Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Isosters are compounds having similar geometry and isoelectronic species are species having the same number of electrons. The pair of species CO_(2) and NO_(2) is

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isosteric and isoelectronic
isosteric, but not isoelectronic
isoelectronic, but not isosteric
neither isosteric nor isoelectronic

Answer :A
2.

Isopropylamine can be obtained by

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`(CH_(3))_(2)C=O+NH_(2)OH to?OVERSET(LiAlH_(4))to`
`(CH_(3))_(2)CO+NH_(3) underset(Delta)overset(Ni//H_(2))to`
`(CH_(3))_(2)CH-Br+NaNH_(2)to`
`(CH_(3))_(2)CH-Br overset(NaN_(3))to?overset(LiAlH_(4))to`

SOLUTION :`NaNH_(2)` brings out DEHYDROBROMINATION to from PROPANE.
3.

Ketones can be prepared by the oxidation of which type alcohol ?

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SOLUTION :SECONDARY ALCOHOL
4.

Isopropyl chloride undergoes hydrolysis by ……

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`SN^(1)` mechanisn
`SN^(2)` MECHANISM
`SN^(1)` and `SN^(2)` mechanism
Neither `SN^(1)` nor `SN^(2)` mechanism

SOLUTION :Isopropyl being `2^(@)` ALKYL halide can undergo hydrolysis either by `S_(N)1` or `S_(N)2` reaction.
5.

Isopropyl methyl ether when treated with cold hydrogen iodide gives

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isopropyl IODIDE and methyl iodide
isopropyl ALCOHOL and methyl iodide
isopropyl alcohol and methyl alcohol
isopropyl iodide and methyl alcohol

ANSWER :B
6.

Ketones cannot be prepared by

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Rosenmud's reaction
The HYDROLYSIS of TERMINAL gen DIHALIDES
The OXIDATION of primary alcohols
All of these

Answer :D
7.

Isopropyl magnesiumbromide with dry ether an methanol gives

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`CH_(3)-underset(OH) underset(|)(CH)-CH_(2)-CH_(3) and CH_(3)-CH_(2)-MGBR`
`CH_(3)-CH_(2)-CH_(3) and CH_(3)-CH_(2)-OMgBr`
`CH_(3)-CH_(2)-CH_(3) and CH_(3) OMgBr`
`CH_(3) -underset(CH_(3)) underset(|)(CH)-CH_(3) and CH_(3) and CH_(3) OMgBr`

Answer :C
8.

Ketones can not be easily oxidised with mild oxidising agents like Tollen's reagent of Fehling's solution.

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ANSWER :F
9.

Isopropyl chloride undergoes hydrolysis by

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`SN^(-1) ` MECHANISM
`SN^(2) ` mechanism
`SN^(1)and SN^(2) `MECHANISMS
ETHER `SN^(1) "or" SN^(2) ` mechanism

Answer :D
10.

Isopropyl chloride undergoes hydrolysis by :

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`S_(N)1` MECHANISM
`S_(N)2` mechanism
`S_(N)1 and S_(N)2` mechanism
neither `S_(N)1 ` nor `S_(N)2` mechanism

Answer :C
11.

Ketones can be prepared by the oxidation of which type of alcohol ?

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SOLUTION :SECONDARY ALCOHOL
12.

Ketones can be prepared by the oxidatin of ________ (primary alcohol, Secondary alcohol)

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SOLUTION :SECONDARY ALCOHOL
13.

Write the relavant chemical equations : Isopropyl bromide to n-propyl bromide

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SOLUTION :`CH_(3)-overset(overset(Br)(|))(CH)-CH_(3) overset("Alc. KOH")RARR CH_(3)-CH=CH_(2) underset("PEROXIDE")overset(HBr)rarr CH_(3)-CH_(2)-overset(overset(Br)(|))(CH_(2))`
14.

Isopropyl amineonacetylationgives

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`(CH_(3))_(2)CH - NCOHCH_(3)`
`(CH_(3))_(2)CH-NHCOCH_(3)`
`(CH_(3))_(2)CHN(COCH_(3))_(2)`
`(CH_(3))_(2)CHN(OCH_(3))_(2)`

Answer :C
15.

