Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Lactic acid, CH_3CH(OH)COOH molecule shows:

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GEOMETRICAL isomerism
Metamerism
Optical isomerism
Tautomerisms

Answer :C
2.

Lactic acid and extracted from muscles is :

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Laevorotatory
Dextrorotatory
similar with syntheticlactic ACID
NONE of these

Answer :B
3.

Lactam from which nylon-4 is synthesised is

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SOLUTION :(LACTAM ) is USED in the SYNTHESIS of nylon-4
4.

Lactic acid which extracted from muscles is :

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Laevorotatory
Dextrorotatory
similar with syntheticlactic ACID
NONE of these

Answer :B
5.

Lactase enzyme hydrolyses the lactose intoitsconstituent as …………. .

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GLUCOSE , FRUCTOSE
glucose , GALACTOSE
fructose only
glucoseonly

ANSWER :B
6.

Lacrymator or tear gas is:

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`C_6H_5COCl`
`C_6H_5OC_6H_5`
`C_6H_5COCH_2Cl`
`C_6H_5COCH_3`

ANSWER :C
7.

Lack of vit-P causes

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beri-beri
weakness of muscles
Hemorrhage
Scurvy

Answer :C
8.

Lack of vitamin B_1 causes scurvy.(True/False)

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ANSWER :beri-beri
9.

Labourer.s working with phosphorus suffer from a diseses in which bones decay. It is known as:

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Arthritis
Phossy jaw
Rickets
Cancer

Answer :B
10.

Laboratory preparation of Nitro ethane from ethyl bromide follows……………….. Mechanism.

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ANSWER :`SN^(2)`
11.

Laboratory method for the preperation of diborane involves the oxidation of

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SODIUM BOROHYDRIDE with iodine
Sodium borohydride with fluorine
Sodium borohydride with chlorine
Sodium borohydride with `KMnO_4`

ANSWER :A
12.

Laboratory method for the preparation of acetyl chloride is

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`CH_(3)COOH+SOCl_(2)toCH_(3)COCL`
`CH_(3)COOH+PCl_(3)toCH_(3)COCl`
`CH_(3)COONa+PCl_(3)toCH_(3)COCl`
All of these

Solution :In laboratory it is prepared by `SOCl_(2)` because byproduct `SO_(2) and HCl` are gases which can EASILY ESCAPE and leave behind `CH_(3)COCl` as a RESIDUE.
`CH_(3)COOH+SOCl_(2)toCH_(3)COCl+HCl uarr+SO_(2)uarr`
13.

Label the hydrophilic and hydrophobic parts in the following compounds. (i) CH_(3)(CH_(2))_(10)CH_(2)OSoverset(-)(O_(2))overset(+)Na (ii) CH_(3)(CH_(2))_(15)overset(+)N(CH_(3))_(3)overset(-)Br (iii) CH_(3)(CH_(2))_(16)COO(CH_(2)CH_(2)O)_(n)CH_(2)CH_(2)OH

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SOLUTION :
14.

Label the hydrophilic and hydrophobic parts in the following compounds : (i) CH_(3)(CH_(2))_(10)CH_(2)OSO_(3)^(-)Na^(+) (ii) CH_(3)(CH_(2))_(15)-overset(+)N(CH_(3))_(3)Br^(-) (iii) CH_(3)(CH_(2))_(16)COO(CH_(2)CH_(2)O)_(n)CH_(2)CH_(2)OH

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Solution :(i) `underset("HYDROPHOBIC part")ubrace(CH_(3)(CH_(2))_(10))-underset("Hydrophilic part")ubrace(OSO_(3)^(-)Na^(+))`
(II) `underset("Hydrophobic part")ubrace(CH_(3)(CH_(2))_(15))-underset("Hydrophilic part")ubrace(overset(+)N(CH_(3))Br^(-))`
(III) `underset("Hydrophobic part")(ubrace(CH_(3)(CH_(2))_(6)))-underset("Hydrophilic part")ubrace(COO(CH_(2)CH_(2)O)_(n)CH_(2)CH_(2)OH)`
15.

