This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 5001. |
Statement-1 : Molality of pure ethanol is lesser than pure water Statement-2 : As density of ethanol is lesser than density of water [Given : `d_("ethanol") = 0.789 gm//ml, d_("water") = 1gm//ml`]A. Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.B. Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.C. Statement-1 is false, statemetn-2 is trueD. Statement-1 is true, statement-2 is false. |
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Answer» Molarity of pure ethanol `(1)/((46)/(1000))=(1000)/(46)` Molarity of pure water `(1)/((18)/(1000))=(1000)/(18)` `m_(C_(2)H_(5)OH)ltm_(H_(2)O)` density is not used to calculate molarity. |
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| 5002. |
Define the wronskain |
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Answer» A mathematical determinant whose first row consists of n functions of x and whose following rows consist of the successive derivatives of these same functions with respect to x. |
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| 5003. |
What is the decimal value for the binary number 1001.0010?1. 1252. 12.53. 90.1254. 9.125 |
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Answer» Correct Answer - Option 4 : 9.125 Concept : The binary number system with only two independent digits, 0 and 1, is a base-2 number system. All larger binary numbers are represented in terms of ‘0’ and ‘1’. The decimal number is equal to the sum of binary digits (Dn) times their power of 2 (2n) Decimal = --- + D2 × 22 + D1 × 21 + D0 × 20 In order to convert the binary fractions to decimal numbers, we use negative power of 2 to the right of the binary point. = D-1 2-1 + D-2 2-2 + --- Calculation: Given binary number is: 1001.0010 The decimal equivalent of the integer part will be: (Decimal)Integer = (1) × 23 + (0) × 22 + (0) × 21 + (1) × 20 = 8 + 1 = 9 The fractional part will be: (Decimal)Fractional = (0) × 2-1 + (0) × 2-2 + (1) × 2-3 + (0) × 2-4 = 2-3 = 0.125 ∴ The resultant decimal equivalent is: (1001.0010)2 = (9.125)10 |
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| 5004. |
The ratio of the monthly income of Radhey and Ranu is 12 ∶ 9 and that their expenditure is 11 ∶ 7 if each of them saves Rs. 18,000 per month, then find the sum of monthly incomes of Radhey and Ranu? (in Rs.)1. Rs. 1,00,8002. Rs. 1,26,0003. Rs. 1,25,0004. Rs. 1,29,000 |
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Answer» Correct Answer - Option 1 : Rs. 1,00,800 Given: The ratio of the monthly income of Radhey and Ranu = 12 ∶ 9 The ratio of their expenditure = 11 ∶ 7 Saving of each of them = Rs. 18,000 Formula used Income = Expenditure + Saving Calculations: Let the income of Radhey and Ranu be 12x and 9x Expenditure of Radhey = 12x – 18000 Expenditure of Ranu = 9x – 18000 According to the question, ⇒ (12x – 18000)/(9x – 18000) = 11/7 ⇒ 84x – 126000 = 99x – 198000 ⇒ 15x = 72000 ⇒ x = 4800 The total income of Radhey and Ranu = 12x + 9x = 21 × 4800 = Rs. 1,00,800 ∴ The total income of Radhey and Ranu is Rs. 1,00,800 |
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| 5005. |
The ratio of monthly earning of Rohit and Ravi is 5 : 4 and their expenditure ratio is 6 : 5. If they save in the ratio 3 : 2 and their combined saving is Rs. 5000 then what is the half yearly earning of Rohit?1. 1800002. 1440003. 900004. 150005. 12000 |
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Answer» Correct Answer - Option 3 : 90000 Given- Ratio of earning of Rohit and Ravi = 5 : 4 Ratio of their expenditure = 6 : 5 Ratio of their Savings = 3 : 2 Concept Used- Income = Expenditure + Savings Calculation- Let the earnings of Rohit and Ravi be 5x and 4x and their expenditure be 6y and 5y Savings of Rohit = 5x - 6y Savings of Ravi = 4x - 5y According to Question- 5x - 6y + 4x - 5y = 5000 ⇒ 9x - 11y = 5000 ---------(i) (5x - 6y)/(4x - 5y) = 3/2 ⇒ 10x - 12y = 12x - 15y ⇒ 2x - 3y = 0 -------(ii) Solving Equation i and ii we get x = 3000 and y = 2000 Monthly earning of Rohit = 5 × 3000 ⇒ 15000 ∴ Half Yearly earning of Rohit = 6 × 15000 ⇒ 90000 |
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| 5006. |
Convert the decimal number 151.75 to binary1. 10000111.112. 11010011.013. 00111100.004. 10010111.11 |
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Answer» Correct Answer - Option 4 : 10010111.11 Concept: Decimal to Binary: To convert the decimal number into binary follow the below steps:
Calculation: Given number is 151.75 Converting the 151 into binary Step 1: Divide (151)10 successively by 2 until the quotient is 0: 151/2 = 75, remainder is 1 Step 2: Read from the bottom (MSB) to top (LSB) as 10010111. This is the binary equivalent of decimal number 151 (Answer). Converting the 0.75 into binary we get 0.11 Now the total conversion is: (151.75)10 = (10010111.11)2 |
