cl_(2(g)) - e^(-) , E_(("CELL"))^(Theta) = 1.36 V`
`2H_2O_((l)) to O_(2(g)) + 4H_((aq))^(+) + 4e^(-) , E_(("cell")^(Theta) = 1.23 V`
`Na_((aq))^(+) + e^(-) to Na_((s)) , E_(("cell")"^(Theta) = 2.71 V`
`H_((aq))^(+) + e^(-) to 1/2 H_(2(g)) , E_("(cell)")^(Theta) = 0.00V`

Solution :During ELECTROLYSIS of brine, the oxidation of OXYGEN and chlorine both are possible at ANODE. However, the oxidation of oxygen requires over voltage and so chloride ions are prefrentially oxidised at anode to `Cl_2`.
11.

Brine is electrolysed by using inert electrodes. The reaction at anode is…………….

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`Cl^(-) (a) to (1)/(2) Cl_(2)(g) +e^(-), ""E_("cell")^(0) = 1.36V`
`2H_(2)O(l) to O_(2)(g)+4H^(+)+4E^(-),""E_("cell")^(0) = 1.23V`
`Na^(+) (aq) +e^(-) to Na (s), ""E_("cell")^(0) = 2.71V`
`H^(+)(aq) + e^(-) to (1)/(2)H_(2) (g), ""E_("cell")^(0) = 0.00V`

Answer :A
12.

Brineiselectrolysedby usinginertelectrodes.The reaction atanodeis ........

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` C l^(-)(aq)to(1)/(2) Cl_ 2(g)+e ^(- ) ,E^(@ )""_("Cell") =1.36 V`
`2 H_2 O (l)toO_2 (g) +4H^(+) +4E^(- ) , E^(@)""_("Cell") =1.23 V `
` Na ^( +) (aq)+e ^( -) toNa (s) , E ^(@)""_("cell") =2.71V`
` H ^(+ ) (aq)+e ^(- ) to(1)/(2) H_ 2 O(g), E^(@)""_("cell") = 0.00 V`

SOLUTION :Althoughoxidationpotentialof` Cl ^(-)` ionsis higherthanthatof` H_ 2 O `, YET oxidationof ` Cl ^- `ionsoccursinpreferenceto` H_ 2O `sincedue toovervoltageof` O_ 2` (i.e.,waterneedsgreatervoltagefor oxidation to ` O_2 `asitisakineticallyslowprocess) muchhigher potentialthan`1* 36 `V isactuallyneededfor the oxidationof`Cl^(-) `ionsto` Cl_ 2`.
13.

Brine is electrolysed by using inert electrodes. The reaction at anode is _____.

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`Cl^(-)(aq) to (1)/(2) Cl_(2)(G) +E^(-), "" E_("CELL")^(@)=1.36V`
`2H_(2)O(l) to O_(2)(g)+4H^(+)+4e^(-), "" E_("Cell")^(@)=1.23 V`
`NA^(+)(aq)+e^(-)to Na(s), "" E_("Cell")^(@)=2.71V`
`H^(+)(aq)+e^(-) to (1)/(2)H_(2)(g), "" E_("Cell")^(@)=0.00V`

Answer :A
14.

Brine helps in food perservation by

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KILLING the germs
destroying the ENZYME action
sealing the FOOD with layer of salt and pervent the direct contact
reducing the avaible water for the GROWTH of microbes

Answer :D
15.

Brine is chemically:

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CONC. SOLUTION of `Na_2CO_3`
Conc. Solution of `Na_2SO_4`
Conc. Solution of NaCl
Conc. Solution of ALUM

ANSWER :C
16.

Briefly explain why electronic configuration of lanthanoids are not known with certainty ?

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Solution :`4f 5d ` subshells are very CLOSE in ENERGY. +ve ELECTRONS can JUMP from 4f to 5d or vice-versa.
17.

Briefly explain why electronic configuration of lanthanoids are not known with certainty.

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Solution :In the lanhanoids, 4f and 5d subshells are very close in energy. The OUTERMOST 6s orbital remains filled with 2 electrons `( 6s^(2))`. The electron can easily JUMP from 4f to 5d or vice-versa. Further, irregularities in ELECTRONIC CONFIGURATION are also RELATED to the stabilities of `f^(0), f^(7)` and `f^(14)` occupacy of f-orbitals. Hence, their electronc configuration are not known with certainity.
18.

