Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

The process of getting freshwater from sea water is known as:

Answer»

Osmosis
Filtration
Diffusion
Reverse Osmosis

Answer :D
2.

The process of froth floatation and chromatography are based on :

Answer»

Emulaification
Adsorption
Absorption
Either of them

Answer :D
3.

The process of formation of RNA from DNA is known as :

Answer»

Translation
Transcription
Replication
Mutation

Answer :A
4.

The process of extraction of sodium on a commercial scale by the electrolysis of fused sodium chloride is called :

Answer»


ANSWER :A
5.

The process of extracting the metal from its ore is called :

Answer»

REFINING
CONCENTRATION
LEACHING
METALLURGY

ANSWER :D
6.

The process of evaporation of a liquid is accompanied by:

Answer»

INCREASE in enthalpy
Decrease in FREE energy
Increase in entropy
All

Answer :D
7.

The process of eudiometry is used to calculate the volume of the various reacting gases present together in a closed vessel, it is done by sparking the content and noting the volume change or pressure change depending upon the conditions mentioned. Various reagents like alkaline pyrogallol, turpentine oil, caustic potash, conc. H_(2)SO_(4) are used to absorb theselective gases like O_(2), O_(3), CO_(2) and H_(2)O (v) respectively. A 2.0 mole mixture of H_(2)(g),O_(2)(g) and He(g) are placed together in a closed container at pressure equal to 50 atm. An electric spark is passed and pressure is noted as 12.5 atm after cooling the content to original temp. (room temp). Oxygen gas is introduced for pressure to change to 25 atm, keeping volume and temp constant. Again electrical spark is passed and pressure drops to 10 atm under original temp. conditions. The mole fraction of H_(2)(g) present in the initial mixture is:

Answer»

0.05
0.7
0.5
1.25

Solution :Let the no. of moles of `H_(2),O_(2)` and He are x,y and z respectively
`therefore x+y+z=20`
Pressure exerted by 2 moles of gaseous MIXTURE is 50 atm.
After the first electric spark decrease in pressure =50-12.5=37.5 atm
`therefore` decrease in no. of moles of gaseous mixture is 1.5
But from the given information limiting reagent in first step is `O_(2)`
`therefore" from "H_(2)(g)+(1)/(2)O_(2)(g) RARR H_(2)O(l)`
`therefore H_(2) and O_(2)` REACTED are in the ratio of 2:1
`therefore` 0.5 mole of `O_(2)` should be reacted with 1.0 mole of `H_(2)`
`therefore` No. of mole of `O_(2)` in the mixture (y) =0.5
When again `O_(2)` is passed, pressure increased from 12.5 to 25.0 atm
`therefore` Change in pressure =12.5 atm
`therefore` No. of moles of `O_(2)` added `=(12.5xx2)/(50)=0.5` mole
Now `H_(2)` will be completely reacted
No. of moles `H_(2)` actually left after first electric spark =x-1
`H_(2)+(1)/(2)O_(2) rarr H_(2)O`
`(x-1)((x-1)/(2))`
Now change in pressure in 25-10 =15 atm
`therefore` change in no. of moles is `(15xx2)/(50)=0.6`
`therefore (x-1)+((x-1)/(2))=0.6`
`rArr x=1.4`
`therefore` no of moles `H_(2)=1.4`
`therefore` no. of moles of `He=2.0-(1.4+0.5)=0.1`
`therefore` mole fraction of `H_(2)=(1.4)/(2.0)=0.7`
8.