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| 5007. |
Find sum of \(\rm \frac{1}{{1 \times 2}} + \frac{1}{{2 \times 3}} + \frac{1}{{3 \times 4}} +...+\frac{1}{{n \times (n+1)}} \)1. n(n + 1)2. \(\rm \frac {n}{n+1}\)3. \(\rm \frac {2n}{n+1}\)4. None of these |
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Answer» Correct Answer - Option 2 : \(\rm \frac {n}{n+1}\) Calculation: \(\rm \frac{1}{{1 \times 2}} + \frac{1}{{2 \times 3}} + \frac{1}{{3 \times 4}} +...+\frac{1}{{n \times (n+1)}} \) \(\rm = \frac{{2\; - \;1}}{{1 \times 2}} + \frac{{3\; - \;2}}{{2 \times 3}} + \frac{{4\; - \;3}}{{3 \times 4}} +... + \frac{{(n+1)\; - \;n}}{{n \times (n+1)}}\) \(\rm = \frac{1}{1} - \frac{1}{2} + \;\frac{1}{2} - \frac{1}{3} + \frac{1}{3} - \frac{1}{4} +... + \frac{1}{n} - \frac{1}{n+1}\) \(\rm = 1 - \frac {1}{n+1}\) \(\rm = \frac {n+1 -1}{n+1}\) \(\rm = \frac {n}{n+1}\) |
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| 5008. |
Difference between work efficiencies of two friends A and B is 80%, A being more hard worker. If B takes 56 days to complete a work, find out in how many days both working together can finish the work.1. 25 days2. 20 days3. 30 days4. 14 days5. 35 days |
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Answer» Correct Answer - Option 2 : 20 days Given: Efficiency of A is 80% more than B and B can finish a work in 56 days. Concept: This is a typical problem of time & work. Time required to complete a work is inversely proportional to the efficiency of the worker. Formula used: Time required = Total work / Rate of work done Calculations: Efficiency of A is 80% more than B. So, ratio of rate of work done between A and B = 180 : 100 = 9 : 5 Let’s assume, A works 9x work per day and B works 5x work per day. Total volume of the given work = 56 × 5x = 280x If they work together, rate of work = (9x + 5x)/day = 14x works/day Time required = 280x/14x = 20 days |
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| 5009. |
A man can row at the speed of 11 kmph in still water. The stream is running at the speed of 2 kmph. If the distance between two places is 117 km then find how long will he take to travel upstream and downstream.1. 9 hours2. 13 hours3. 18 hours4. 22 hours |
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Answer» Correct Answer - Option 4 : 22 hours Given: Speed of boat in still water = 11 kmph Speed of stream = 2 kmph Distance = 117 km Formula used: Downstream speed = Speed of boat + Speed of stream Upstream speed = Speed of boat – Speed of stream Speed = Distance/Time Calculations: Let the downstream speed and upstream speed be d and u respectively Downstream speed ⇒ d = 11 + 2 = 13 kmph Upstream speed ⇒ u = 11 – 2 = 9 kmph Time taken in going upstream and downstream ⇒ (117/9) + (117/13) ⇒ 13 + 9 ⇒ 22 hours ∴ The man will go upstream and downstream in 22 hours |
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| 5010. |
Ratio of the present ages of Abhik and Anuja is 3 : 2. After 15 years ratio of ages of Abhik and Ankan will be 9 : 5 and that between Anuja and Ankan will be 7 : 5. What is the present age of Ankan?1. 25 years2. 20 years3. 10 years4. 15 years5. Can’t be determined |
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Answer» Correct Answer - Option 3 : 10 years Given: Ratio of the present ages of Abhik and Anuja is 3 : 2. After 15 years ratio of ages of Abhik and Ankan will be 9 : 5. After 15 years ratio of ages of Anuja and Ankan will be 7 : 5 Calculation: Let us assume present ages of Abhik, Anuja and Ankan be 3x, 2x and y respectively. ATQ, \(\frac{{3x\; + \;15}}{{y\; + \;15}} = \;\frac{9}{5}\) ⇒ 15x + 75 = 9y + 135 ⇒ 15x – 9y = 60 ----(1) And, \(\frac{{2x\; + \;15}}{{y\; + \;15}} = \;\frac{7}{5}\) ⇒ 10x + 75 = 7y + 105 ⇒ 10x – 7y = 30 ----(2) Solving (1) & (2), y = 10 Present age of Ankan = 10 years. |
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| 5011. |
The average age of a family consisting both the parents along with their 3 sons is 30 years. If age of the second son is 12 years. What was the average age of the family just before the birth of second son?1. 32 years2. 33 years3. 34 years4. 35 years5. 36 years |
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Answer» Correct Answer - Option 3 : 34 years Given: Average age of 5 members of the family is 30 years and second son is 12 years old at present. Concept: This is an age related question and can be solved just by simple calculations. Calculation: Total age of the family at present = 5 × 30 = 150 years When second son was born, number of members in the family = 3 [since the youngest son was not born at that time] And, 12 years ago their sum of ages = (150 – 4 × 12) = 102 years Their average age at that time = 102/3 = 34 years Students often makes mistakenly takes number of family members as 4 when calculating. Beware of that mistake. |
