This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
At equilibrium the rate of dissolution of a solution solute in a volatile liquid solvent is …… |
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Answer» Less than the RATE of crystallisation |
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| 3. |
At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is |
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Answer» less than the rate of CRYSTALLISATION The solution is saturated. In the solution, the rate of DISSOLUTION is equl to RATIO of crystallisation. |
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| 4. |
At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ………….. |
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Answer» LESS than the RATE of CRYSTALLISATION |
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| 5. |
At equilibrium the free energy change (Delta G) is : |
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Answer» `Delta G = 0` |
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| 6. |
At equiliberium , the amount of HI in a 3 litre vessel was 12.8 g. Its equiliberium concentraction is : |
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Answer» 4.267 M |
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| 7. |
At elevated temperatures, S_2 is the dominant species and is _________like O_2 |
| Answer» SOLUTION :PARAMAGNETIC | |
| 8. |
At elevated temperature, HI decomposes according to the chemical equations: 2HI(g) to H_(2)(g) + I_(2)(g) a)Determine (i) the order of reaction and (iii) Write the rate expression. b) Calculate the rate constant and give its units. |
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Answer» rate = `(30 xx 10^(-4))/(7.5 xx 10^(-4)) =4` When (HI) is increased from 0.01 to 0.02 (made twice), rate `= (12 xx 10^(-3))/(3 xx 10^(-3)) =4` a) `therefore` ORDER of reaction=2 Rate expression, (r)=`k[HI]^(2)` b) Calculation of rate constant: For EXPT. (1), `k(0.005 mol L^(-1))^(2)=(7.5 xx 10^(-4)mol^(-1)s^(-1)` `k=(7.5 xx 10^(-4) mol L^(-1)s^(-1))/(2.5 xx 10^(-5)mol^(2)L^(-2))=30 mol^(-1)Ls^(-1)`. |
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| 9. |
At different condition nitration of phenol gives |
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Answer» o-nitrophenol |
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| 10. |
At CMC, the surfactant molecules : |
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Answer» Dissociate |
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| 11. |
At critical micelle concentration (CMC) |
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Answer» the ions of surfactant molecules UNDERGO ASSOCIATION to FORM clusters |
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| 12. |
At constant volume, for a fixed number of moles of a gas, the pressure of the gas increases with rise of temperature due to: |
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Answer» INCREASE in AVERAGE molecular speed |
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| 13. |
At constant volume, for a fixed number of moles of a gas the pressure of the gas increases with rise of temperature due to |
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Answer» 1. INCREASE in average molecular speed |
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| 14. |
At constant volume at 27^(@) C, 2C_(6)H_(6)(g)+150_(2)(g) to 12CO_(2)(g)+6H_(2)O(l), Delta u=-1600 kcal 2C_(2)H_(2)(g)+5O_(2)(g) to 4CO_(2)(g)+2H_(2)O (l), Deltau=-620 kcal Calculate the heat of polymerisation of acetylene to benzene at constant pressure. |
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Answer» |
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| 15. |
At constant teperature, the equlimbeijm constnt (K_(p)) for the decomposition reaction N_(2)O_(4)hArr2NO_(2) is expressed by K_(p)=(4x^(2)P)(1-x^(2)), where P = pressure, x= ectent of decomposition. Which one of the following statements is true |
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Answer» `K_(p)` increases with increase of P |
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| 16. |
At constant volume and temperature conditions the rates of diffusion D_(A) and D_(B) of gases A and B having densities rho_(A) and rho_(B) are related by the expression |
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Answer» `D_(A)=[D_(B).(rho_(A))/(rho_(B))]^(1//2)` |
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| 17. |
At constant volume , for a fixed number of mole of a gas , the pressure of the gas increase with rise of temperature due to : |
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Answer» INCREASE in AVERAGE molecular speed |
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| 18. |
At constant temperture and pressure which one of the following statements is correct for the reaction ? CO(g)+ 1/2O_(2)(g) to CO_(2)(g) |
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Answer» `DeltaH = DELTAE` for the reaction , `CO(G)+1/2O_(2)(g) to CO_(2)(g)` ` Deltan=1-(1+1/2) =-1/2` `DeltaH=DeltaE-1/2 RT` `DeltaH lt DeltaE` |
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| 19. |
At constant temperature, the pressure of V mL of a dry gas was increased from 1 atm to 3 atm. The new volume will be : |
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Answer» Solution :`p_(1) = 1 atm,p_(2)` = 3 atm, `V_(1) `= V ml, `V_(2) = ?` `p_(1) V_(1) = p_(2) V_(2)` ( at constant temperature ) `1 XX V = 3 xx V_(2)` or `V_(2) = V//3` |
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| 20. |
