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`EtOEt UNDERSET(/_\)OVERSET(NaOH)rarrEtONa+EtOH`
`EtOEtunderset(/_\)overset(EtNa)rarrCH_(2)=CH_(2)+CH_(3)CH_(3)`
`EtOEtunderset(underset(""KCNS)(2)FeSO_(4))overset((1) "air HV")rarr"Red colour"`
`EtOEt+Counderset(/_\)overset(BF_(3))rarr Et-overset(O)overset(||)C-O-Et`

It is diamagnetic in nature
It is shows optical isomerism
It is shows geometrical isomerism
It has four `N-Zn-O` bond angles

`{:(CH_(2)-NH_(2)),("|"),(CH_(2)-NH_(2)):}`
CONTAINS total three chelating ligands
oxidation NUMBER and coordination number of METAL are `+2` and SIX respectively

`XeO_(2)F_(2), SiF_(4)`
`XeO_(2)F_(2), IO_(2)F_(2)^(-)`
`TeCl_(4), I Cl_(4)^(-)`
`BrO_(3)F, XeOF_(2)`

Gases which have high VALUE of van der Waals constant ‘a’ are EASILY liquefied
Easily liquefied gases are water soluble
Ions FORMING gases in a SOLVENT are soluble in that solvent
Under same conditions, `NH_3` has LOW solubility than that of `CO_2`

Solid `PCl_5` EXIST as `[PCl_4]^(+)[PCl_6]^(-)`<BR>Solid `PBr_5` exist as `[PBr_4]^(+)[Br]`
The ANHYDRIDE of `HClO_4Cl_2O_7`
`NO_2` on cooling BECOMES paramagnetic.

`S^(-)(g) to S^(2-)(g)`
`NA^(+)(g) +Cl^(-)(g) to NaCl(s)`
`N(g) to N^(-)(g)`
`Al^(2+)(g) to Al^(3+)(g)`

`Ph-CH=CHCONH_(2)overset(KOBr)toPhCh=CH-NH_(2)`
`H_(2)N-UNDERSET(O)underset(||)C-NH_(2)underset(Cl_(2))overset(NaOH)toHN_(2)-NH_(2)`
`Ph-CequivC-COOHunderset(H_(2)SO_(4),DELTA)overset(HN_(3))toPhCH_(2)COOH`

Alanine at pH = 4,`CH_(3)-overset(COOH)overset(|)(CH)-overset(o+)NH_(3)`
Pyenyl alanine at pH = 10, `CH_(3)-underset(Ph)underset(|)overset(COO^(Θ))overset(|)C-NH_(2)`
GLUTAMIC ACID at pH = 2, `HOOC-CH_(2)-CH_(2)-overset(overset(o+)NH_(3))overset(|)(CH)-COOH`
TYROSINE at pH = 12,

We can condense vapours simply by applying pressure
To liquify a gas one MUST lower the temperature below `T_(c)` and ALSO apply pressure
At `T_(c)`, there is no distinction between liquid and vapour state HENCE density of the liquid is nearly equal to density of the vapour
All the statements are CORRECT statements

Acidic strength of `HBr gt HCL` but reverse is true for their REDUCING property
Basic strength of `PH_(3) gt AsH_(3)` but reverse is true for their `HhatCH` bond angle
`K_(a_(1))` of fumaric acid is higher than maleic acid but reverse is true for their `K_(a_(2))`
Cassiterite and rutile are sulphides ore

`SIGMA` - bond lies on the line joining the nuclei of bonded atoms
`pi` - electron cloud lies on either SIDE to the line joining the nuclei of bonded atoms
`(2p_(pi)-3d_(pi)) pi` - bond is stronger than `(2p_(pi)-3p_(pi))pi` - bond.
`sigma`-bond has primary effect to decide direction of COVALENT bond, while `pi`- bond has no primary effect in direction of bond

it acts as oxidinsing agnet because `NI^(2+)` cation is having E.A.N. 34.
It is extra stabilized by hydrogen bonding
It's IUPAC name is Bis(dimethylyoximato)nickelate(II)
It's LIGAND CONTAINS two different DONAR sites

