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What is the relation between Gibbs free energy and the EMF of the cell?(a) ΔG = -nFEcell(b) G = -nFEcell(c) ΔG = -nEcell(d) ΔG = -nFcellI had been asked this question in an international level competition.Query is from Gibbs Energy Change and Equilibrium in chapter Thermodynamics of Chemistry – Class 11

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Correct ANSWER is (a) ΔG = -nFEcell

Easy explanation: The RELATION between Gibbs free ENERGY and EMF of the cell is ΔG = -nFEcell, where G is the caps free energy and as a number of electrons lost or gained while f depicts Faraday and E cell STAND for standard electrode POTENTIAL.



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