Explain the following (i). With the same d orbital configuration (d4)

1.	Explain the following (i). With the same d orbital configuration (d4) before Cr2+ is a reducing agent while Mn3+ is an oxidizing agent (ii). Many of the transition metals are known to form interstitial compounds
Answer» (i) Cr²⁺ has the configuration 3d⁴ . It can lose electron to form Cr³⁺ which has stable 3d³ configuration. Hence it is reducing agent. On the other hand, Mn³⁺ also has 3d⁴ configuration but it can gain electron to form Mn²⁺which has stable 3d⁵ configuration (as it is exactly half - filled). Hence it is oxidising agent. (ii) Many of the transition elements are known to form interstitial compounds due to presence of unpaired electrons in the d-orbital.

Explain the following (i). With the same d orbital configuration (d4) before Cr2+ is a reducing agent while Mn3+ is an oxidizing agent (ii). Many of the transition metals are known to form interstitial compounds

Answer»

(i) Cr²⁺ has the configuration 3d⁴ . It can lose electron to form Cr³⁺ which has stable 3d³ configuration. Hence it is reducing agent. On the other hand, Mn³⁺ also has 3d⁴ configuration but it can gain electron to form Mn²⁺which has stable 3d⁵ configuration (as it is exactly half - filled). Hence it is oxidising agent.

(ii) Many of the transition elements are known to form interstitial compounds due to presence of unpaired electrons in the d-orbital.

Discussion

No Comment Found

Related InterviewSolutions

What is the difference between multimolecular and macromolecular collids ? Give one example of each . How are associated colloids different from these two types of colloids ?
Gastrointestinal irritation, cardiovascular effects, including tachycardia,arrhythmias, and orthostatic hypotension, mental disturbances, and withdrawalare possible adverse effects of: A. Amantadine B. Benztropine C. Levodopa D. selegiline
Match the column I and IIColumn-IColumn-II(a)Parasitism(i)++(b)Commensalism(ii)+ –(c)Amensalism(iii)0 + (d)Mutualism(iv)0 –(1) (a) - iii, (b) - ii, (c) - iv, (d) - i (2) (a) - i, (b) - ii, (c) - iii, (d) - iv (3) (a) - ii, (b) - iii, (c) - i, (d) - iv (4) (a) - ii, (b) - iii, (c) - iv, (d) - i
Assertion: In commensalism, one organism is benefitted and other is unaffected Reason: Cattle egret bird and cattle is an example of commensalism (1) If both assertion and reason are true and reason is the correct explanation of assertion. (2) If both assertion and reason are true but reason is not the correct explanation of assertion. (3) If assertion is true but reason is false. (4) If both assertion and reason are false.
In charge of Calcutta Mint between 1832 to 1838, he studied and deciphered Ashokan rocks and pillars. His essays on antiquities are considered as classics. Hint: Varanasi. Who are we referring to?
Nature of climax community depends upon(A) Climate (B) Water (C) Soil fertility (D) Temperature
How do biofertilisers enrich the fertility of the soil?
Read carefully the passage and select the correct answer out of given four options:Biofertilizers are organisms that enrich nutrient quality of the soil. The important sources of biofertilizers are bacteria, fungi and cyanobacteria. The symbiotic association of Rhizobium with the root nodules of leguminous plants is the common example. These bacteria convert atmospheric nitrogen into nitrogenous compound and fix in the soil.The organisms which enrich the nutrient quality of the soil are called(a) Microbes(b) Biofertilizers(c) Yeast(d) Biopesticides
Electrophoresis is an essential procedure that needs to be employed in genetic fingerprinting why?
Assertion: Angiosperms form endosperm after fertilization and is diploid. Reason: In gymnosperms, endosperm is formed before fertilization and is triploid. a. Both assertion and reason are true, and reason is the correct explanation of assertion. b. Both assertion and reason are true, but reason is not the correct explanation of assertion. c. Assertion is true but reason is false. d. Both assertion and reason are false.

Explain the following (i). With the same d orbital configuration (d4) before Cr2+ is a reducing agent while Mn3+ is an oxidizing agent (ii). Many of the transition metals are known to form interstitial compounds

Discussion

No Comment Found

Related InterviewSolutions

Reply to Comment