Compound is neither LOW spin nor high spin complex
Type of hybridisation complex does not depend upon nature of ligands
Magnetic MOMENT of complex COMPOUNDS is either `sqrt(15)B.M or sqrt(8)B.M.`
All are incorrect statements

`[Fe(CO)_(5)]`, the orbitals used for HYBRIDISATION in Fe atom are s, `p_(x),p_(y),p_(z),d_(z^(2))` and it is high spin complex
`[Pt(NH_(3))_(2)Cl_(2)]`, the orbtials used for hybridization on Pt atom are s,`p_(x),p_(y),d_(x^(2)-y^(2)) ` and it is low spin complex
`[Cr(H_(2)O)_(6)]^(3+)`, the orbitals used for hybridization in Cr atom are s,`p_(x),p_(y),p_(z),p_(x^(2)),d_(x^(2)-y^(2))` and it is high spin complex
`Ni(CO)_(4)`, the orbitals used of rhybridization in Ni atom are s,`p_(x),p_(y),p_(z)`, and it is low SPI complex

`H_(3)PO_(4)`is conjugate ACID of `HPO_(4)^(-2)`
`H_(2)PO_(3)^(-1)` is conjugate acid of `HPO_(3)^(-2)`
`H_(2)PO_(2)^(-1)` can be conjugate acid of `HPO_(2)^(-2)`
`H_(2)PO_(4)^(-1)` is conjugate acid of `H_(3)PO_(4)`

In `AsH_(3)` molecule lone pair at central atom is PRESENT in almost pure s-orbital
Number of `p pi -d pi` BOND in `SO_(3) and SO_(2)` are same
`NF_(3)` is better Lewis base than `NCl_(3)`
Stable oxidation state of Lead is `+2`

I,II
III,IV
both (a) and (B)
NONE of these

It is an example of `S_N` REACTION in which protonated ALCOHOL is the substrate and second molecule of alcohol is the nucleophile.
It is intermolecular dehydration of alcohols
This reaction can be `S_N2` if alcohol is `1^@`.
All of the above statements are correct.

Gases which have high value of Van der Waals constant `'a'` are EASILY liquefied
Easily liquenfiable gases are WATER soluble
Ions FORMING gases in a solvent are solutble in that solvent
Under same condition, `NH_(3)` has low solubility that that of `CO_(2)`

hydrophilic COLLOID is a colloid in which there is a strong attraction between the dispersed phase and water
hydrophobic colloid is a colloid in which there is a lack of attraction between the dispersed phase and water
hydrophobic SOLS are often formed when a SOLID crystallises RAPIDLY from a chemical reaction or a SUPERSATURATED solution
all of the above

This reaction is called Hofmann ELIMINATION
`OH^(-)` ION functions as a BASE in an `E_(2)` elimination
Less substituted ALKENE is the predominant alkene
All are correct statements.

It is termed as `BETA`- elimination reaction
`C_(2)H_(5)O^(-)` is a BRONSTED -base
Produced are 1-butene and 2-butene
All are correct statements

Total 10 monochloro products are obtained.
Total 8 FRACTIONS are obtained on fractional distillation of all monochloro DERIVATIVES obtained.
Out of all monochloro products only 3 are capable of showing GEOMETRICAL isomerism.
Out of all monochloro products 4 are chiral.

Borax is used as a buffer
1M borax SOLUTION reacts with equal volumes of `2m HCL` solution
Titration of borax can be made using methyl orange as the indicator
Coloured bead obtained in borax-bead test contains metaborate

Only one`1^(@)` MONOCHLORO product is obtained.
`4,3^(@)`monochloro PRODUCTS are obtained.
7 FRACTIONS are obtained on FRACTIONAL distillation.
`8,2^(@)` monochloro products are obtained.

