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28801.

The correct decreasing order for acid strength is(1)   NO2 CH2 COOH > NCCH2 COOH >  FCH2 COOH > ClCH2COOH (2)   FCH2COOH > NCCH2 COOH  > NO2 CHCOOH > ClCH2 COOH (3)   NO2CH2 COOH  > FCH2 COOH  > NCCH2 COOH  > ClCH2 COOH (4)   NCCH2COOH > O2NCH2 COOH > FCH2 COOH > ClCH2COOH 

Answer»

Correct option (1)   NO2 CH2 COOH > NCCH2 COOH >  FCH2 COOH > ClCH2COOH 

Explanation:

EWG increase acidic strength 

NO2 CH2 COOH > NCCH2 COOH >  FCH2 COOH > ClCH2COOH 

28802.

The decreasing order of electrical conductivity of the following aqueous solutions is : 0.1 M Formic acid (A), 0.1 M Acetic acid (B), 0.1 M Benzoic acid (C) (1) A > B > C (2) A > C > B (3) C > B > A (4) C > A > B

Answer»

Correct option (2) A > C > B  

Explanation:

Order of acidity : A > C > B 

Order of electrical conductivity : A > C > B 

28803.

 Suggest two materials other than hydrogen that can be used as fuels in fuel cells

Answer»

Methane and Ethane

28804.

Suggest two materials other than hydrogen that can be used as fuels in fuel cells.

Answer»

Methane and methanol.

28805.

Why does the conductivity of a solution decrease with dilution ? 

Answer»

Conductivity of a solution is dependent on the number of ions per unit volume. On dilution, the number of ions per unit volume decreases, hence the conductivity decreases.

28806.

Depict the galvanic cell in which the reaction Zn (s) + 2Ag+ -->Zn2+ + 2Ag (s)takes place. Further show : (a) Which of the electrode is negatively charged? (b) The carriers of the current in the cell. (c) Individual reaction at each electrode.

Answer»

Zn (s)|Zn2+ (aq) || Ag+ (aq)|Ag (s)

 (a) Zn electrode (anode)

 (b) Ions are carriers of the current in the cell.

 (c) At anode : 

Zn (s) --> Zn2+ + 2e-

At cathode :

 Ag+ + e- --> Ag (s)

28807.

What are sacred groves? Where are they found?

Answer»

Sacred Groves:-

Sacred groves are the secret patches around places of worship. They are of a great religious value among tribal communities.

In such cases nature is protected by prevailling religious and cultural traditions. Here tracts of forests are set a side and all plants and animals are venerated and provided with complete protection.

Example of sacred groves are Kashi and Jaintia hills in Meghalaya, Aravali Hills in Rajasthan, westen Ghat regions of Karnataka, Maharastra and Sarguja (MP), Chanda and Batsar areas of M.P., Kaimul in Bihar, Rajgir and Brabar Hills in Bihar regions Hazaribagh in Jharkhand. In Sikkim, Khecheo palri lake is decleared sacred by peope, thus protecting the aquatic flora and fauna.

Role in conservatino:- Many rare and threatened plants have bun protected in sacredgroves of Meghalaya. Such areas have been found to be most undistrubed and they are usually surrounded bymost degraded lands capes.

28808.

Which one of the following is not the Characteristics of the Social Class ?(a) Class Concioussness(b) Achieved membership(c) Based on birth(d) Open System. 

Answer»

Based on birth is not the Characteristics of the Social Class.

28809.

Which Statement is not Correct amongst the following ?(a) Restriction on food are found in the caste system(b) Caste system is based on birth(c) Hierarchy is not found in the Caste system(d) Hierarchy is found in the Caste system. 

Answer»

Hierarchy is not found in the Caste system is not Correct .

28810.

Bullet train in india was run with the help of which country?1. Japan2. China3. Russia4. USA

Answer» Correct Answer - Option 1 : Japan

Concept:

  • The First Bullet Train project was completed with Japan.
  • Japan provides technical and financial support.
  • The length of the track is 508 km.
  • The construction began in September 2017.