Isopropyl amine can be obtained by

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`(CH_(3))_(2)CHO+NH_(2)Ohto(A)overset(LiAlH_(4))to`
`(CH_(3))_(2)CHO+NH_(3)to(A)overset(H_(2)//Ni)to`
`(CH_(3))_(2)CHOH+NH_(3)to`
none of these

Answer :A::B::C
16.

Isopropyl alcohol underset(Delta )overset(H^+ //K_2 Cr_2 O_3)tofinalproduct

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PROPENE
PROPANOL
ETHANAL
ETHANOICACID

ANSWER :D
17.

Ketones can be prepared by :

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ROSENMUND reduction
Stephen's SOLUTION
Both (a) and (B)
NONE

ANSWER :D
18.

Ketones can be obtained in one step by ,

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HYDROLYSIS of esters
oxidation of PRIMARY alcohols
oxidation of secondary alcohols
reaction of ACID unhydride and ALCOHOL .

ANSWER :C
19.

Isopropyl alcohol on passing over heated copper at 300^@C gives :

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Propylene
Acetaldehyde
Acetone
None

Answer :C
20.

Isopropyl alcohol on oxidation gives:

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Acetone
Ether
Ethylene
Acetaldehyde

Answer :A
21.

Isopropyl alcohol onoxidation forms

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ACETONE
ETHER
ACETALDEHYDE
ester

Answer :A
22.

Isopropyl alcohol is used as ………………….. For injection.

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SOLUTION :SKIN CLEANSER
23.

Isopropyl alcohol on oxidation forms

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acetone
ether
ethylene
acetaldehyde

Answer :A
24.

Ketones are prepared by:

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Clemenson's reduction
Rosenmund reduction
Oppenauer oxidation
Cannizzaro's reaction

Answer :C
25.

Isopropyl alcohol is oxidised by CrO_3 gives,

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`CH_3COCH_3`
`CH_3COOH`
`CH_3CH=CH_2`
`CH_3CHO`

SOLUTION :`(CH_3)_2CHOH + [O] OVERSET"OXIDATION"to CH_3COCH_3 + H_2O`
26.

Ketones can be obtained in one step by :

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Hydrolysis of ESTER
Oxidation of primary alcohols
Reaction of ACID halide with alcohols
Oxidation of secondary alcohol

Answer :D
27.

Isopropyl alcohol is obtained by reacting which of the following alkenes with conc. H_(2)SO_(4) and H_(2)O

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Ethylene
Propylene
2-methyl propene
Isoprene

Solution :`CH_(3)-CH=CH_(2)+H_(2)O UNDERSET("Markonifoff's rule")overset(CONC. H_(2)SO_(4))to `
`CH_(3)-underset("Isopropyl ALCOHOL ")underset(OH)underset(|)(CH)-CH_(3)`
28.

Isopropyl alcohol is heated on a water bath with the suspension of bleaching powder. Which of the following products will be formed ?

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isopropyl chloride
trichloromethane
propane
ETHANOL

SOLUTION :REFER to Haloform reaction.
29.

Explain why aldehydes are more reactive than ketones towards nucleophilic addition reactions ?

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ANSWER :F
30.

Isopropyl alcohol and n-propyl alcohol, both have the same molecular formula C_3H_8O . A solution of the two, that is, 25% isopropyl alcohol by mass, has a total vapour pressure of 0.09 atm at a given temperature. A solution of the two, that is, 75% isopropyl alcohol by mass, has a total vapour pressure of 0.12 atm at the same temperature. Find the vapour pressures of the pure alcohols at this temperature.

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SOLUTION :0.135 ATM, 0.075 atm
31.

Isopropyl alcohol and propyl alcohol are :

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POSITION isomers
Chain isomers
Functional isomers
None

Answer :A
32.

Ketones are isomeric with

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alcohols
aldehydes
ester
acetic acid

Answer :B
33.