The process of eudiometry is used to calculate the volume of the various reacting gases present together in a closed vessel, it is done by sparking the content and noting the volume change or pressure change depending upon the conditions mentioned. Various reagents like alkaline pyrogallol, turpentine oil, caustic potash, conc. H_(2)SO_(4) are used to absorb theselective gases like O_(2), O_(3), CO_(2) and H_(2)O (v) respectively. A 2.0 mole mixture of H_(2)(g),O_(2)(g) and He(g) are placed together in a closed container at pressure equal to 50 atm. An electric spark is passed and pressure is noted as 12.5 atm after cooling the content to original temp. (room temp). Oxygen gas is introduced for pressure to change to 25 atm, keeping volume and temp constant. Again electrical spark is passed and pressure drops to 10 atm under original temp. conditions. The moles of O_(2)(g) introduced in the vessel after first electrical spark is :

Answer»

0.25
0.5
0.1
0.2

Solution :Let the no. of moles of `H_(2),O_(2)` and He are x,y and z respectively
`therefore x+y+z=20`
Pressure exerted by 2 moles of gaseous mixture is 50 atm.
After the first electric spark DECREASE in pressure =50-12.5=37.5 atm
`therefore` decrease in no. of moles of gaseous mixture is 1.5
But from the given information limiting reagent in first STEP is `O_(2)`
`therefore" from "H_(2)(G)+(1)/(2)O_(2)(g) rarr H_(2)O(l)`
`therefore H_(2) and O_(2)` reacted are in the ratio of 2:1
`therefore` 0.5 MOLE of `O_(2)` should be reacted with 1.0 mole of `H_(2)`
`therefore` No. of mole of `O_(2)` in the mixture (y) =0.5
When again `O_(2)` is passed, pressure increased from 12.5 to 25.0 atm
`therefore` Change in pressure =12.5 atm
`therefore` No. of moles of `O_(2)` added `=(12.5xx2)/(50)=0.5` mole
Now `H_(2)` will be completely reacted
No. of moles `H_(2)` actually left after first electric spark =x-1
`H_(2)+(1)/(2)O_(2) rarr H_(2)O`
`(x-1)((x-1)/(2))`
Now change in pressure in 25-10 =15 atm
`therefore` change in no. of moles is `(15xx2)/(50)=0.6`
`therefore (x-1)+((x-1)/(2))=0.6`
`rArr x=1.4`
`therefore` no of moles `H_(2)=1.4`
`therefore` no. of moles of `He=2.0-(1.4+0.5)=0.1`
`therefore` mole fraction of `H_(2)=(1.4)/(2.0)=0.7`
9.

The process of eudiometry is used to calculate the volume of the various reacting gases present together in a closed vessel, it is done by sparking the content and noting the volume change or pressure change depending upon the conditions mentioned. Various reagents like alkaline pyrogallol, turpentine oil, caustic potash, conc. H_(2)SO_(4) are used to absorb theselective gases like O_(2), O_(3), CO_(2) and H_(2)O (v) respectively. A 2.0 mole mixture of H_(2)(g),O_(2)(g) and He(g) are placed together in a closed container at pressure equal to 50 atm. An electric spark is passed and pressure is noted as 12.5 atm after cooling the content to original temp. (room temp). Oxygen gas is introduced for pressure to change to 25 atm, keeping volume and temp constant. Again electrical spark is passed and pressure drops to 10 atm under original temp. conditions. The moles of He (g) present in the mixture samples is

Answer»

0.2
0.1
0.5
1.4

Solution :Let the no. of moles of `H_(2),O_(2)` and He are x,y and z respectively
`therefore x+y+z=20`
Pressure EXERTED by 2 moles of gaseous MIXTURE is 50 atm.
After the FIRST electric spark decrease in pressure =50-12.5=37.5 atm
`therefore` decrease in no. of moles of gaseous mixture is 1.5
But from the given information limiting reagent in first step is `O_(2)`
`therefore" from "H_(2)(g)+(1)/(2)O_(2)(g) rarr H_(2)O(l)`
`therefore H_(2) and O_(2)` reacted are in the ratio of 2:1
`therefore` 0.5 MOLE of `O_(2)` should be reacted with 1.0 mole of `H_(2)`
`therefore` No. of mole of `O_(2)` in the mixture (y) =0.5
When again `O_(2)` is passed, pressure increased from 12.5 to 25.0 atm
`therefore` Change in pressure =12.5 atm
`therefore` No. of moles of `O_(2)` added `=(12.5xx2)/(50)=0.5` mole
Now `H_(2)` will be completely reacted
No. of moles `H_(2)` actually left after first electric spark =x-1
`H_(2)+(1)/(2)O_(2) rarr H_(2)O`
`(x-1)((x-1)/(2))`
Now change in pressure in 25-10 =15 atm
`therefore` change in no. of moles is `(15xx2)/(50)=0.6`
`therefore (x-1)+((x-1)/(2))=0.6`
`rArr x=1.4`
`therefore` no of moles `H_(2)=1.4`
`therefore` no. of moles of `He=2.0-(1.4+0.5)=0.1`
`therefore` mole fraction of `H_(2)=(1.4)/(2.0)=0.7`
10.