Briefly explain why the following reaction does not occur

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Solution :By itself, `(CH_(3))_(3)CO^(-)`is not a good enough LEAVING group to allow iodide to ATTACK the methyl carbon in an `S_(N)2`fashion. PROTONATION of the oxygen converts the leaving group to methanol `(CH_(3)OH)`, which is good enough to leave when iodide attacks.
19.

Briefly explain the effects of temperature on the solubility of solids in liquids.

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SOLUTION :If the PROCESS of dissolution is exothermic, the SOLUBILITY decreases with the increase in TEMPERATURE.
(ii) If the process of dissolution is endothermic, the solubility INCREASES with the increase in temperature.
20.

Briefly explain the acidic nature of phenols.

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Solution :The acidic nature of phenols can be explained on the BASIS of resonance.

Due to resonance in phenol the `O-` atom of `-O-H` group acquires slight `+ve` charge and `H-` atom is RELEASED as proton. ALSO phenoxide ion is more stabilised due to resonance.
`therefore"The equilibrium (1) will shift towards R.H.S. giving more of "H^(+)" ions."`
21.

What is the name of the method that is used in manufacturing of sodium hydroxide? Explain the method.Write the equations of the reactions involved in this process

Answer»


ANSWER :REFER THEORY SECTION 6.7 (E)
22.

Briefly discuss Schottky defects and give examples.

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SOLUTION :When imperfections or defects in a crystal are caused by a DEPARTURE from the periodic ARRANGEMENT in the VICINITY of an atom or a group of atoms, the imperfections are called point defects. The imperfections are caused either by missing or dislocations of a. constitutent particle to a position meant for ANOTHER particle or shifting to an interstitial position. Point defects are of two common types :
1. Schottky defects 2. Frenkel defects.
1. Schottky defects. This defect arises if some of the atoms or ions are missing from their normal lattice sites. The lattice sites which are unoccupied are called latrice vacancies or holes. Since the crystal is to remain electrically neutral, equal number of cations and anions are missing. The ideal AB crystal is shown in Fig. The existence of two holes, one due to a missing cation and the other due to a missing anion, is shown in Fig. Schottky defect is more common in strongly ionic compounds having a high coordination number.

For example, NaCl and CsCl ionic solids have Schottky defects. Because of the presence of vacancies in crystals, its density is markedly lowered.
2. Frenkel defects. This defect arises when an ion is missing from its own position and occupies an interstitial site. The existence of one hole due to a missing cation its proper position and occupying an interstitial position is shown in Fig. In this case also, the crystal remains electrically neutral. Frenkel defects generally occur in

compounds in which anions are much larger than the cations and the co-ordination number is low. These defects can be found in silver halides because of the small size in the `Ag^(+)` ion.
23.

BrF_(5) undergoes hydrolysis then the products formed are

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`HBrO_(2),HF`
`HOBr,HF`
`HBrO_(3),HF`
`HBrO_(4),HF`

ANSWER :C
24.

BrF_3 is a liquid which considerably undergoes self ionization to form cationic and anionic species.Based on VSEPR theory, number of 90 degree F-Br-F bond angles is ……. In anionic species. 2BrF_3 hArr [BrF_2]^++ [BrF_4]^(-)

Answer»


SOLUTION :
25.

Brewery and sugar factory waste alter the quality of a water body by increasing

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pH
Temperature
Turbidity
COD and BOD

Answer :D
26.

Breding arc method cannot be used to prepare colloidal solutionof which of the following ?

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`Pt`
`Fe`
`Ag`
`Au`

Solution :Electrical disintegration of Bredigs are METHOD is used for preparing colloidal solution of metal like gold silver, platinum. Etc. In this method electric arc is struck between electrodes of metal immersed in the dispersion medium. The intense heat produced vaporizes some of the METALS which then condenses to form particles of colloidal size. As iron do not vaporise easily, it cannot be prepared by this method. A colloidal solution of `Au,Ag` and `Pt` can also be prepared by reducing its SALT solution with suitable reducing agent.
`2AuCl_(3)+3SnCl_(2)rarrunderset("Gold sol")(2Au+3SnCl_(4))`
27.

Bredig's arcmethod cannot be used for the preparation of colloidal sol of :

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Cu
Mg
Ag
Na

Answer :B::D
28.

Bredig's arc method involves

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Only DISPERSION of metal
Only CONDENSATION of metal
Dispersion as WELL as condensation
Neither dispersion nor condensation

Answer :C
29.