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| 5012. |
Bhanu can row upstream at 8 kmph and downstream at 15 kmph. Find Bhanu's rowing speed in still water and the speed of current respectively.1. 11.5 kmph, 3.5 kmph2. 3.5 kmph, 11.5 kmph3. 12 kmph, 3 kmph4. 3 kmph, 12 kmph |
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Answer» Correct Answer - Option 1 : 11.5 kmph, 3.5 kmph Given: Downstream speed = d = 15 kmph Upstream speed = u = 8 kmph Formula used: Speed of boat in still water = (d + u)/2 Speed of stream = (d – u)/2 Calculations: Let the speed of boat in still water be B and the speed of stream be S Speed of boat in still water ⇒ B = (15 + 8)/2 ⇒ B = 23/2 ⇒ B = 11.5 kmph Speed of stream ⇒ S = (15 – 8)/2 ⇒ S = 7/2 ⇒ S = 3.5 kmph ∴ The speed of boat in still water is 11.5 kmph and the speed of stream is 3.5 kmph |
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| 5013. |
A can of pickle consist mixture of olives and oil in ratio of 3 : 5, when 2 liters of oil is replaced with mixture, the ratio of olive to oil becomes 3 : 9. Calculate quantity of olives in the initial mixture. 1. 1.5 L2. 2.5 L3. 10/3 L4. 2.25 L5. 3 L |
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Answer» Correct Answer - Option 4 : 2.25 L Given: Initial mixture = 3 : 5 Final mixture = 3 : 9 Calculation: Let’s, calculate this sum in terms of parts. ⇒ Initial mixture = 3 + 5 ⇒ Initial mixture = 8 parts ⇒ Final mixture = 3 + 9 ⇒ Final mixture = 12 parts 2 liters were replaced while forming final mixture ⇒ 12 – 8 = 2 L ⇒ 4 Parts = 2 L ⇒ 1 Part = 1/2 L ⇒ 8 Parts = 8 × (1/2) ⇒ Initial Quantity = 4 L + 2L (∵ 2 L was replaced) ⇒ Quantity of olives = (3/8) × 6 ∴ Quantity of olives = 2.25 L |
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| 5014. |
A mixture of acid and water has a volume of 164 liters with ratio of acid to water as 21 : 20. What volume of the mixture have to be replaced with 10 liters of water so that the ratio becomes 1 : 4?1. 157.6 liters2. 124.7 liters3. 152.7 liters4. 162 liters5. None of these |
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Answer» Correct Answer - Option 1 : 157.6 liters Given: Initial quantity of mixture = 164 liters Acid : Water = 21 : 20 Concept: When replacing the mixture with water, quantity of acid will only decrease whereas quantity of water will first decrease and then increase. Calculations: Initial quantity of acid = 164 × 21/41 = 84 liters Initial quantity of water = 164 – 84 = 80 liters Let us assume the volume of mixture that has to be replaced by 10 liters of water = 41x [Note how we are choosing the values so that we can avoid complicated fractions] In 41x liters mixture, Quantity of acid = 21x liters Quantity of water = 20x liters ∴ Final quantity of acid = (84 – 21x) liters ∴ Final quantity of water = (80 – 20x + 10) liters = (90 - 20x) liters ATQ, (84 – 21x)/ (90 - 20x) = ¼ ⇒ 336 – 84x = 90 – 20x ⇒ x = 246/64 = 123/32 ∴ Quantity of mixture to be replaced = 123/32 × 41 = 157.6 liters |
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| 5015. |
10 ml mixture of `H_(2), CH_(4)` and `CO_(2)` was exploded with 15 ml of oxygen. After treatment with KOH the vloume reduced by 6 ml and again on treatment with alkaline pyrogallol, the volume further reduced by 3 ml. Then volume of `H_(2)` in mixture.A. 6 mlB. 1 mlC. 5 mlD. 4 ml |
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Answer» Correct Answer - D `{:(H_(2) (g),+,(1)/(2)O_(2) (g),rarr,H_(2)O(l),),(x,,(x)/(2),,,),(-,-,-,,,):}` `{:(CH_(2) (g),+,2O_(2) (g),rarr,CH_(4) (g),+,2H_(2)O(g),),(y,,2y,,-,,-,),(-,,-,,y,,-,):}` `CO_(2) (g) + O_(2) (g) rarr x` `10 - (x + y)` `V_(CO_(2))` (total) = 6 mL (absorbed by KOH) `y + 10 - (x - y) = 6` `10 - x = 6` `x = 4 mL` `V_(H_(2)) = 4 mL` `V_(O_(2)) = 15 - ((x)/(2) + 2y) = 3` (absorbed by alkaline pyrogallol) `V_(O_(2)) = 12 = (x)/(2) + 2y` `x + 4y = 24` `4y = 20` `y = 5` `V_(O_(2)) = 5 mL` |
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| 5016. |
10 ml mixture of `H_(2), CH_(4)` and `CO_(2)` was exploded with 15 ml of oxygen. After treatment with KOH the vloume reduced by 6 ml and again on treatment with alkaline pyrogallol, the volume further reduced by 3 ml. Percentage (%) composition of `CH_(4)` in the mixture.A. 0.4B. 0.6C. 0.5D. 0.1 |
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Answer» Correct Answer - C `{:(H_(2) (g),+,(1)/(2)O_(2) (g),rarr,H_(2)O(l),),(x,,(x)/(2),,,),(-,-,-,,,):}` `{:(CH_(2) (g),+,2O_(2) (g),rarr,CH_(4) (g),+,2H_(2)O(g),),(y,,2y,,-,,-,),(-,,-,,y,,-,):}` `CO_(2) (g) + O_(2) (g) rarr x` `10 - (x + y)` `V_(CO_(2))` (total) = 6 mL (absorbed by KOH) `y + 10 - (x - y) = 6` `10 - x = 6` `x = 4 mL` `V_(H_(2)) = 4 mL` `V_(O_(2)) = 15 - ((x)/(2) + 2y) = 3` (absorbed by alkaline pyrogallol) `V_(O_(2)) = 12 = (x)/(2) + 2y` `x + 4y = 24` `4y = 20` `y = 5` `V_(O_(2)) = 5 mL` |