Explanation:

  • Prime Minister Narendra Modi started the bullet train project connecting Mumbai and Ahmadabad.
  • The train has a feature of high speed around 350kmph.
28811.

In which state is Sriharikota located?1. Andhra Pradesh2. Tamilnadu3. Orissa4. Gujarat

Answer» Correct Answer - Option 1 : Andhra Pradesh

The correct answer is Andhra Pradesh.

  • Sriharikota:
    • It is a barrier island near the Bay of Bengal.
    • It is located in Nellore district in Andhra Pradesh.
    • The Satish Dhawan Space Centre is also located here.
    • It is known as ‘Spaceport of India’.

  • This place is selected for rocket launching in India because Sriharikota is located at the equator.
  • There is an additional velocity present on the equator which will eventually help rockets launching from the east coast of India.
28812.

What name is given to the path of a planet around the sun?1. Route2. Milky Way3. Cosmic highway4. Orbit

Answer» Correct Answer - Option 4 : Orbit

The correct answer is Orbit.

  • An orbit is the path of a planet around the sun.

  • Kepler's Law of Planetary Motion states that planets revolve in an elliptical orbit.
  • Kepler’s Laws of Planetary Motion:
    • All planets move around the sun in elliptical orbits, with the sun being at rest at one focus of the orbit.
    • The position vector of the planet with the sun at the origin sweeps out equal area in equal time.
    • The square of the period of revolution of a planet around the sun is directly proportional to the cube of the main distance of the planet from the sun.

  • Our galaxy is called the Milky Way (or the Akashganga) and it contains about 300 billion stars and one of these is our sun.
    • Planets and other objects go round the sun and make up the solar system with the sun at the center. 
    • Milky Way Galaxy was formed 5 billion years after the Big Bang.
28813.

Most southern state of India?1. Karnataka2. Kerla3. Tamil Nadu4. Andhra Pradesh

Answer» Correct Answer - Option 3 : Tamil Nadu

Concept:

  • Cape Comorin is the southernmost point in South India.
  • It is located in Tamil Nadu.

Explanation:

  • The southernmost part refers to the place farthest towards the south.
  • Kanyakumari is the coastal town on the southernmost tip.
  • Cape Comorin is a town in Kanyakumari.
  • It is referred to as 'The Land's End'.
  • It is a popular tourist place with unique ocean sunrise and sunset.
28814.

Rafale jet come from which country?1. France2. Japan3. China4. Russia

Answer» Correct Answer - Option 1 : France

Explanation:

  • Rafale jet is a technology of France. It was built by Dassault Aviation. The Rafale jet deal was controversial for years.
  • In the year 2019, the Supreme court of India dismissed all the petitions regarding the case.
  • India has also finalized the 21 Russia's MiG-29 fighter's deal with Russia in 2020.
28815.

What is responsible for the chemical transmission of messages between cells?1. Synapse2. Neurotransmitters3. Axons4. Dendrites

Answer» Correct Answer - Option 1 : Synapse
  • Synapse is responsible for the chemical transmission of messages between cells.
  • Neurons communicate with one another at junctions called synapses. At a synapse, one neuron sends a message to a target neuron—another cell.
    Most synapses are chemical; these synapses communicate using chemical messengers. Other synapses are electrical; in these synapses, ions flow directly between cells.
    At a chemical synapse, an action potential triggers the presynaptic neuron to release neurotransmitters. These molecules bind to receptors on the postsynaptic cell and make it more or less likely to fire an action potential.

Let us discuss other options as well:

  • Axons connect with other cells in the body including other neurons, muscle cells, and organs. 
  • At a chemical synapse, an action potential triggers the presynaptic neuron to release neurotransmitters.
  • Dendrites are projections of a neuron (nerve cell) that receive signals (information) from other neurons.
28816.

