This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
C1 of alpha - D- glucoseand C_(2) of beta - D-fructoseare linked togetherto form a molecule of sucrose . |
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| 6. |
c) Write Nernst equation for the cell represented as: Mg(s)|Mg_((aq))^(+2)||Al_((aq))^(3+)|Al_((S)). |
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Answer» Solution :The cell reaction according to the cell REPRESENTATION is `[Mg|Mg^(+2)||Al^(3+)|Al]` `3Mg+2Al^(3+)rarr 3Mg^(2+)+2Al` Nernst equation for the GIVEN cell is `E_("cell")=E_("cell")^(Theta)-(0.059)/(6)log""([Mg^(2+)]^(3))/([Al^(3+)]^(2))` |
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| 7. |
(c) Why have the transition metal high enthalpy of hydration ? |
| Answer» SOLUTION :(C) Due to their small size and LARGE NUCLEAR CHARGE. | |
| 8. |
Which is more basic among aqueous solutions of aniline and ammonia ? Give one reason. |
| Answer» Solution :C) AMMONIA is more BASIC than aniline DUE to delocalisation of lone pair of electrons in the ring. | |
| 9. |
Which class of alcohols do not readily form turbidity with Lucas reagent? |
| Answer» Solution :`1^(@)` ALCOHOLS donot readily form turbidity with LUCAS REAGENT. | |
| 10. |
(c) What is the effect of lanthoids contraction beyond lanthanoid ? |
| Answer» Solution : (c) SIZE of RESPECTIVE 4d and 5d SERIES elements becomes comparable from fourth GROUP onwards (e.g., Zr and HF). | |
| 11. |
What major molecular shape does the tertiary structure of protein lead to? |
| Answer» SOLUTION :Fibrous (or globular) SHAPES are FORMED by tertiary structure of protein. | |
| 12. |
What is Zeigler-Natta catalyst? |
| Answer» SOLUTION :`TiCI_(4)` and triethyl aluminium is known as Zeigler-Natta CATALYST | |
| 13. |
What is the effect of a catalyst on DeltaG of a reaction? |
| Answer» SOLUTION :CATALYST has no EFFECT on `DELTAG` of a REACTION. | |
| 14. |
(C) turns lime water milky which disappears on continuous passage of (C) forming a compound (F). Identify (A) to (F) and give chemical equations for the reactions at step (i) to (iv). |
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| 15. |
Molar conductivities (Lambda_(m)^(@)) at infinite dilution of NaCl, HCl and CH_(3)COONa arc 126.4, 425.9 and 91.0 S cm^(2) mol^(-1) respectively. Lambda_(m)^(@) for CH_(3)COOH will be |
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Answer» SOLUTION :`Lambda_(m)^(@)CH_(3)COOH=LAMBDA^(@)CH_(3)COONa+Lambda^(@)HCl-Lambda^(@)NaCl` `=91.0+425.9-126.4` `="390.5 cm"^(2)"MOL"^(-1)` |
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| 16. |
c) Resistance of a conductivity cell containing 0.1 M KCl solution is 100Omega. Cell constant of the cell is 1.29/cm. Calculate the conductivity of the solution at the same temperature. |
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Answer» SOLUTION :Given Resistance `=100Omega` Cell constant `=1.29//cm` To find conductivity of the cell we have the formula `K=("Cell constant")/("RESISTANT")` `K=(1.29)/(100)=1.29xx10^(-2)SCM^(-1)` |
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| 17. |
C+O_(2)rarrCO_(2), DeltaH=XCO+(1)/(2)O_(2)rarrCO_(2),DeltaH=YThen the heat of formation of CO is |
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Answer» X-Y |
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| 18. |
C-O-C bond in ethers can be cleaved by |
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Answer» `KMnO_(4)` |
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| 19. |
C-O-C bond angle in ether is more than H-O-H bond angle in water although oxygen is sp^(3) hybridised in both the cases. Explain |
| Answer» Solution :DUE to BIGGER size of ALKYL groups, there are repulsive interactions present. | |
| 20. |
C-O bond length in phenol is less than C-O bond length in methyl alcohol because |
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Answer» partial double bond CHARACTER DUE to resonance |
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| 21. |
C-O bond in ether is not cleaved by |
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Answer» HCI |
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| 22. |
Name the final product of ammonolysis of an alkyl halide. |
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Answer» Solution :The process of cleavage of the C-X bond of HALO alkane by AMMONIA is called ammonolysis. This reaction is carried out in a sealed vessel at 373 K. `underset(1^(@)" amine")(R-NH_(2))OVERSET(R-X)rarr underset(2^(@)-" amine")(R_(2)-NH)overset(R-X)rarr underset(3^(@)" amine")(R_(3)-NH) overset(R-X)rarr underset("ammonium SALT")underset("Quaternary")(R_(4)-N^(+)H^(-))` The final product of ammonolysis of an ALKYL halide is quaternary ammonium slat. |
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| 23. |
Name the enzyme that catalyses the reaction: H_(2)NCONH_(2)+H_(2)Orarr2NH_(3)+CO_(2). |
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Answer» Solution :The enzyme that USED in this reaction is urease `NH_(2)CONH_(2)+H_(2)O overset("urease")rarr 2NH_(3)+CO_(2)` |
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| 24. |
Name the base present only in DNA but not in RNA. |
| Answer» SOLUTION :c) The BASE present only in DNA but not in RNA is Thymine. | |
| 25. |
c) Molecular mass of polymers are expressed as an average. Give reason |
| Answer» Solution :MOLECULAR mass of POLYMERS are expressed as an average because polymers contains CHAINS of different lengths. | |
| 26. |
C is |
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| 27. |
c) For the reaction, H_(2)+I_(2)rarr 2HI, the rate of disappearance of H2 is 1xx10^(-4)Ms^(-1). What is the rate of appearance of HI. |