Label the hydrophillic and hydrophobic parts in the following compounds: (a) CH_(3)(CH_(2))_(10)CH_(2)OSO_(3)""^(-)Na^(+) (b) CH_3 (CH_2)_(15) N^(+) (CH_3)_2 Br^(-) (c) CH_3 (CH_2)_(16) COO (CH_2 CH_2 O)_n CH_2 CH_2 OH

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SOLUTION :(a) `underset("Hydrophobic part")(CH_3 (CH_2)_(10)) underset("HYDROPHILIC part")(CH_2- OSO_3 NA)`
(B) `underset("Hydrophobic part")(CH_3 (CH_2)_(15))- underset("Hydrophilic part")(N^(+) (CH_3)_3 Br^(-))`
(c) `underset("Hydrophobic part")(CH_3 (CH_2)_(16)) - underset("Hydrophilic part")(COO (CH_2 CH_2 O)_n CH_2 CH_2 OH)`
16.

Label the sterogenic center in each biologically active compound as R orS.

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ANSWER :(a) S (B) S ( C) R
17.

Label the hydrophilic and hydrophobic parts in the following compounds. (a)CH_3(CH_2)_10CH_2OSO_3^(-)Na^+ , (b)CH_3(CH_2)_15-overset+N(CH_3)_3Br^- , (c ) CH_3(CH_2)_16COO(CH_2CH_2O)_n CH_2CH_2OH

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Solution :(a)`ubrace(CH_3(CH_2)_10CH_2)_"Hydrophobic"-ubrace(OSO_3^(-)Na^(+))_"Hydrophilic PART"`
(b)`ubrace(CH_3(CH_2)_15)_"Hydrophobic part"-ubrace(overset+N(CH_3)_3Br^-)_"Hydrophilic part"`
(c )`ubrace(CH_3(CH_2)_16)_"Hydrophobic part"-ubrace(COO(CH_2CH_2O)_nCH_2CH_2OH)_"Hydrophilic ACID"`
18.

Label the following as, E, Z isomers.

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SOLUTION :ECLIPSED < PARTIALLY eclipsed < SKEW < staggard.
19.

(a) Complete the following chemical equations : (i) MnO_(4)^(-) (aq) + S_(2)O_(3)^(2-) (aq) + H_(2)O(l) to (ii)Cr_(2)O_(7)^(2-)(aq)+Fe^(2+) (aq) + H^(+) (aq) to (b) Explain the following observatons : (i) La^(3+) (Z = 57) and Lu^(3+) (Z = 71) do not show any colour in solutions. (ii) Among the divalent cations in the first series of transition elements, manganese exhibits the maximum paramagnetism. (iii) Cu^(+) ion is not known in aqueous solutions.

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SOLUTION :Configurationof `La^(3+) is 4F^(0)` and that of `Lu^(3+) is 4f^(14)` . Due to the absence of partially FILLED f-orbitals, `La^(3+)` and `Lu^(3+)` do not SHOW any colour in solution.
20.

Label each stereogenbic center as R or S.

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ANSWER :(a) S (B) R ( C) R (d) R `(##GRB_CHM_ORG_HP_C02_E01_313_A01##)`
`(##GRB_CHM_ORG_HP_C02_E01_313_A02##)` (G) S `(##GRB_CHM_ORG_HP_C02_E01_313_A03##)`
21.

La^(3+)(Z=57) and Lu^(3+)(Z=71) do not show any colour in solutions.

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Solution :CONFIGURATIONOF `La^(3+) is 4f^(0)` and that of `LU^(3+) is 4f^(14)` . Due to the ABSENCE of partially filled f-orbitals, `La^(3+)` and `Lu^(3+)` do not show any colour in solution.
22.

La (lanthanum) having atomic number 57 is a member of :

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s-block elements
p-block elements
d-block elements
f-block elements

Answer :C
23.

La^(3+) and Lu^(3+) ions exhibit ________ property.

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SOLUTION :DIAMAGNETIC
24.

La ^(3+) is isoelectronic with

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`TB ^(3+)`
`Eu^(3+)`
`CE ^(4+)`
`Sm^(3+)`

Answer :C
25.

l high temperature the amount of sodium formed in the Castner process decreases due to

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Sodium metal HIGH densit
Sodium metal dissolves in fused NaOH
High electrode potential
Low JONISATION potential

ANSWER :B
26.

