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Bring out the following conversion: a. Acetyl chloride to Acetaldehyde b. Ethanol to Acetaldehyde c. Acetic acid to Acetaldehyde d. 2-Butanol to 2-Butanone. |
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Answer» Solution :The conversions are achieved as under: a. `UNDERSET("Acetyl chloride")(CH_(3)COCl)+H_(2)underset("Xylene")overset(Pd-BaSO_(4))(to)underset(.Acetaldehyde")(CH_(3)CHO)+HCl` B. `underset("ETHANOL")(CH_(3)CH_(2)OH)underset(573K)overset(Cu)(to)CH_(3)-underset("Acetaldehyde")overset(O)overset(||)(C)-H+H_(2)` c. `underset("Acetic ACID")(CH_(3)COOH)overset(LiAlH_(4))(to)underset("Ethanol")(CH_(3)CH_(2)OH)underset(573K)overset(Cu)(to)CH_(3)-underset("Acetaldehyde")overset(O)overset(||)(C)-H` d. `CH_(3)-underset(2-"Butanol")overset(OH)overset(|)(CH)-CH_(2)-CH_(3)underset(573K)overset(Cu)(to)CH_(3)-underset(2-"Butanone")overset(O)overset(|)(C)-CH_(2)-CH_(3)+H_(2)` |
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