Electronic City of India?1. Delhi2. Chandigarh3. Bangalore4. Indore

Answer» Correct Answer - Option 3 : Bangalore

Explanation:

  • Bangalore is the electronic city of India. It has an industrial park spread over 800 acres (3.2 km²) in Konappana Agrahara and Doddathogur villages. R. K. Baliga is the mastermind behind the concept of the electronic city.
DelhiIt is the capital of India.
ChandigarhIt is the joint capital of the two states Punjab and Haryana.
IndoreIt is the fourth-largest centre of the cotton textile industry in the country.
28817.

Neither my friend ______ I like playing soccer. A) or B) and C) but D) nor

Answer»

Correct option is D) nor

28818.

Who wrote 'Origin of Species'?1.Einstein2. Gibbs3. Newton4.Charles Darwin

Answer» Correct Answer - Option 4 :
Charles Darwin

Origin of Species by Natural Selection: 

  • It was written by Charles Darwin.
  • It was a groundbreaking scientific work by British naturalist Charles Darwin.
  • It was originally published in 1859.
  • Darwin, through his theory, argued, that organisms gradually evolve through a process he called “natural selection.”
  • In natural selection, organisms with genetic variations that are better suited to their environment have an advantage over the organisms of the same species that lack the variation.
  • And thus, the better-suited organism or specie, are in turn more likely to survive and more likely to give their features to future generations than the other.
  • And such, the cycle of natural selection of the specie is carried out during the course of evolution.

 

Charles Darwin:

  • Charles Darwin was born in 1809 in Shrewsbury, England.
  • Darwin proposed a theory of evolution called natural selection in the year 1859.
  • According to it those populations which are a better fit (reproductively fit) in an environment will be selected by nature and will survive more.
  • Darwin's theory of natural selection is popularly known as 'Darwinism'.
  • English naturalist Charles Darwin developed the idea of natural selection after a five-year voyage to study plants, animals, and fossils in South America and on islands in the Pacific.
  • Darwin conducted a sea voyage in a sailing ship called H.M.S Beagle as a part of his experiments on the theory of evolution.
  • Charles Darwin became almost universally thought of as the "Father of Evolution".
  • Darwin's process of natural selection has four components:
    • Variation 
    • Inheritance
    • High rate of population growth
    • Differential survival and reproduction
  • Charles Darwin died in 1882 at the age of seventy-three.

Thus, Charles Darwin wrote 'Origin of Species'.

BooksAuthor
The World As I See It Albert Einstein
How to Live Longer and Feel BetterLinus Pauling
The Theory of EverythingStephen Hawking
Mathematical Principles of Natural PhilosophyNewton
28819.

In which of the following years Kabir Purushkar award started?1. 19872. 19883. 19894. 1986

Answer» Correct Answer - Option 4 : 1986

The correct answer is 1986.

  • This award is given by the Government of Madhya Pradesh in the field for the Best Indian Poet composing poems in Indian languages. 
  • The Kabir Puruksar was instituted in the year 1986. It consists of a cash prize of 3 Lakhs, citation, Shawl, and coconut.
  • The first recipient of this award was poet Gopal Krishna in the year 1986. 

  •  The last recipient of this award was Ashok Chakradhar in the year 2018.
28820.

Out of NaCl and AgCl, which one shows Frenkel defect and why?

Answer»

AgCl shows Frenkel defect due to large difference in size between the positive (Ag+) and negative (Cl) ion

28821.

what gives covalent bond its strength?

Answer»

The strength of a covalent bond is measured by its bond dissociation energy, that is, the amount of energy required to break that particular bond in a mole of molecules. Multiple bonds are stronger than single bonds between the same atoms.

28822.

The coagulation of `100mL` of a colloidal solution of gold is completely prevented by adding `0.25g` of starch to it before adding `10mL` of `10%NaCl` solution. The gold number of starch isA. `24`B. `240`C. `120`D. `360`

Answer» Correct Answer - A
`0.024g` or `24mg`
28823.