The process of employed for the concentration of sulphide ore is

Answer»

Froth-floatation
Roasting
Electrolysis
Calcination

Answer :A
11.

The process of covering iron sheet with a layer of zinc is called:

Answer»

Galvanizing
Zinc plating
Tempering
Rusting

Answer :A
12.

The process of converting precipitate into colloidal solution on adding an electrolyte is called

Answer»

Peptisation
Dialysis
Electro-osmosis
Electrophoresis

Solution :The conversion of a FRESH PPT. into colloidal STATE by ADDITION of small amount of a suitable electrolyte is called peptization e.g.

i.e., ions are adsorbed on particles to give colloidal SIZE.
13.

The process of converting hydrated alumina to anhydrous alumina is called

Answer»

Calcination
Smelting
Rosting
Concentration

Answer :A
14.

The process of converting hydrated alumina into anhydrous alumina is called :

Answer»

Roasting
Smelting
Dressing
Calcination

Answer :D
15.

The process of converting alkyl halides into alcohols involves _________reaction.

Answer»

addition
substitution
dehydrohalogenation
rearrangement

Answer :B
16.

The process of converting alkyl halides into alcohols involves_____

Answer»

ADDITION reaction
substitution reaction
dehydrohalogenation reaction
rearrangement reaction.

Answer :B
17.

The process of converting alkyl halide into alcohols involves .........

Answer»

ADDITION reaction
SUBSTITUTION reaction
Dehydrohalogenation reaction
Rearrangement reaction

Solution :`R- X OVERSET(NaOH)to R- OH+ NAX`
18.

The process of converign one enatiomer of an optically active compound inot racemic mixture is called:

Answer»

Resolution
Inversion
Epimerisation
Racemission

Solution :NA
19.

The process of conversion of colloidal solution into precipitate is called .............

Answer»

SOLUTION :COAGULATION
20.

The process of conversion of colloidal solution into precipitate is known as .....

Answer»

PEPTISATION
dispersion
COAGULATION
decomposition

Solution :coagulation
21.

The process ofconcentrating silver are is based on its solubility in :

Answer»

HCL
`HNO_3`
KCN
NaoH

Answer :C
22.

What is the method of concentrating iron pyrite ore?

Answer»


ANSWER :C
23.

The process of combining metals present in their native ores with mercury to form an alloy is called

Answer»

ALLOYING
GALVANISATION
amalgamation
crystallisation

Answer :C
24.

The process of calcination and roasting are carried out in:

Answer»

BLAST furnace
Muffle furnace
Reverberatory furnace
Open HEARTH furnace

Answer :C
25.

The process of AgCN+KCNtoK[Ag(CN)_(2)] involves the oxidation of Ag.

Answer»


SOLUTION :The OXIDATION NUMBER is not CHANGING for AG.
26.

The process of bringing the metal or its ore into solution by the action of a suitable chemical reagnetfollowing by extraction of the metal either by electrolysis or by suitable precipitating agentis called

Answer»

Electrometallurgy
Electro-refining
Hydrometallurgy
Zone-refining

Answer :C
27.

The process of a protein, losing its higher order structure without losing the primary structure is called……………..

Answer»

SOLUTION :DENATURATION
28.