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| 5017. |
Which of the following is not responsible for stability of acyclic hydrocarbon?(1) Torsional strain(2) Angle strain(3) Steric strain(4) Vander waal's strain |
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Answer» Correct option: (2) Angle strain Explanation: Angle strain is found in cyclic compounds. |
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| 5018. |
Two numbers are respectively 40% and 80% more than a third number. Then find the ratio of the two numbers.1. 4 ∶ 52. 3 ∶ 53. 7 ∶ 94. 2 ∶ 9 |
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Answer» Correct Answer - Option 3 : 7 ∶ 9 Given: Two numbers are respectively 40% and 80% more than a third number Calculations: Let the third number be 100x So, First number = 100x × (140/100) = 140x Second number = 100x × 180/100 = 180x Required ratio = 140x ∶ 180x ⇒ 7 ∶ 9 ∴ Required ratio is 7 ∶ 9 |
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| 5019. |
If 40% of x = 15% of y, then (y - x)/(y + x) is-1. 5∶42. 5∶11 3. 11∶54. 4∶5 |
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Answer» Correct Answer - Option 2 : 5∶11 Given: 40/100) × x = (15/100) × y Calculation: 40/100) × x = (15/100) × y ⇒ x/y = 15/40 ⇒ x/y = 3/8 ⇒ x ∶ y = 3p∶ 8p ⇒ (y - x)/(y + x) = (8p - 3p)/(8p + 3p) ⇒ (y - x)/(y + x) = 5p/11p ∴ (y - x) ∶ (y + x) = 5∶ 11 The Correct option is 2 i.e. 5∶11 |
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| 5020. |
If the ratio between two numbers are 3 : 4. If the first number and second number are increased by 40% and 50% respectively. Then the new ratio of the numbers are:1. 9 : 102. 11 : 103. 3 : 44. 7 : 10 |
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Answer» Correct Answer - Option 4 : 7 : 10 Given: The ratio between two numbers = 3 : 4 Formula used: If a number is increased by y%, then the new number will be [(100 + y)/100] × a number Calculation: Let the first number be 3x and the second number be 4x According to the question, the first number increased by 40% Now new first number = [(100 + 40)/100] × 3x ⇒ New first number = (140/100) × 3x ⇒ New first number = 1.4 × 3x ⇒ New first number = 4.2x And the second number is increased by 50% Now new second number = [(100 + 50)/100] × 4x ⇒ New second number = (150/100) × 4x ⇒ New second number = 1.5 × 4x ⇒ New second number = 6x The ratio of the first number and the second number = 4.2x/6x ⇒ The ratio of the first number and the second number = 42/60 ⇒ The ratio of the first number and the second number = 7/10 ∴ The ratio of the first number and the second number is 7/10. |
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| 5021. |
The two number A and B are 50% and 40% more than the third number C. Then, find the ratio of A and B. 1. 16 : 172. 15 : 143. 12 : 174. 17 : 155. 15 : 16 |
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Answer» Correct Answer - Option 2 : 15 : 14 Given: The number A is 50% more than the number C. The number B is 40% more than the number C. Concept Used: The increased value = Value × (100 + percentage)/100 Calculation: Let the value of C be x. Then , the value of A = (100 + 50)/100 × x = 3x/2 The value of B = (100 + 40)/100 × x = 7x/5 Then, the ratio of A and B = 3x/2 : 7x/5 The ratio of A and B = 15 : 14 ∴ The ratio of the number A and B is 15 : 14. |
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| 5022. |
Seats of IT, mechanical and civil in a college are in ratio 4 : 4 : 5. If it is decided to increase the seats by 20%, 50% and 20% respectively in these branches what will be the ratio of increased seats.1. 4 : 4 : 52. 4 : 3 : 73. 4 : 5 : 54. 5 : 6 : 95. 3 : 6 : 7 |
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Answer» Correct Answer - Option 3 : 4 : 5 : 5 Given: Seats of IT, mechanical and civil in a college are in ratio 4 : 4 : 5 Calculation: Let the seats of IT, mechanical and civil be 4x, 4x and 5x After increment seats of IT will be = 4x × 120/100 = 4.8x After increment seats of Mechanical will be = 4x × 150/100 = 6x After increment seats of civil will be = 5x × 120/100 = 6x ⇒ required ratio = 4.8x : 6x : 6x ⇒ After solving ratio = 4 : 5 : 5 |
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| 5023. |
Hydro-metallurgical process of extraction of metals is based onA. complex formationB. hydrolysisC. dehydrationD. dehydrogenation |
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Answer» Correct Answer - A Hydrometallurgical process of extraction of metals is based on complex formation ,e.g. `Ag_2S` is converted into `Na[Ag(CN)_2]`. When Zn is added , Ag is displaced . |
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| 5024. |