In which of the following, first memeber is more stable than second?A. `(C_(6)H_(5))_(2)overset(**)(C)CH_(3),(C_(6)H_(5))_(3)overset(**)C`B. `:CH_(2),*CH_(2)*`C. `(C_(6)H_(5))_(3)overset(+)C,overset(+)CH_(3)`D. `(C_(2)H_(5))_(3),overset(**)C,(CH_(3))_(3)overset(**)C`

Answer» Correct Answer - C
`(C_(6)H_(5))_(3)overset(-)C` is more stable than `overset(-)CH_(3)` because three phenyl groups not only decrease the electron density but also stabilise it by the phenomena of resonance.
28824.

Ammonia changes the moist red litmus paper into-(A) Blue(B) Green(C) Black(D) White

Answer»

Answer is (A) Blue

28825.

How will you distinguish between: (i). Propan-2-ol and propan-1-ol (ii). Phenol and ethanol

Answer»

(i) propan-2-ol when treated with iodine and alkali gives yellow precipitate of iodoform whereas propan -1- ol does not gives iodoform test. 

(ii) Only phenol gives violet colour with FeCl3 solution.

3C6H5OH + FeCl3  (C6H3)3Fe + 3HCl

28826.

(I) Mention one important application of Henry's law. (II) Calculate the osmotic pressure of a solution obtained by mixing 100 cm3 of 0.25m and urea 100 cm3 of 0.1 m solution of cane sugar [R= 0.0821 L atm/mol/K]

Answer»

(i) soft drink and soda water packing under high pressure 

(ii) Number of mole of cane sugar = \(\frac{0.1\times100}{1000}\) = 0.01 mol 

Total volume, V = (100 + 100) cm3 

= 200 cm3 = 0.2L

For osmotic pressure, \(\pi=\frac{(n_1+n_2)}{v}RT\) 

\(\frac{(0.025+0.01)}{0.2}\) x 0.082 x 293

\(\frac{0.035}{2}\) × 0.082 × 293 = 4.2 atm

28827.

When NaCl solution is added to Fe(OH)3 colloidal solution then-(a) [Fe(OH3)]Fe3+ is formed(b) [Fe(OH3)]Cl-(c) [Fe(OH3)]Na+ is formed(d) Fe(OH)3 is coagulated

Answer»

Answer is (a) [Fe(OH3)]Fe3+ is formed

28828.

What will be the van't hoff factor for a solution of K4[FeCN6] if its dissociation is 50%

Answer»

Degree of dissociation, x=50%=0.5
Van't Hoff factor, i= number of moles after dissociation/total number of moles initially

= (1+4x)/1

i=1+4(0.5)=1+2=3

28829.

Strips of zinc, iron, magnesium and copper are taken in the test tubes \( A, B, C \) and \( D \) respectively. Same quantity of ferrous sulphate solution is added to these test tubes. In which test tubes chemical reaction will occur? Why? Write the chemical equations for the reactions taking place here.

Answer»

According to the metal reactivity series- zinc, magnesium metals are highly reactive metals and iron metal is also move reactive than copper metal.

Highly reactive metal can displace les reactive metals from their solutions.

Order of reactivity-

Mg > Zn > Fe > Cu

Therefore-

In test tube 'A & B' chemical reaction occurs-

In test tube -A

Zn(5) + FeSO4(aq) → Zn SO4(aq) + Fe(s)

In test tube - B

Mg(s) + FeSO4 (aq) → MgSO4(aq) + Fe(s)

In test tube - C & D

→ No chemical reactions.

28830.

On the basis of crystal field theory the write the electronic configuration of d4 in terms of t2g and eg in an octahedral field , when (I) Δ0 > P (II) Δ0 < P

Answer»

If ∆o > P, it becomes more energetically favourable for the fourth electron to occupy a t2g orbital with configuration t2g4 eg0 . Ligands which produce this effect are known as strong field ligands and form low spin complexes. If ∆o < P. Ligands which produce this effect are known as strong field ligands and form low spin complexes. In this case the configuration is t2g3 eg1

28831.