The process involving reduction of metal oxide with coke or carbon monoxide is called………..

Answer»

SOLUTION :SMELTING
29.

The process is spontaneous at the given temperature, if

Answer»

`Delta H" is " +ve and Delta S " is " -ve`
`Delta H " is " -ve and Delta S " is " +ve`
`Delta H " is " +ve and Delta S " is " +ve`
`Delta H "is " and DeltaS` is EQUAL to zero.

Solution :`Delta G = Delta H - T Delta S` (Gibbs ENERGY EQUATION)
When, `Delta H` is -ve, but `T Delta S` is `+ve rarr Delta G` will be (-ve) [Highly spontaneous].
30.

The process involving transfer of five electrons is:

Answer»

`CrO_4^(2-) rarrCr^(3+)
`MnO_4^- rarrMn^(2+)`
`MnO_4^- rarrMnO_2`
`Cr_2O_7^(2-) rarr2Cr^(3+)`

ANSWER :A
31.

The process involving heating of rubber with sulphur is called

Answer»

galvanisation
VULCANIZATION
bessemerisation
sulphonation.

Solution :Vulcanization
32.

The process involving heating of natural rubber with sulphur is known as:

Answer»

VULCANISATION
GALVANISATION
SULPHONATION
BESSEMERISATION

Answer :B
33.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. Which one of the following statements is correct regarding the experiment ?

Answer»

First of all YELLOW ppt. will appear
First of all black ppt. will appear
Appearance of yellow ppt. and black ppt. will OCCU simultaneously
Cannot be PREDICTED

Answer :A
34.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. In experiment -2what % of the metal ions get precipitated at which S^(2-) get saturated with another ion ?

Answer»

`10%`
`80%`
`20%`
`90%`

ANSWER :A
35.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. In experiment 02, what is the maximum concentration of S^(2-)ion at which one of the two metal ions gets maximum precipitation ?

Answer»

`10^(-8)` M
`2 XX 10^(-7)M`
`2 xx 10^(-9)M`
None

Answer :A
36.

The process in which the concentrated ore is strongly heated in the absence of air is called as………

Answer»

Roasting
Calcination
Smelting
Leaching

Answer :B
37.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. What %of the (ion) will get precipitate when the second ion start precipitating in experiment -1 ?

Answer»

`10%`
`90%`
`1%`
`99%`

ANSWER :D
38.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. What percent of the anions Br^(-) and I^(-) get precipitated respectively when the third ion starts precipitating in experiment -1 ?

Answer»

`90%,99.9%`
`99.9%,90%`
`80%,90%`
`90%,80%`

ANSWER :A
39.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. Which of the following will precipitate first in experiment -1 ?

Answer»

`I^(-)`ION<BR>`Br^(-)` ion
`CL^(-)` ion
cannot be predicted

Answer :A
40.