At constant temperature, the equilibrium constant (K_(p)) for the decomposition reaction, N_(2)O_(4)iff2NO is expressed by K_(p)=((4x^(2)P))/((1-x^(2))), where P = pressure, x = extent of decomposition. Which one of the following statements is true? |
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Answer» `K_(p)` increases with increase of P |
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| 21. |
At constant temperature, the equilibrium constant (K_(p)) for the decomopsition reaction N_(2)O_(4)hArr2NO_(2) is expressed byK_(p) = ((4x^(2)P))/((1-x^(2)), where P = pressure, x = extent of decomposition. Which one of the following statement is true ? |
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Answer» <P>`K_p` remains constant with change in P |
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| 22. |
At constant temperature, the equilibrium constant (K_p)for the decomposition reaction, N_2O_4 hArr 2NO_2 is expressed by K_p=4x^2P//(1-x^2) , where P = pressure and x = extent of decomposition. Which of the following statements is true? |
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Answer» `K_p`increases with increase in P. |
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| 23. |
At constant temperature ,osmotic pressure of an aqueous solution of 1.5 M NH_(4)NO_(3) and x N Al_(2)(SO_(4))_(3) are equal, thenmention the value of X. ( Assume that ionic solid substances completely dissociates in the solution . ) |
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Answer» Solution :`n_(1)M_(1) = n_(2)M_(2)` For`NH_(4)NO_(3)`VALUES of `n_(1)` and `M_(1)` are 2 and 1.5respectively For `Al_(2)(SO_(4))_(2)n_(2) = 5 ` `:. M_(2) =( 2)/(5) xx 1.5 = 0.6 ` Normality of `Al_(2)(SO_(4))_(3)= 6 xx ` molarity `= 6 xx 0.6 = 3.6 N ` |
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| 24. |
AT constant temperature, the equilibrium constant (K_p) for the decomposition reaction N_2O_4 hArr 2NO_2 is expressed by K_p=(4x^2P)//(1-x^2), where P= pressure ,x = extent of decomposition . Which one of the following statements is true ? |
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Answer» `K_p` INCREASES with increases of P |
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| 25. |
At constant temperature in one litre vessel when the reaction 2SO_2 (g) ⇌ 2SO_2 (g) + O_2 (g) is at equiliberium the SO_2 concentration is 6.0 M, initial concentration of SO_3 is 1 M. calculate the equiliberium constant. |
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Answer» 2.7 |
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| 26. |
At constant temperaturein a litre vessel , when the reaction 2SO_(3)(g) iff 2SO_(2)(g) + O_(2)(g)the SO_(2) concentration is 0.6M , initial concentration ofSO_(3) is 1M . The equilibrium constant is |
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Answer» 1.36 |
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| 27. |
At constant temperature and volume, X decomposes as 2" X "(g) to 3" Y "(g)+2" Z "(g). P_(x) is the partial pressure of X. {:("Observation No.",,,"Time (in minutes)",,,P_(x)("in mm of Hg")),(1,,,0,,,800),(2,,,100,,,400),(3,,,200,,,200):} (i)What is the order of reaction with respect with respect of X ? (ii) Find the time for 75% completion of the reaction. (iii) Find the total pressure when pressure of X is 700 mm of Hg. |
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Answer» Solution :(i) As pressure of X is changing with time, it cannot be a zero order REACTION. LET us now check it for 1st order. `{:("At",,,t=100" min,",,,k=(2.303)/(100)log""(P_(0))/(P_(t))=(2.303)/(100)log""(800)/(400)=6.932xx10^(-3)"min"^(-1)),("At",,,t=200" min,",,,k=(2.303)/(200)log""(800)/(200)=(2.303)/(800)log4=6.932xx10^(-3)"min"^(-1)):}` As k comes out to be constant, hence it is a reaction of 1st order. (II) `t_(75%)=(2.303)/(k)log""(100)/(100-75)=(2.303)/(6.932xx10^(-3)"min"^(-1))log4=200" min".` (iii) `2X(g) to 3" Y"(g)+2" Z"(g)` `{:("Initial Pressure",,,800" mm",,,0,,,0),("Pressure after time t",,,800-2" p",,,3" p",,,2" p"):}` When pressure of X is 700 mm, `800-2" p"=700" or "p=50" mm"` Total pressure `=(800-2" p")+3" p"+2" p"=800+3" p"=800+3xx50=950" mm"` |
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| 28. |
At constant temperature , if pressure increases by 1% , the percentage decrease of volume is : |
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Answer» `1%` INCREASE in PRESSURE `= 100 XX ( 1)/( 100) = 1 ` `p_(2) = 100 +1 = 101 mm Hg ` `V_(1) = V` and `V_(2) = ?` `p_(1) V_(1) = p _(2) V_(2)` or `V_(2) = ( p_(1) V_(1))/(p_(2)) = ( 100 xx V )/( 101) = ( 100)/( 101) V ` Decrease in volume`= ( V - ( 100)/( 101) V )/( V )` ` = V ( 1 - (100)/( 101))/( V ) = ( 1)/( 101)%` |
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| 29. |
At constant temperature , in a given mass of an ideal gas |
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Answer» The RATIO of pressure and volume ALWAYS remains constant `V = ("Constant")/(P) , VP =` Constant |
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| 30. |
At constant temperature and pressure, correct order of entropy of gases for their equal moles is |
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Answer» `He gt NE gt Ar gt Kr gt XE` |
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| 31. |
At constant temperature and 1 atm pressure, PCl5 dissociate 2% then at what pressure PCl5 dissociate4% :- (Use PCl_(5)(g) hArrPCl_(3)(g) + Cl_(2)(g)) |