`(Ag +Pb) alloy overset("Melt and add zinc")rarr (Ag +Pb +Zn) "melt" overset("Cool") rarr (LayerX)/(LayerY)` Select correct statements based on above scheme:A. Layer X contains Zn and AgB. Layer Y contains Pb and Ag but amount of silver in this layer is smaller than in layer XC. X and Y are immiscible layerD. All of the above are correct statements . |
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Answer» Correct Answer - D Zn and Pb is molten state are immiscible and form separate layers , zinc being lighter forms upper layer . Ag in soluble in both . Hence , all statements are correct . |
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| 5025. |
Which is correct process-mineral group in metallurgical extraction ?A. Leaching : `Ag`B. Van Arkel : `Zr`C. Liquation : `Sn`D. Zone refining : `Sn` |
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Answer» Correct Answer - A::B::C Redining of impure `Sn` cannot be done by zone-refining process , other options are correct. |
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| 5026. |
In the metallurgy of iron, when limestone is added to the blast furnace,the calcium ions end up inA. SlagB. GangueC. Calcium metalD. `CaCO_(3)` |
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Answer» Correct Answer - A `underset("Impurity")(SiO_(2)) +underset("Flux")(CaO)rarrunderset("Slag")(CaSiO_(3))` |
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| 5027. |
This picturesque town circled by the majestic Myntdu River and serves as the headquarters of the district. Caves in Lumshnong and Syndai in this district is one of the largest cave networks in Asia. Name the headquarter town |
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Answer» Jowai headquarter town |
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| 5028. |
Crystal field theory with its assumptions of completely electrostatic metal-ligand interactions, does not appear to retionalize the spectrochemical series particularly well. To explain the order of ligands in the series we must admit some covalent contribution to the metal ligand bond, both sigma and pi. Sigma bonds are formed by ligands using their p orbitals (e.g. `Cl^(-)`) or by hybrid orbitals (e.g. `sp^(3)`) by `(H_(2)O`) since all ligands are capable of such sigma interaction, this is not very useful in rationalizing spectrochemical series. The pi bonding ability of ligands partially justifies their position in spectrochemical series. pi-acid ligands. which can accept electron density from filled metal orbital into their empty orbital via pi interation appear towards stronger/higher and of the series e.g. `CN^(-).PR_(3)` etc. While sigma-donor ligands are typically weak field ligands e.g. `Cl^(-),O^(2-)` etc. Q. Which of the following `d` orbitals of the central atom is useful for sigma bond formation with ligands in octahedral field?A. `d_(xy),d_(x^(2)-y^(2))`B. `d_(z^(2)),d_(x^(2)-y^(2))`C. `d_(yz),d_(xz)`D. `d_(xy),d_(yz),d_(xz)` |
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Answer» Correct Answer - A For sigma covalent bond, that is head on overlap the d orbitals must be those of the `e_(g)` set, because only these orbitals point at the ligands in octahedral field. |
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| 5029. |
Crystal field theory with its assumptions of completely electrostatic metal-ligand interactions, does not appear to retionalize the spectrochemical series particularly well. To explain the order of ligands in the series we must admit some covalent contribution to the metal ligand bond, both sigma and pi. Sigma bonds are formed by ligands using their p orbitals (e.g. `Cl^(-)`) or by hybrid orbitals (e.g. `sp^(3)`) by `(H_(2)O`) since all ligands are capable of such sigma interaction, this is not very useful in rationalizing spectrochemical series. The pi bonding ability of ligands partially justifies their position in spectrochemical series. pi-acid ligands. which can accept electron density from filled metal orbital into their empty orbital via pi interation appear towards stronger/higher and of the series e.g. `CN^(-).PR_(3)` etc. While sigma-donor ligands are typically weak field ligands e.g. `Cl^(-),O^(2-)` etc. Q. Which of the following is false for CO ligand?A. it is a pi-acid ligand.B. CO accepts electron density from central atom into its pi bonding molecular orbital.C. CO forms sigma bond with central atom using its sp hybrid orbital.D. CO is a strong field ligand. |
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Answer» Correct Answer - C CO accepts electron density from central atom into its empty pi anti-bonding MO, because its pi bonding MO is already occupied Hence it is pi-acid ligand. |
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| 5030. |