The process in which solution containing more than one typeof ions (either cation or anion) and in which one ion undergoes almst complete precipitation followed by the second ion and similarly second ion undergoes complete precipitation followed by the third ion is known as preferentialprecipitation. It is the solubility of the salt,not the solubility product of the salt, by means of which one can predict the preferential precipitation of the salt or ion among the lot of ions in the solution. For example , in a solution containing Cl^(-), Br^(-) and I^(-) ions, if Ag^(+) ions are added, then out of three , the less soluble salt is precipitated first . If the addition of Ag^(+) ions is continued, eventually , a stage is reached when the next lesser soluble salt starts precipitating along with the least soluble salt and so on. If the stiochiometry of the salt is same, then the salt with the minimum K_(sp) ( solubility product ) will have minimum solubility and will precipitate first, followed by the salt of next higher solubility product and so on. If the stiochiometry of teh salt is not same, then from the solubility product data alone, we cannot predict which ions will precipitate first. For example, a solution containing Cl^(-) and CrO_(4)^(2-). In order to predict which ion will precipitate first, we have to calculate the amount of Ag^(+) ions needed to start precipitation through the solubility productdata given. When AgNO_93) is added to the solution, the minimum of the two concentrations needed to start the precipitation will be reached and thus corresponding [Ag^(+)] to start the precipitation increases. Its concentration eventually becomes equal to the value required for CrO_(4)^(2-) . At this stage, practically almost the whole of Cl^(-) ions get precipitated . Addition of more AgNO_(3) causes simultaneous precipitation of both the ions together. Suppose a student of chemistry performs the following two sets of experiments in order to known the preferential precipitation of ions as well as its precipitated percentage amount. Experiment 1. He prepare a solution of anions composed of 0.1 M each of Cl^(-),Br^(-) and I^(-) . Further he adds gradually solid AgNO_(3) to this solution. He assumes thatvolume of the solution does not change after the addition of solid AgNO_(3)(K_(sp)AgCl=1.0 xx 10^(-9)M^(2),K_(sp) AgBr=10^(-10)M^(2) and K_(sp) AgI=10^(-12)M^(2)) Experiment -2. He prepares a solution of cations Cd^(2+)(0.2 M) and Bi^(3+) (0.3 m) . Now he adds S^(2-) ions into the solution of cations in order to separate them by selective precipitationCd^(2+) forms yellow precipitate of CdSand Bi^(3+) forms black precipitate of Bi_(2)S_(3) with S^(2-) ions respectively. (K_(sp)Bi_(2)S_(3) = 9 xx 10^(-25) M^(5) and K_(sp)CdS =2 xx 10^(-20)M^(2)).Answer the following questions ont he basis of the above write up. Which of the following is the correctorder of appearance of coloour of the precipitate in experiment ?

Answer»

YELLOW `GT` PALE yellow `gt` CURDY white
yellow `LT` pale yellow `lt` curdy white
pale yellow `gt` yellow `lt` curdy white
pale yellow `gt` yellow `gt` curdy white

Answer :A
41.

The process in which pressure remains constant throughout a change is:

Answer»

Adiabatic
Isochoric
Isobaric
Isothermal

Answer :C
42.

The process, in which no heat enters or leaves the system, is termed as

Answer»

Isochoric
Isobaric
Isothermal
ADIABATIC

Solution :For adiabatic process q = 0. If a process is CARRIED out under such a condition that no EXCHANGE of HEAT takes place between the SYSTEM and surroundings, the process is termed adiabatic. The system is thermally isolated i.e., dQ=0. In adiabatic process, the temperature of the system varies.
43.

The process in which metalsurface is madeinactiveis called

Answer»

passivation
galvanising
CORROSION
pickling

SOLUTION :Passivation is the process in which metal surfaceis MADE INACTIVE
44.

The process in which metal surface is made inactive is called

Answer»

PASSIVATION
Galvanizing
CORROSION
Pickling

Solution :Passivation: A/c to DEFINITION
45.

The process in which higher hydrocarbons are broken down into lower hydrocarbons by controlled pyrolysis, is called

Answer»

Hydrolysis
Cracking
Oxidation
Reduction

Answer :B
46.

The process in which chemical change occurs on passing electricity is termed as __________.

Answer»

neutralisation
hydrolysis
electrolysis
ionisation

Answer :C
47.

The process in which chemical change occurs on passing electricity is termed:

Answer»

Ionisation
neutralisation
electrolysis
hydrolysis

Answer :C
48.

The process in which chemical change accompanies the passage of current is called :

Answer»

CONDUCTION
Metallic conduction
ELECTROLYTIC conduction
NON- electrolytic condution

Answer :C
49.

The process in which lighter earthy particles are freed fromthe heavier particle by washing with water is called :

Answer»

LEACHING
LEVIGATION
LIQUATION
GRAVITY separation

Answer :B
50.

The process (es) by which lighter earthy particles are freed from the heavier particles using water is / are :

Answer»

GRAVITY SEPARATION method
Levigation
Hydraulic washing
Leaching

Answer :A::B::C