(i). why is adsorption always exothermic? (ii). Physisorption is multi layered while chemisorption is mono layered.

Answer»

(i) The particles are attached to the surface of another medium for the reaction to take place. During this process the residual forces on the surface of adsorbent decreases which in turn decreases the surface energy. This energy appears in the form of heat, hence adsorption is exothermic in nature. 

(ii) Chemisorption takes place as a result of the reaction between adsorbent and adsorbate. When the surface of the adsorbent is covered with one layer, no further reaction can take place. Physisorption is simply by Vander Wall’s forces. So any number of layers may be formed one over the other on the surface of the adsorbent.

28832.

(i). copper iron is not stable in aqueous solution(ii). Many of the transition metals shows maximum paramagnetic character amongst the bivalent ions of 1st transition series.

Answer»

(i) Cu+ ion in an aqueous solution is unstable. It disproportionate to give Cu2+ and Cu. 

(ii) Many of the transition metals shows maximum paramagnetic character amongst the bivalent ions of 1st transition series due to maximum number of unpaired electrons.

28833.

Explain the following (i). With the same d orbital configuration (d4) before Cr2+ is a reducing agent while Mn3+ is an oxidizing agent (ii). Many of the transition metals are known to form interstitial compounds

Answer»

(i) Cr2+ has the configuration 3d4 . It can lose electron to form Cr3+ which has stable 3d3 configuration. Hence it is reducing agent. On the other hand, Mn3+ also has 3d4 configuration but it can gain electron to form Mn2+ which has stable 3d5 configuration (as it is exactly half - filled). Hence it is oxidising agent. 

(ii) Many of the transition elements are known to form interstitial compounds due to presence of unpaired electrons in the d-orbital.

28834.

Give reasons:a). thermal stability decreases from H2O to H2Te b). fluoride ion has higher hydration enthalpy than chloride ion

Answer»

(a) Thermal stability decreases from H2O to H2Te. The thermal stability of the hydrides of group 16 elements decreases down the group. This is because M-H bond dissociation energy decreases down the group with the increase in the size of a central atom. 

(b) The size of halogen decreases down the group, therefore hydration enthalpy decrease.

28835.

Corbonyl compound (p) `underset((2). H_(2)O)overset((1). "grignard reagent")toPh-CH_(2)-underset(OH)underset(|)overset(H)overset(|)C-CH_(3)` Carbonyl compound can be:A. `Ph-CH_(2)-underset(O)underset(||)C-CH_(3)`B. `Ph-CH_(2)-CH=O`C. `CH_(3)-CH_(2)-CH=O`D. `CH_(3)-underset(O)underset(||)C-CH_(3)`

Answer» Correct Answer - B
`Ph-CH_(2)-CH-=Ounderset((2). H_(2)O)overset((1). CH_(3)MgBr)toPh-CH_(2)-underset(OH)underset(|)overset(H)overset(|)C-CH_(3)`
28836.

In which of the following reaction incorrect product is given?A. `PhMgBroverset(O_(2))tooverset(H^(+))toPh-OH`B. `CH_(3)-CH_(2)-MgBroverset(CO_(2))tooverset(H^(+))toCH_(3)-CH_(2)-COOH`C. `CH_(3)-CH=Ooverset(PhMgBr)tooverset(H^(+))toCH_(3)-underset(OH)underset(|)CH-Ph`D. `CH_(3)-C-=Noverset(PhMgBr)tooverset(H_(2)O)toCH_(3)-underset(OH)underset(|)CH-Ph`

Answer» Correct Answer - D
`CH_(3)-C-=Noverset(PhMgBr)tooverset(H_(2)O)toCH_(3)-underset(O)underset(||)C-Ph`
28837.