Crystal field theory views the bonding in complexes as arising from electrostatic interaction and considers the effect of the ligand charges on the energies of the metal ion d-orbitals In this theory, a ligand lone pair is modelled as a point negative charge that repels electrons in the d-orbitals of the central metal ion.The theory concentrated on the resulting splitting of the d-orbitals in two groups with different energies and used that splitting to rationalize and correlate the optical spectra,thermodynamic stability, and magnetic properties of complexes.This energy splitting between the two sets of d-orbitals is called the crystal field splitting `Delta`. In general, the crystal field splitting energy `Delta` corresponds to wavelenght of light in visible region of the spectrum, and colours of the complexes can therefore be attributed to electronic transition between the lower and higher energy sets of d-orbitals. In general, the colour that we see is complementry to the colour absorbed. Different metal ions have different value of `Delta`, which explains why their complexes with the same ligand have different colour. Similarly the crystal field splitting also depends on the nature of ligands and as the ligand for the same metal varies from `H_2O` to `NH_3` to ethylenediamine, `Delta` for complexes increase.Accordingly, the electronic transition shifts to higher energy (shorter wavelength) as the ligand varies from `H_2O` from `NH_3` to en, thus accounting for the variation in colour. Crystal field theory accounts for the magnetic properties of complexes in terms of the relative values of `Delta` and the spin pairing energy P. Small `Delta` values favour high spin complexes, and large `Delta` values favour low spin complexes. Which of the following complexes are diamagnetic ? `{:([Pt(NH_3)_4]^(2+),[Co(SCN)_4]^(2-),[Cu(en)_2]^(2+),[HgI_4]^(2-)),("square planar","tetrahedral","square planar","tetrahedral"),((i),(ii),(iii),"iv"):}`A. (i) and (ii)B. (ii) and (iii)C. (i) and (iv)D. (iii) and (iv) |
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Answer» Correct Answer - C (i)`._78`Pt(II) has `5d^8` configuration , all electrons are paired , so diamagnetic . (ii)`._27Co^(2+)` has `3d^7` configuration , `SCN^-` is weak field ligand. So the complex is paramagnetic with three unpaired electrons. (iii)`._29Cu^(2+)` has `3d^9` configuration , complex is paramagnetic with one unpaired electron. (iv)`._80Hg^(2+)` has `5d^10` configuration , all electrons are paired so diamagnentic |
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| 5031. |
Crystal field theory views the bonding in complexes as arising from electrostatic interaction and considers the effect of the ligand charges on the energies of the metal ion d-orbitals In this theory, a ligand lone pair is modelled as a point negative charge that repels electrons in the d-orbitals of the central metal ion.The theory concentrated on the resulting splitting of the d-orbitals in two groups with different energies and used that splitting to rationalize and correlate the optical spectra,thermodynamic stability, and magnetic properties of complexes.This energy splitting between the two sets of d-orbitals is called the crystal field splitting `Delta`. In general, the crystal field splitting energy `Delta` corresponds to wavelenght of light in visible region of the spectrum, and colours of the complexes can therefore be attributed to electronic transition between the lower and higher energy sets of d-orbitals. In general, the colour that we see is complementry to the colour absorbed. Different metal ions have different value of `Delta`, which explains why their complexes with the same ligand have different colour. Similarly the crystal field splitting also depends on the nature of ligands and as the ligand for the same metal varies from `H_2O` to `NH_3` to ethylenediamine, `Delta` for complexes increase.Accordingly, the electronic transition shifts to higher energy (shorter wavelength) as the ligand varies from `H_2O` from `NH_3` to en, thus accounting for the variation in colour. Crystal field theory accounts for the magnetic properties of complexes in terms of the relative values of `Delta` and the spin pairing energy P. Small `Delta` values favour high spin complexes, and large `Delta` values favour low spin complexes. Which of the following statements is incorrect ?A. The `Ni^(2+)` (aq) cation is coloured because `Ni^(2+)` ion can absorb light, which promotes electrons from the filled d-orbitals to the higher energy half filled d-orbitalsB. The `Zn^(2+)` (aq) cation is colourless because the d-orbitals are completely filled and no electrons can be promoted, so no light is absorbedC. A complex which has just one absorption band at 455 nm, must be red colouredD. None |
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Answer» Correct Answer - C As it absorbs blue colour light (`lambda`=455 nm), the colour of the complex must be orange. |
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| 5032. |