Bredig's arc method cannot be used to prepare colloidal solution of

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Pt
Fe
Ag
Au

Solution : Bredig.s arc method cannot be used because at HIGH TEMPERATURE, IRON REACTS with water which is in the FORM of steam.
30.

Brass is mixture of …… metals.

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Zn, NI
Cu, SN
Cu, Zn
Cu, Zn, Ni

ANSWER :C
31.

Brass is an example of a the defect

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SCHOTTKY DEFECT
Frenkel defect
Interstitial defect
SUBSTITUTION impurity defect

Solution :It is an ALLOY of copper and ZINC metal
32.

Brass is an alloy of ul"copper and tin"

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SOLUTION :COPPER and ZINC
33.

Brass is an alloy of ___________ and ___________.

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ZN and Cu
Cu and Sn
Sn and Zn
Cu, Zn and Sn

Answer :A
34.

Brass is an alloy of :

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ZN and Cu
Cu and SN
Zn and Sn
Cu, Zn and Sn

ANSWER :A
35.

Brass is a mixture of

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CU and SN
Cu and ZN
Sn and Zn
Cu and carbon

Answer :B
36.

Brass is :

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A COMPOUND
An amalgam
An ELEMENT
An ALLOY

ANSWER :D
37.

Brass contains which metals?

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SOLUTION :COPPER and ZINC
38.

Brass contains

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(Cu+Sn)
(Cu+Ni)
(Cu+Zn)
(Mg+AL)

ANSWER :C
39.

Brass contains ___________.

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SOLUTION :`90%` CU and` 10% ZN`
40.

Brandy is distilled form fermented fruits, rum is distilled form molasses, Bourbon whisky form corn, rye whisky form rye, sotch whisky form barley, Irish whisky form potatoes, Saki form rice, and beer form….

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Malt
Yeast
Grapes
Apples

Solution :NA
41.

Bragg's law is given by the equation:

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`nlambda = 2 SIN theta`
`nlambda = 2d sin theta`
`2d = nlambda sin theta`
`nlambda = d sin theta`

ANSWER :B
42.

The PH of a solution is defined by the equation:

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`nlambda=2sintheta`
`nlambda =2dsintheta`
`2d=nlambdasintheta`
`nlambda=dsintheta`

ANSWER :B
43.

Bragg's equation is:

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`nlambda=2thetasintheta`
`nlambda=2dsintheta`
`2nlambda=dsintheta`
`LAMBDA=(2d/n)SINTHETA`

ANSWER :B
44.

Bragg’s equation has no solution if:

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`nlambda=2d`
`nlambdagt2d`
`nlambdalt2d`
All

Answer :B
45.

Bragg’s equation is- (A) ngamma=20sin theta(B) ngamma=2d sin theta 2ngamma=d sin theta(D)gamma=(2d//n) sin theta

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Solution :(B) BRAGG’s EQUATION is `ngamma` = `2d SIN THETA`.
46.

Br_(2)(l) reacts with Cl_(2) (g) to form BrCl_(3) ,simultaneously .How many moles of Cl_(2)(g) reacts completely with 3 moles of Br_(2)(l) to form BrCl and BrCl_(3) in 5 :1 molar ratio .

Answer»


ANSWER :4
47.

Br_(2) water in NaOH soin .Oxidises Mn(OH)_(2) to a…. Ppt due to theformationof MnO(OH)_(2)

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BLACK
violet
Blue
white

Answer :a
48.

Br_2+NaOHrarrNaBrO_3+H_2O In the above balanced chemical equation, number of moles of Br_2 reduced to bromide is

Answer»

1.5
2.5
3
5

Answer :B
49.

Br_(2) reacts with O_(2) in either of the following ways depending upon supply of O_(2) Br_(2) + (1)/(2) O_(2) rarr Br_(2) O Br_(2) + (3)/(2) O_(2) rarr Br_(2) O_(3) If 4 moles of Br_(2) and 10 moles of O_(2) are taken in a container then calculate the number of moles of reactant left complete reaction.

Answer»

<BR>

Solution :`{:(Br_(2),+,(3)/(2)O_(2),RARR,Br_(2)O_(3),),("Moles",4,,(3)/(2) xx 4,,),(,,,= 6 "moles",,):}`
Moles of REACTANT `(O_(2))` left = 4 moles
50.

Br_(2)+H_(2)O rarr Br^(-) + BrO_(3) In the above reaction, following takes place a

Answer»

Bromine UNDERGOES OXIDATION & REDUCTION
Bromine is oxidised only
Bromine is REDUCED only
None

Answer :A