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Answer» `1/8 ` atm `KP=( alpha^(2))/((1-alpha ))xx[(p)/((1+alpha))]^(1)` `KP= (alpha^(2) P)/(1-alpha ^(2)) ~~- alpha ^(2)P ` ` alpha_(1) ^(2)P_(1)= alpha _(2) ^(2)P_(2) ` `( 0.02 ) xx 1 = ( 0.04 ) ^(2).Pa` `impliesP2= 0.25atm ` `=(1)/(4) atm` |
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| 32. |
At constant temperature and pressure, which of the following statement is true for the reaction.CO[g]+1/2O_2[g]-rarrCO_2[g] |
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Answer» `/_\H=/_\E` |
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| 33. |
At constant temp. the osmotic pressure (pi) and the molarity (M) of the solution are related as |
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Answer» `PI prop M` `pi=CRT, C=Molarity` |
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| 34. |
At constant T and P, which one of the following statements is correct for the reaction, CO(g) +(1)/(2)O_(2)(g) rarrCO_(2)(g) |
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Answer» `DeltaH` is independent of the PHYSICAL state of the reactants of that compound |
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| 35. |
At constant pressure, the heat of formation of a compound is not dependent on temperature, when |
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Answer» `DELTA C_P = 0` `Delta H_2 = Delta H_1+ Delta C_P (Delta T)` when `Delta C_P = 0` then `Delta H` does not DEPEND on temperature . |
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| 36. |
At constant T and P which one of the following statements is correct for the reaction : CO(g) + (1)/(2) O_(2)(g) rarr CO_(2)(g) |
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Answer» `Delta H = Delta U` |
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| 37. |
At constant P and T which statement is correct for the reaction, CO(g)+1//2O_2(g)rarrCO_2(g): |
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Answer» `triangleH=triangleU` |
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| 38. |
At constant P and T which of the following statement is correct for, C (s) + O_(2)(g) rarr CO_(2) (g) |
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Answer» `DELTAH = DeltaE` |
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| 39. |
At CMC the surfactant molecules |
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Answer» DECOMPOSES |
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| 40. |
At CMC, the surfactant moleculesdecompose,become completely soluble,associate,dissociate. |
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Answer» decompose |
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| 41. |
At CMC the surfact molecules: |
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Answer» decompose |
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| 42. |
At CMC, surfactant molecules |
| Answer» Answer :C | |
| 43. |
At CMC (Critical Micellisation Conc.) the surface molecules |
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Answer» Associate |
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| 44. |
At certain temperature, vapour pressure of pure element A and B has 108 and 36 torr respectively. If solution has equal mole of A and B elements, then vapour pressure of solution is ……. |
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Answer» 144 torr |
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| 45. |
At certain temperature, the r.m.s. velocity for CH_4gas molecules is 100 m/sec. This velocity for SO_2 gas molecules at same temperature will be |
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Answer» 400 m/sec |
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| 46. |
At certain temperature, the solution of benzene in toulene exihibits the vapour pressure (in m bar) representes as P= 150x + 65, where 'x' is mole fraction of benzene, the vepour pressure of pure benzene is |
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Answer» 150 m BAR |
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| 47. |
At certain temperature a solution of 3mol of a liquid A(P^(0)=500 torr) and 1 mol of liquide B(P^(0)=340 torr) has a vapour pressure of 435 torr , we can conclude that |
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Answer» a solution of 5 mL of A and 50 mL of B must have a volume of 100 mL . |
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| 48. |
At certain temperature and infinite dilution , the equivalent conductances of sodium benzoate , hydrochloric acid , and sodium chloride are 240, 349 and 229 Omega^(-1) cm^(2) eq^(-1) respectively . The equivalent conductance of benzoic acid in Omega^(-1) cm^(2) eq^(-1) at the same condition is |
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Answer» 80 `Lambda_(C_(6)H_(5) COOH)^(@) = 240 + 349 - 229` `Lambda_(C_(6)H_(5) COOH)^(@)= 240 + 349 - 229` `Lambda_(C_(6)H_(5)COOH)^(@) = 360 Omega^(-1) CM^(2) eq^(-1)` |
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| 49. |
At certain temperature 1.6% solution of an unknown substance is isotonic with 2.4 % solution of Urea. If both the solutions have the same solvent and both the solutions have same density 1 gm/cm^(3), what will be the molecular mass of unknown substance in gm/mol. [Mole mass of urea = 60 gm/mol] |
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Answer» 40 `((% w//V)/(M))_("UREA")=((%w//V)/(M))_("unknown")` `(2.4)/(60)=(1.6)/(M)` `THEREFORE M=(1.6xx60)/(2.4)=40` gram/mole |
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| 50. |
At cathode, the electrolysis of aqueous Na_(3)SO_(4) gives |
| Answer» Solution :Calomel electrode USED asa reference electrdrodeuses `Hg_(2)Cl_(2)`. | |