Kwashiorkor is caused by the deficiency of-

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vitamins
hormones
AMINO acids
essential amino acids

Answer :D
27.

K_(w) of H_(2)O at 373 K is 1 xx 10^(-12). Identify which of the following is/are correct

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`pK_(w)` of `H_(2)O` is 12
pH of `H_(2)O` is 6
`H_(2)O` is neutral
`H_(2)O` is acidic

Solution :`pK_(w) = -logK_(w) - log 1 xx 10^(-12) = 12`
`RARR K_(w) = [H^(+)][OH^(-)] = 10^(-12)`
`[H^(+)] = [OH^(-)] rArr`
`[H^(+)]^(2) = 10^(-12), [H^(+)] = 10^(-6), pH = -log [H^(+)] = -log 10^(-6) = 6`
`H_(2)O` is neutral because `[H^(+)] = [OH^(-)]` at 373 K even when pH = 6
(d) Is not correct at 373 K. Water cannot become acidic.
28.

Kwashiorkar is caused by the deficiency of:

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Vitamins
Hormones
AMINO acids
Essential amino acids

Answer :C
29.

K_w=1 times 10^-14 at 25^@C Justify that statement.

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Solution :(i) Experimentally found that the concentration of `H_3O^+` in pure water is `1 times 10^-7` at `25^@C`.
(ii) SINCE the dissociation of water PRODUCES equal number of `H_3O^+ and OH^-`, the concentration of `OH^-` is also equal to `1 times 10^-7` at `25^@C`.
(ii) `therefore` The IONIC PRODUCT of water at `25^@C` is
`K_w=[H_3O^+][OH^-]`
`=[1 times 10^-7][1 times 10^-7]`
`K_w=[1 times 10^-14]`
30.

K_w represents

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IONIC PRODUCT CONSTANT of water
Solubility product of water
Equilibrium constant of water
Buffer index

Answer :A
31.

What are the possible products.

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SOLUTION :` (##KSV_CHM_ORG_P2_C15_E01_007_S01.png" WIDTH="80%">.
32.

NaNO_(2) +Dil. HCI. What are the possible products?

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SOLUTION :` (##KSV_CHM_ORG_P2_C15_E01_006_S01.png" WIDTH="80%">,
33.

K_(sp) value of Al(OH)_(3) and Zn(OH)_(2) are 8.5 xx 10^(-23) and 1.8 xx 10^(-14) respectively. If NH_(4)OH is added in a solution of Al^(3+) and Zn^(2+), which will precipitate earlier

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`AL(OH)_(3)`
`ZN(OH)_(2)`
Both together
None

Solution :Solubility of `Al(OH)_(3)` is lesser than `Zn(OH)_(2)`.
34.

K_(sp) of an electrolyte AB is 1 xx 10^(-10).[A^(+)] = 10^(-5) m, which concentration of B^(-) will not give precipitate of AB

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`5 XX 10^(-6)`
`1 xx 10^(-5)`
`2 xx 10^(-5)`
`5 xx 10^(-5)`

Solution :`K_(sp) gt` IONIC PRODUCT `1 xx 10^(-10) gt 5 xx 10^(-11)`.
35.

K_(sp) of Al(OH)_3 is 1 times10^-15 At what pH does 1.0 times 10^-3 M Al^(3+) precipitate on the addition of buffer of NH_4Cl and NH_4OH solution?

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Solution :`Al(OH)_3 LEFTRIGHTARROW Al^(3+)(aq)+3OH^- (aq)`
`K_(sp)=[Al^(3+)][OH^-]^3`
`Al(OH)_3` PRECIPITATES when
`[Al^(3+)][OH]^3 gtK_(sp)`
`(1 times10^-3)[OH^-]^3gt1 times10^-15`
`[OH]^3 GT 1 times 10^-12`
`[OH] gt1 times10^-4M`
`[OH^-]=1 times10^-4M`
`pOH=-log_10[OH^-]=-LOG( 1 times 10^-4)=4`
`pH=14-4=10`
Thus `Al(OH)_3` precipitates at a pH of 10
36.