Isoprophyl alcohol on oxidation forms

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Acetone
Ether
Ethylene
Acetaldehyde

Solution :`CH_(3)-underset(OH)underset(|)CH-CH_(3)underset(KMnO_(4))OVERSET("OXIDATION")to underset("Acetone")(CH_(3)-underset(O)underset(||)C-CH_(3))`
34.

Ketones are less reactive than aldehydes because:

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C=O group is LESS POLAR in ketones
of electromeric effect
Of STERIC hindrance to the attacking reagent
None

Answer :C
35.

Ketones are generally less reactive than Aldehydes in nucleophilic addition reactions because

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Carbonyl CARBON in ketones is sterically more PROTECTED and more electrophilic
Carbonyl carbon in ALDEHYDES is sterically more protected and more electrophilic
Carbonyl carbon in aldehydes is sterically LESS protected and less electrophilic
Carbonyl carbon in ketones is sterically more protected and less electrophilic

Answer :D
36.

Isoprene,CH_(2)=C-underset(CH_(3))underset(|)(CH)=CH_(2),is the repeating unit in:

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VITAMIN `A`
TERPENES
RUBBER (NATURAL)
All the above

ANSWER :D
37.

Isoprophylbenzene on air oxidation in the presence of dilute acid gives…………………

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`C_6H_5COOH`
`C_6H_5COCH_3`
`C_6H_5COC_6H_5`
`C_6H_5-OH`

SOLUTION :`C_6H_5-OH`
38.

Ketones and 1^(@) amine react to form

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Amides
Oximes
Urea
Schiff's BASES

ANSWER :4
39.

Isoprophlbenzene on air oxidation in the presence of dilute acid gives

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`C_(6)H_(5)COOH`
`C_(6)H_(5)COCH_(3)`
`C_(6)H_(5)CHO`
`C_(6)H_(5)OH`

Solution :ACIDIC hydrolysis of CUMENE hydropenoxide
40.

Isoprene unit present in

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terpenes
waxes
phospholipids
glycolipids

Answer :A
41.

Ketones are first oxidation product of:

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PRIMARY alcohols
Secondary alcohols
Dihydric alcohols
Tertiary alcohols

Answer :B
42.

Ketones and 1@ aminest react to form :

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AMIDES
OXIMES
Urea
Anils

Answer :D
43.

Ketone (A), which indergoes halform reaction, give compound (B) on reduction. (B) on heating with H_(2)SO_(4) gives compound (C ), which forms mono-ozonide (D). (D) on hydrolysis in the presence of Zn dust gives only acetaldehyde. Identify (A). (B), and (C ). Write down the reactions involved.

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Solution :Ketone `(A)` gives HALOFORM reaction, so it must contain `(Me-CO-)` group. Ketone on reduction gives `2^(@)` alcohol. (B), which gives alkene `(C )` with `H_(2)SO_(4)`. Alkene on ozonolysis FOLLOWED by reduction with `Zn` dust gives `MeCHO`. So, the structure of alkene `(C )` is:

So `(A)` is: Butan-`2`-one, `(B)` is: Butan-`2`-ol, `(C )` is: Butan-`2`-one.
44.

Ketone never show

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CHAIN ISOMERISM
POSITION isomerism
GEOMETRICAL isomerism
optical isomerism

ANSWER :C
45.

Ketone is the first oxidative product of,

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`1^@` ALCOHOL
`3^@` alcohol
`2^@` alcohol
acid

Answer :C
46.

Isoprene is used for making :

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RUBBER
Petrol
Liquid fuel
None

Answer :A
47.

Ketol in the following compounds is

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.
.

ANSWER :D
48.

Ketohexoses do NOT contain__________.

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`-CHO` GROUP
`-OH` group
`-CH_2OH ` group
NONE of these

ANSWER :A
49.

Keto-enol tautomerism is observed in:

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`C_(6)H_(5)-CHO`
`C_(6)H_(5)COCH_(3)`
`C_(6)H_(5)COC_(6)H_(5)`
`C_(6)H_(5)COCH_(2)COCH_(3)`

Answer :A::C
50.

Isoprene is synthetic rubber?

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SOLUTION :Buna-S is a SYNTHETIC RUBBER.