Assertion:- If dipole `(vecP_(1))` is moved along the line normal to the axis (dotted line shown) of another dipole `(vecp_(2))`, their interaction energy does not chagne. Reason:- Electric field of `vecp_(2)` at the position of `vecp_(1)` is normal to `vecp_(1)`.A. If both Assertion `&` Reason are True `&` the Reason is a correct explanation of the Assertion.B. If both Assertion `&` Reason are True but Reason is not a correct explanation of the Assertion.C. If Assertion is True but the Reason is False.D. If both Assertion `&` Reason are False. |
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Answer» Correct Answer - A Position of `vecP_(1)` remains at equitorial position of `vecP_(2)` hence electric field of `vecP_(2)` at position of `vecP_(1)` always remains perpendicular `vecU=-vecP.vecE=0` |
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| 5033. |
An isolated parallel-plate capacitor of capacitor C has paltes X and Y. If plate X is given charge Q, the potential difference between X and Y IsA. zeroB. `(2Q)/(C)`C. `(Q)/(C )`D. `(Q)/(2C )` |
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Answer» Correct Answer - D |
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| 5034. |
A uniform disk, a thin hoop (ring), and a uniform sphere, all with the same mass and same outer radius, are each free to rotate about a fixed axis through its center. Assume the hoop is connected to the rotation axis by light spokes. With the objects starting from rest, identical forces are simultaneously applied to the rims, as shown. Rank the objects according to their angular momentum after a given time t, least to greatest. A. all tieB. disk, hoop, sphereC. hoop, disk, sphereD. hoop, sphere, disk |
| Answer» Correct Answer - A | |
| 5035. |
In the given figure, charge +Q is placed at the centre of a dotted circle. Work done in taking another charge +q from A to B is W1 and from B to C is W2. Which one of the following is correct : W2>W1 ; W1 = W2; W1>W2? |
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Answer» As charge +Q is at the center of the circle, Therefore, VA = VC If VB is potential at point B, Then, VB = VA = VB - VC ∴ WAB = Q(VB - VA) = W1 WBC = Q(VB - VC) = W2 ∴ Numerically, W1 = W2 |
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| 5036. |
An electron orbiting around a nucleus has angular momentum L. The magnetic field produced by the electron at the centre of the orbit can be expressed as :A. `B = (mu_(0) e//8pi mr^(3))L`B. `B =(mu_(0)e//4 pi mr^(3))L`C. `B = (mu_(0) e//pi mr^(3))L`D. `B =(e//4 pi epsilon_(0) mr^(3))L` |
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Answer» Correct Answer - B `(B)/(L)=(mu_(0))/(4 pi)((eV)/(r^(2)))/(mVr)L=m Vr` `(B)/(L)=(mu_(0))/(4pi)(eV)/(e^(2))xx(1)/(mVr)` `rArr B =(mu_(0))/(4 pi)(L)/(r)=(mu_(0)eL)/(4 pimr^(3))`. |
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| 5037. |
Only lyman series is found in the absorption spectrum of hydrogen atom whereas in the emissions spectrum , all the series are found. Please makes this statement clear |
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Answer» Absorption transitions of Balmer series will be those which start from second energy-level(n=2). But because at ordinary temperatures almost all the atoms remain in their lowest energy level (n=1), hence absorption transitions can start only from n=1 (not from n=2,3,4....levels). Thus, only Lyman series is found in the absorption spectrum of Hydrogen atom whereas in the emission spectrum, all the series are found. |
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| 5038. |
An electron orbiting around the nucleus of an atomA. has a magnetic dipole momentB. exerts an electric force on the nucleus equal to that on it by the nucleusC. does produce a magnetic induction at the nucleusD. has a net energy inversely proportional to its distance from the nucleus. |
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Answer» Correct Answer - A::B::C::D `(mv^(2))/(r)=(kZe^(2))/(r^(2))rArr(mv^(2))/(2)=(kZe^(2))/(2r),M.E.=(mv^(2))/(2)-(Ze^(2))/(r)=(-Ze^(2))/(2r)prop(1)/(r)` |
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| 5039. |
Which of the following statements is correct with respect to colloidal state and surface phenomenon.A. Gold sol can be coagulated by SO `._(4)^(2-)ion`.B. `Sb_(2)S_(3)` sol can be coagulated by adding `Fe(OH)_(3)` sol.C. Adsorption processes are entropy driven process always.D. At very high pressures, adsorption increases with pressure. |
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Answer» Correct Answer - B `Sb_(2)S_(3)` is the negatively charged sol. |
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| 5040. |