The metal extracted by leaching with cyanide isA. MgB. AgC. CuD. Na

Answer» Correct Answer - B
Silver ore forms a soluble complex when leached with NaCN solution and from which silver is precipitated using scrap zinc.
`Ag_(2)S("conc. Ore")+2NaCNoverset(Air)iff2AgCN+Na_(2)S`
`4Na_(2)S+5O_(2)+2H_(2)Oto2Na_(2)SO_(4)+4NaOH+2S`
`Na_(2)S` is converted in to `Na_(2)SO_(4)` Hence equilibrium shifts towards right side.
`AgCN+NaCNtoNa[Ag(CN)_(2)]` (soluble complex)
28838.

Reagent for the above reaction will be:A. hot acidic `KMnO_(4)`B. `CrO_(3),H^(+)`C. `CrO_(3)`, Pyridine, `CH_(2)Cl_(2)`D. dil alkaline `KMnO_(4)`

Answer» Correct Answer - C
Mild oxidizing agent like PCC can oxidize only alcohols into carbonyl compounds.
28839.

`NH_3` is heated initially at 15 atm from `27^@C` to `127^@C` at constant volume.At `127^@C` equilibrium is established.The new pressure at equilibrium at `127^@C` becomes 30 atm for the reaction `2NH_3(g)hArrN_2(g)+3H_2(g)` Then find the % of moles of `NH_3` actually decomposed.

Answer» Correct Answer - 50
`{:(2NH_3hArr,N_2+,3H_2),(a,0,0),(a-2x,x,3x):}`
`P_1/T_1=P_2/T_2implies15/300=P_2/400implies P_2=20` atm
Now `(a+2x)/a=30/20`
2a+4x=3a
`implies x=1/4a " " :.` % of `NH_3` decomposed =`(2x)/axx100=50%`
28840.

Match the following : `{:("Column I(Assume only reactant were present initially)","Column II"),((A)"For the equilibrium" NH_4I(s)hArr NH_3(g)+HI(g)",""If pressure is increased at equilibrium",(p)"Forward shift"),((B)"For the equilibrium" N_2(g)+3H_2(g)hArr 2NH_3(g)"volume is increased at equilibrium",(q)"No shift in equilibrium"),((C )"For the equilibrium" H_2O(g)+CO(g)hArr H_2(g)+CO_2(g)"inert gas is added at constant pressure at equilibrium",(r)"Backward shift"),((D)"For the equilibrium" PCl_5hArr PCl_3+Cl_2 Cl_2"is removed at equilibrium",(s)"Final pressure is more than initial pressure "):}`

Answer» Correct Answer - A-r ; B-r ; C-q ; D-p
(A)`Deltan_(g)` is +ve so as P is increased, backward shifting will take place.Total pressure even after shifting will remain same.
(B)`Deltan_g` is -ve so as V is increased, backward shifting will take place. But `P_("final")ltP_("Initial")`
( C)No change but `P_("final")ltP_("Initial")` as volume has increased.
(D)Forward shifting will take place and `P_("final")ltP_("Initial")`
28841.

For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride, etc. the measured densities are found to be less than those calculated from their molecular formula.The observed densities decreases towards a limit as the temperature is raised.This is due to the splitting of the molecular into simpler ones.The process is reversible and is called thermal dissociation. Example : `NH_4Cl hArr NH_3+HCl I_2hArr 2I` `N_2O_4 hArr 2NO_2 PCl_5hArr PCl_3+Cl_2` With increase in the number of molecules, the volume increases (pressure remaining constant) and in consequence, the density decreases.As the temperature rises, more and more dissociation takes place, and when practically complete dissociation occurs the density reaches its lowest limit. The extent of dissociation, i.e., the fraction of the total number of molecules which suffers dissociation is called the degree of dissociation.Gas density measurements can be used to determine the degree of dissociation.Let us take by general case where one molecule of a substance A splits up into n molecule of A on heating , i.e., `A_n(g)hArr nA(g)` `t=0 " " a" " 0` `t=t_(eq) a-x n.x alpha=x/a rArr x=a alpha.` `a-a alpha naalpha` Total no. of moles =`a-a alpha+n a alpha` =`[1+(n-1)alpha]a` Observed molecular weight or molar mass of the mixture `M_("mixture")=M_(A_(n))/([1+(n-1)alpha]), M_(A_(n))`=Molar mass of gas `A_n` The `K_P` for the reaction `N_2O_4 hArr 2NO_2` is 640 mm at 775 K.The percentage dissociation of `N_2O_4` at equilibrium pressure of 160 mm is :A. `80%`B. `30%`C. `50%`D. `70%`