K_(sp)of AgCl is 1.8 times 10^-10. Calculate molar solubility in 1M AgNO_3

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Solution :`AGCL(s) leftrightarrow Ag^+(aq)+Cl^-(aq)`
X= SOLUBILITY of AgCl in 1 M `AgNO_3`
`AgNO_3(s) leftrightarrow Ag^+(aq)+NO_3^- (aq)`
`[Ag^+]=x+1 approx 1M (because x lt lt 1)`
`[Cl^-]=x`
`K_(SP)=[Ag^+][Cl^-]`
`1.8 times 10^-10 =(1) (x)`
`x=1.8 times 10^-10 M`
37.

K_(sp) of AgCl at 25^(@)C is 1.782 xx10^(-10). At 35^(@)C, K_(sp) is 4.159xx10^(10). What are DeltaH^(0) and DeltaS^(0) for the reaction : AgCl(s)=Ag^(+)(aq)+Cl^(-)(aq) ?

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ANSWER :`(DeltaH^(0)=64.6555 KJ, DELTA S^(0)=30.3 J)`
38.

K_(sp) of AI(OH)_3 is 1xx10^(-15) M. At what pH does 1.0xx10^(-3) M AI^(3+)precipitate on the addition of buffer of NH_4 CI and NH_4 OH solution.

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Solution :`AI(OH)_3 hArr AI+_((aq))^(3+)+3OH_((aq))^(-)`
`[K_(sp)=pAI^(3+)][OH^-]^3`
`AI(OH)_3` precipitates when
`[AI^(3+)][OH^(-)]^3 GT K_(sp)`
`[1xx10^(-3)][OH^(-)]^3 gt 1xx10^(-15)`
`[OH]^3 gt 1xx10^(-12)`
`[OH^-] gt 1xx10^(-4) M`
`[OH^-]=1xx10^(-4) M`
`POH=-log_(10)[OH^-]`
`=-LOG[1xx10^(-4)]=4`
`PH=14-4=10`
Thus, `AI(OH)_3` precipitates at a `pH of 10.`
39.

K_sp of AgCl at 18^@C is 1.8 xx 10^-10. If Ag^+ of solution is 4 xx 10^-3 mol/litre. The Cl^- that must exceed before AgCl is precipitated would be:

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`4.5xx10^(-8)` mol/lit
`7.2xx10^(-13)` mol/lit
`4XX10^(-3)` mol/lit
`4.5xx10^(-7)` mol/lit

Answer :A
40.

K_(sp) of Ag_2CrO_4 is 1.1 times 10^-12. What is solubility of Ag_2CrO_4 in 0.1 M K_2CrO_4.

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Solution :`Ag_2CrO_4 leftrightarrow 2Ag^+ +CrO_4^(2-)`
x 2X x
x is the solubility of `Ag_2CrO_4` in 0.1 M `K_2CrO_4`
`K_2CrO_4 leftrightarrow 2K^+ + CrO_4^(2-)`
0.1 M 0.2 M 0.1 M
`[Ag^+]=2x`
`[CrO_4^(2-)]=(x+0.1) APPROX 0.1 therefore x lt lt 0.1`
`K_(sp)=[Ag^+]^2 [CrO_4^(2-)]`
`1.1 TIMES 10^-12=(2x)^2 (0.1)`
`1.1 times 10^-12=0.4x^2`
`x^2=(1.1 times10^-12)/0.4`
`x=sqrt((1.1 times10^-12)/0.4)`
`x=sqrt(2.75 times10^-12)`
`x=1.65 times 10^-6 M`
41.

K_(sp) of AgCI is1.8xx10^(-10). Calculate molar solubility in 1M AgNO_3.

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SOLUTION :`AgCI_((s))HARR Ag_((aq))^(+)+CI_((aq))^(-)`
`x="solubility of in " 1M AgNO_3`
`AgNO_(3(aq)) hArr underset(1M)(Ag_((aq))^(+))+underset(1M)(NO_(3(aq))^-)`
`[AG^+]=x+1 cong 1M (because x ltlt 1)`
`[CI^-]=x`
`K_(sp)=[Ag^+][CI^-]`
`1.8xx10^(-10)=(1)(x)`
`x=1.8xx10^(-10)M`.
42.