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Answer» Solution :Rate EXPRESSION for the reaction `H_(2)+I_(2)rarr2HI` is `-(Delta[H_(2)])/(Deltat)=-(Delta[I_(2)])/(Deltat)=(1)/(2)([HI])/(Deltat)"…(1)"` Given that `-(Delta[H_(2)])/(Deltat)="Rate "=1xx10^(-4)MS^(-1)` SUBSTITUTE in the equation (1) Rate of appearance will be equal to rate of disappearance `-(Delta[H_(2)])/(Deltat)=(1)/(2)(Delta[HI])/(Deltat)` `1xx10^(-4)=(1)/(2)(Delta[HI])/(Deltat)` `2(1xx10^(-4))=(Delta[HI])/(Deltat)="Rate "=2xx10^(-4)ms^(-1)` Rate of appearance of `HI` is `2xx10^(-4)ms^(-1)` |
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| 28. |
Fluorine does not exhibit positive oxidation state. Why? |
| Answer» Solution :FLUORINE does not EXHIBIT positive oxidation STATE because it is the most electronegative element. | |
| 29. |
C electricity deposits |
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Answer» 10.8 G of AG mass W= Z.Q whenQ = 1C w=Z = electrochemical equivalent |
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| 30. |
C (diamond) +O_(2)(g)rarrCO_(2)(g), DeltaH-395 kJC (graphite) +O_(2)(g)rarrCO_(2)(g), DeltaH-393.5 kJ From the data, the DeltaH when diamond is formed from graphite, is |
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Answer» `-1.5 kJ` |
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| 31. |
C-COOH overset(NH_(3).Heat)toA overset(Br_(2)+KOH)toB overset(HONO)toC. The compound ‘C' is |
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| 32. |
C Cl_(4) is used as a fire extinguisher, because |
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Answer» its boiling point is low |
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| 33. |
C Cl_(4)+H_(2)overset(Fe)underset(H_(2)O)rarr (A)+HClThe product (A) is ……. |
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Answer» `CH_(2)Cl_(2)` |
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| 34. |
C Cl_4 does not give a precipitate with AgNO_3 be because |
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Answer» It FORMS COMPLEX with `AgNO_3` |
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| 35. |
C Cl_3CH=CH_2overset(Cl_2H_2O)rarrA. A is : |
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Answer» `HC Cl_3underset(OH)UNDERSET(|)C=CH_2Cl` |
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| 36. |
C Cl_3 is used as…………….. |
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Answer» SOIL STERILIZING agent |
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| 37. |
C CI_(4) and freons |
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Answer» are geencompoundsbecausethey aregreencoloured |
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| 38. |
c) Calculate the pH of an aqueous solution obtained by mixing 50 ml of 0.2 M HCI with 50 ml 0.1 M" " NaOH. |
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Answer» Solution :No. of moles of HCI `=0.2 xx50xx10^(-3)` `=10xx10^(-3)` No. of moles of NAOH `=0.1 xx50xx10^(-3)` `=5xx10^(-3)` No. of moles of HCI after MIXING `=10xx10^(-3)-5xx10^(-3)` `5xx10^(-3)` after mixing total VOLUME `= 100` mL `therefore` Concentration of HCI in moles per litre `=(5xx10^(-3)"Mole")/(100xx10^(-3) L)` `[H_3 O^+]=5xx10^(-2) M` `pH=-log (5xx10^(-2))` `=2-log5` `=2-0.6990` `=1.30`. |
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| 39. |
The C - C bond length of benzene is _____. |
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Answer» `1.54overset@A` |
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| 40. |
c) Between which is an allylic chloride? |
Answer» SOLUTION :
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| 41. |
c) Between t_(2g) and e_(g) sets of d-orbitals of a central metal in an octahedral complex, which set has higher energy? |
Answer» Solution :In octahedral COMPLEX the central metal ion, surrounded.by 6 ligands. The REPULSION is more when the metal d-orbital directed TOWARDS the ligand and less when it is away from the ligands. So `d_(x^(2)-y^(2)) and d_(z^(2))` orbitals are towards the ligand. Hence they EXPERIENCE more repulsion and will be raised in energy. So they forin eq set
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| 42. |
C and Si belong to group 14. The maximum coordination numberof carbon in commonly occurring compounds in 4, whereas that of silicon is 6. This is due to : |
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Answer» Large SIZE of silicon |
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| 43. |
C-6 H_5 CH=CH-CHO is |
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Answer» Benzaldehyde |
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| 44. |
C - 14 is used in carbon dating of dead objects because |
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Answer» Its half-life is `10^(3)` years |
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| 45. |
C-12 and C-14 isotopes are found as 98% and 2% respectively in any sample. Number of atoms of C-14 in 12 g of sample will be |
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Answer» 1.5 MOLE ATOMS ` = (12 xx 2)/(100 xx 14) xx 6.02 xx 10^23 =1.032 xx 10^22` |
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| 46. |
Byavais lattices are of |
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Answer» 10 TYPES |
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| 47. |
ByWurtz reaction, amixtureof methyl iodineand ethyliondinegives : |
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Answer» Propane |
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| 49. |
By which reagent the diethyl ether is dissociate at high temperature ? |
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Answer» Water |
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