Answer» Correct Answer - D
`{:(,N_2O_4" "hArr,2NO_2),("Mole before equilibrium",1,),("Mole at equilibrium",(1-x),2x):}`
`K_p=(4x^2)/((1-x))xx[P/(sumn)]^(Deltan)implies 640=(4x^2)/((1-x))160/((1+x))`
`4=(4x^2)/((1-x))` or `1-x^2=x^2` or `2x^2=1`
`:. " " x^2=1//2 or x=0.707=70.7%`
28842.

For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride, etc. the measured densities are found to be less than those calculated from their molecular formula.The observed densities decreases towards a limit as the temperature is raised.This is due to the splitting of the molecular into simpler ones.The process is reversible and is called thermal dissociation. Example : `NH_4Cl hArr NH_3+HCl I_2hArr 2I` `N_2O_4 hArr 2NO_2 PCl_5hArr PCl_3+Cl_2` With increase in the number of molecules, the volume increases (pressure remaining constant) and in consequence, the density decreases.As the temperature rises, more and more dissociation takes place, and when practically complete dissociation occurs the density reaches its lowest limit. The extent of dissociation, i.e., the fraction of the total number of molecules which suffers dissociation is called the degree of dissociation.Gas density measurements can be used to determine the degree of dissociation.Let us take by general case where one molecule of a substance A splits up into n molecule of A on heating , i.e., `A_n(g)hArr nA(g)` `t=0" " a" " 0` `t=t_(eq) a-x n.x alpha=x/a rArr x=a alpha.` `a-a alpha naalpha` Total no. of moles =`a-a alpha+n a alpha` =`[1+(n-1)alpha]a` Observed molecular weight or molar mass of the mixture `M_("mixture")=M_(A_(n))/([1+(n-1)alpha]), M_(A_(n))`=Molar mass of gas `A_n` The equation `alpha=(D-d)/((n-1)d)` is correctly matched for :A. `A hArr nB//2+nC//3`B. `A hArr nB//3+(2n//3)C`C. `A to(n//2)B+(n//4)C`D. `A hArr (n//2)B+C`

Answer» Correct Answer - B
`alpha=(D-d)/((n-1)d) implies (n-1)alpha=D/d-1`
`implies D/d=1+(n-1)alpha`
Hence one mole of reactant should produce total n moles of product
28843.

For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride, etc. the measured densities are found to be less than those calculated from their molecular formula.The observed densities decreases towards a limit as the temperature is raised.This is due to the splitting of the molecular into simpler ones.The process is reversible and is called thermal dissociation. Example : `NH_4Cl hArr NH_3+HCl I_2hArr 2I` `N_2O_4 hArr 2NO_2 PCl_5hArr PCl_3+Cl_2` With increase in the number of molecules, the volume increases (pressure remaining constant) and in consequence, the density decreases.As the temperature rises, more and more dissociation takes place, and when practically complete dissociation occurs the density reaches its lowest limit. The extent of dissociation, i.e., the fraction of the total number of molecules which suffers dissociation is called the degree of dissociation.Gas density measurements can be used to determine the degree of dissociation.Let us take by general case where one molecule of a substance A splits up into n molecule of A on heating , i.e., `A_n(g)hArr nA(g)` `t=0 " "a" " 0` `t=t_(eq) a-x n.x alpha=x/a rArr x=a alpha.` `a-a alpha naalpha` Total no. of moles =`a-a alpha+n a alpha` =`[1+(n-1)alpha]a` Observed molecular weight or molar mass of the mixture `M_("mixture")=M_(A_(n))/([1+(n-1)alpha]), M_(A_(n))`=Molar mass of gas `A_n` x(degree of dissociation) varies with `D/d` in the above reaction according to :A. B. C. D.