K_(sp) of Ag_2 CrO_4 is 1.1xx10^(-12). What is solubility of Ag_2 CrO_4 in ox.1M K_2 CrO_4.

Answer»

Solution :`Ag_2 CrO_4 hArr 2AG^(+)+CrO_(4)^(2-)`
x is the solubility of `Ag_2 CrO_4` in `0.1 M K_2 CrO_4`
`UNDERSET(0.1M)(K_2 CrO_4) hArr underset(0.2 M)( 2K^+)+underset(0.1 M)(CrO_(4)^(2-))`
`[Ag^+]=2x`
`[CrO_(4)^(2-)]=(x+0.1)=0.1""because xlt LT 0.1`
`K_(sp)=[Ag^(+)^(2)[CrO_(4)^(2-)]`
`1.1xx10^(-12)=(2x)^2(0.1)`
`1.1xx10^(-12)=0.4x^2`
`x^2=(1.1xx10^(-12))/(0.4)`
`x=sqrt((1.1xx10^(-12))/(0.4))`
`x=sqrt(2.75xx10^(-12))`
`x=1.65xx10^-5M`.
43.

K_(sp) for sodium chloride is 36 mol^(2)//"litre"^(2). The solubility of sodium chloride is

Answer»

`(1)/(36)`
`(1)/(6)`
6
3600

Solution :`{:(NaCl,hArr,NA^(+),+,Cl^(-)),(,,S,,S):}`
`K_(sp) = S^(2), S = sqrt(K_(sp)) = sqrt(36) = 6`.
44.

K_sp for sodium chloride is 36 mol^2/liter^2. The solubility of sodium chloride is :

Answer»

1/36 M
1/6 M
6 M
3600 M

Answer :C
45.

K_(sp) for sodium chloride is 36 "mol"^(2)//"litre"^(2)". The solubility of sodium chloride is

Answer»

6M
`(1)/(6)M`
`3600M`
`(1)/(36)`M

Answer :A
46.

K_(sp) for Cr(OH)_(3) is 2.7 xx 10^(-31). What is its solubility in moles/litre

Answer»

`1 XX 10^(-8)`
`8 xx 10^(-8)`
`1.1 xx 10^(-8)`
`0.18 xx 10^(-8)`

SOLUTION :`{:(Cr(OH)_(3),rarr,Cr^(+3)+,3OH^(-)),(,,x,3x):}`
`K_(sp) = x.(3x)^(3) = 27 x^(4)`
`x = 4sqrt((K_(sp))/(27)) , x = 4sqrt((2.7 xx 10^(-31))/(27))`
`x = 1 xx 10^(-8)` mole/litre.
47.

K_(sp) for Cr(OH)_3 is 2.7 times 10^-3. What is the solubility in moles/litre?

Answer»

`1 TIMES 10^-8`
`8 times 10^-8`
`1.1 times 10^-8`
`0.18 times 10^-8`

Solution :`Cr(OH)_3 to Cr^(3+)+3OH^-`
x 3x
`K_(SP)=x.(3x)^3=27x^4`
`therefore x=4sqrt(K_(sp)/27)=4sqrt((2.7 times 10^-31)/27)`
`therefore x=1 times 10^-8`
48.

K_(sp) = [A]^3 [B]^2 for the salt where A and B are the cation and anion as the case may be stands true for

Answer»

`As_2S_3`
`Ca_3(PO_4)_2`
`Bi_2S_3`
All are CORRECT

ANSWER :D
49.

K_sp = 1.2 xx 10^-5 of M_2SO_4 (M^+ is monovalent metal ion) at 298K find the maximum concentration of M^+ ions that could be attaiined in a saturated solution of this solid at 298 K.

Answer»

`3.46xx10^(-3)` M
`7XX10^(-3)` M
`2.88xx10^(-2)` M
14.4 XX 10^(-3) M

Answer :C
50.

K_s for the acid HA is 1 xx 10^-6. The value of K fo the reaction A + H_3O^+ ⇌ HA + H_2O is:

Answer»

`1xx 10^(-6)`
`1xx10^(12)`
`1xx10^(-12)`
`1xx10^(6)`

ANSWER :D