Choose the correct option from the following options given below : (A) In the ground state of Rutherford's model electrons are in stable equilibrium. While in Thomson's model electrons always experience a net-force. (B) An atom has a nearly continuous mass distribution in a Rutherford's model but has a highly non-uniform mass distribution in Thomson's model (C) A classical atom based on Rutherford's model is doomed to collapse. (D) The positively charged part of the atom possesses most of the mass in Rutherford's model but not in Thomson's model |
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Answer» Correct option is (C) A classical atom based on Rutherford's model is doomed to collapse. According to Rutherford, e– revolves around nucleus in circular orbit. Thus e– is always accelerating (centripetal acceleration). An accelerating change emits EM radiation and thus e– should loose energy and finally should collapse in the nucleus. |
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| 5041. |
The `.^(238)U` nucleus has a binding energy of about 7.6 MeV per nucleon. If the nucleus were to fission into two equal fragments, each would have a kinetic energy of just over 100 MeV. From this, it can be concluded thatA. nuclei near A = 119 has mass less than half that of `.^(238)U`.B. nuclei near A = 119 have masses greater than half that of `.^(238U`C. nuclei near A = 119 must be bound by about 6.7 MeV / nucleonD. nuclei near A = 119 must be bound by about 8.5 MeV / nucleon |
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Answer» Correct Answer - A::D `200=238xxE-238xx7.6` `(200)/(238)+7.6=E` |
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| 5042. |
In an amplitude modulated wave upper and lower side band frequencies are 10MH3 and 6MH3 respectively find band width of signal(1) 8 MHz(2) 6 MHz(3) 4 MHz(4) 2 MHz |
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Answer» Correct option is (3) 4 MHz Band width = upper frequency - lower frequency = 10 - 6 = 4MHz |
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| 5043. |
Assertion: Potential is constant on surface & inside of conductor.Reason: E is perpendicular to surface of conductor.(a) If both assertion and reason are true and the reason is the correct explanation of the assertion.(b) If both assertion and reason are true, but the reason is not the correct explanation of the assertion.(c) If assertion is true, but reason is false.(d) If both the assertion and reason are false. |
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Answer» (a) If both assertion and reason are true and the reason is the correct explanation of the assertion. Since E=0, therefore the potential V inside the surface is constant. Because there is no potential difference between any two points inside the conductor, the electrostatic potential is constant throughout the volume of the conductor. |
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| 5044. |
The group of nicotinic receptor-blocking drugs consists of: a) Ganglion-blockers b) Atropine-similar drugs c) Neuromuscular junction blockers d) Both a and c |
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Answer» d) Both a and c |
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| 5045. |
M3 receptor sub type is located: a) In the myocardium b) In sympathetic post ganglionic neurons c) On effector cell membranes of glandular and smooth muscle cells d) On the motor end plates |
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Answer» c) On effector cell membranes of glandular and smooth muscle cells |
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| 5046. |
Which of the following drugs is both a muscarinic and nicotinic blocker? a) Atropine b) Benztropine c) Hexamethonium d) Succinylcholine |
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Answer» b) Benztropine |
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| 5047. |
All of the following parts of the heart are very sensitive to muscarinic receptor blockade except: a) Atria b) Sinoatrial node c) Atrioventricular node d) Ventricle |
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Answer» d) Ventricle |
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| 5048. |
Only good employer-employee relationships can make ______ good production. A) at B) for C) after |
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Answer» Correct option is B) for |
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| 5049. |
Heart muscle is sensitive toA. Electrical stimuliB. Chemical stimuliC. Mechanical stimuliD. All the above |
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Answer» Correct Answer - D Heart muscle is sensitive to electrical stimuli, chemical stimuli and mechanical stimuli. |
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| 5050. |
I saw a(n) _____ for a job as a waiter. A) invention B) mystery C) waste D) advertisement |
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Answer» Correct option is D) advertisement |
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