Answer» Correct Answer - B
`D/d=1+(n-1)x`
`implies D/d=1+x " " [n=2]`
which is a line with positive slope and X intercept =1
28844.

The following reaction attains equlibrium at high temperature `N_(2)(g)+2H_(2)O(g)+heathArr2NO(g)+2H_(2)(g)` The concentration of NO(g)is affected byA. increasing the nitrogen concentrationB. decreasing the nitrogen concentrationC. Compressing the reaction mixtureD. None of these

Answer» Correct Answer - A,B,C
As concentration of reaction (gaseous) are increased at equilibrium reaction will go in the forward direction.Also above reaction is endothermic therefore increase in temperature will favour it.
28845.

For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride, etc. the measured densities are found to be less than those calculated from their molecular formula.The observed densities decreases towards a limit as the temperature is raised.This is due to the splitting of the molecular into simpler ones.The process is reversible and is called thermal dissociation. Example : `NH_4Cl hArr NH_3+HCl I_2hArr 2I` `N_2O_4 hArr 2NO_2 PCl_5hArr PCl_3+Cl_2` With increase in the number of molecules, the volume increases (pressure remaining constant) and in consequence, the density decreases.As the temperature rises, more and more dissociation takes place, and when practically complete dissociation occurs the density reaches its lowest limit. The extent of dissociation, i.e., the fraction of the total number of molecules which suffers dissociation is called the degree of dissociation.Gas density measurements can be used to determine the degree of dissociation.Let us take by general case where one molecule of a substance A splits up into n molecule of A on heating , i.e., `A_n(g)hArr nA(g)` `t=0 " " a " " 0` `t=t_(eq) a-x n.x alpha=x/a rArr x=a alpha.` `a-a alpha naalpha` Total no. of moles =`a-a alpha+n a alpha` =`[1+(n-1)alpha]a` Observed molecular weight or molar mass of the mixture `M_("mixture")=M_(A_(n))/([1+(n-1)alpha]), M_(A_(n))`=Molar mass of gas `A_n` A sample of mixture of A(g),B(g) and C(g) under equilibrium has a mean molecular weight (observed ) is 80. The equilibrium is `underset((mol.wt.=100))(A(g))hArrunderset((mol.wt.=60))(B(g))+underset((mol.wt.=40))(C(g))` Find the degree of dissociation `alpha` for A(g)A. `0.25`B. `0.5`C. `0.75`D. `0.8`

Answer» Correct Answer - A
`A(g) hArr B(g)+C(g)`
`M_(Ob)=M_(th)/(M+(n-1)alpha)implies 80=100/(1+alpha)implies =1/4=0.25`
28846.

Statement-1 :Graphite can be converted into diamond by application of very high pressure and temperature. Using a suitable catalyst. Statement-2: Graphite is thermodynamically more stable and less dense than diamond.A. Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1B. Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1C. Statement-1 is True, Statement-2 is False.D. Statement-1 is False, Statement-2 is True.

Answer» Correct Answer - A
`C_(("graphite"))hArrC_(("diamond"))`(at high T and high P) (It is a fact)
28847.

Name the elements present in anode mud during refining of copper. Why does it contain such elements ?

Answer»

Au and Ag. They are not oxidized at anode. They are less electropositive than copper.

28848.

What is the effect of adding catalyst on the free energy of a reaction ?

Answer»

No change in AG.

28849.

What are collectors in froth floatation process ? Give one example.

Answer»

The correct answer  " Pine oil. "

28850.

Give the names and formulae of three ores which are concentrated by froth fioatation process.

Answer»

Galena (PbS), Zinc blende (ZnS), Cinnabar (HgS).