It acts as oxidising agent because `NI^(2+)` CATION is having EAN 34.
It is extra-stabilized byhydrogenn bonding
It's IUPAC name is Bis(dimethylglyoximato) nickelate (II)
It's ligand contains TWO different DONAR sites

When the LEAD-silver alloy is RICH in silver, lead is removed by the curpellation process
When the lead-silver alloy is ICH in lead, lead is removed byparke's or pattinson's process
ZINC forms an alloy with lead, from which lead is SEPARATED by distillation
Zinc forms an alloy with silver, from which zinc is separated by distillation

strongest force of attraction in alkyl halide is the LONDON force
London FORE is a surface attraction
Molecules with LARGER surface AREA have higher b.p
All of the above are correct statements

In both COMPLEX COMPOUNDS SECONDARY valency is satisfied by only `NH_3`
In both complex compounds `Cl^(-)` are satisfying only PRIMARY valency
In both complex compounds primaryvalency is satisfied by only `Cl^(-)`
In both complex compounds all `Cl^-` are ionizable

Each bond is formed by maximum OVERLAP for its maximum stability
It represents localised electron model of bonding
Most of the electron RETAIN the same orbital locations as in a SEPARATED ATOMS
All are correct .

Compound 'C' on TREATING with conc. NaOH showns disprotionation reaction.
Compound 'C' forms diiazonium salt with AQ. `HNO_(2) or(naNO_(2)+HCl)//0.5^(@)`
Compound 'C' gives foul smelling compound with `(CHCl_(3)+KOH)`.
Compound 'C' is primary amine.

It gives yellow ppt. with `NaOH//I_(2)`
It eill rep[lace maximum 3`alpha` H ATOMS when PLACED in `D^(o+)//D_(2)O`SOLUTION for longer time.
It will give 2,4-DNP test.
It will give n-pentene when reduced with Zn-Hg /HCl.

CANE SUGAR is laevorotatory.
Cane sugar is dextrarotatory.
Invent sugar is laevorotatory.
Invert sugar is dextrarotatory.

Lassaigen's extrect made by E gives prussian BLUE colour with `FeSo_(4)+FeCl_(3)`.
Lassaingne's extreact of D gives pale yellow PPT. with aq. `AgNO_(3)`.
Lassaingne's extreact of D gives BLACK colour with `Pb(Oac)_(2)`.
B reacts with Mg/ether followed by Me-Br to

b.p. of 1 molal NaCl solution is TWICE that of 1 molal SUCROSE solution
b.p. elevation of 1 molal GLUCOSE solution is half of the 1 molal KCL solution
b.p. is a colligative property
All of the above

Product mixture is having no optical activity if ALCOHOL is FULLY consumed.
Organic product is having no `O^(18)`.
This reaction follows `A_(AL^(2))` mechanism.
None of the above

Geometricalisomersof COMPLEXES may differin dipole MOMENT and visible / UV SPECTRA
Complexes of the TYPE `[Ma_3b_3]` can also havefacial (FAC) and meridional (mer ) isomer
No optical isomer exists for thecomplextrans-`[co(en)_2Cl_2]^(+)`
All are correct

The `d_(x^(2)-y^(2))` and `d_(z^(2))` orbitals are called `e_(g)` orbitals for octahedral splitting
The `d_(XY), d_(XZ)" and "d_(yz)` orbitals LIE between the axes and collectively called `t_(2g)` orbitals
both are correct
NONE is correct

Only (IV)
(III) and (iv)
(II), (iii) and (iv)
all (i), (ii), (iii) and (iv)

emulsions EXHIBIT TYNDALL effect 
Oil emulsions are more viscous than the aqueous emulsions 
ELECTRICAL conductance of aqueous EMULSION is higher than that of oil emulsion 
emulsion exhibits brownian movement 

`IV GT III gt I gt II`
`IV gt I gt III gt II`
`III gt II gt I gt IV`
`II gt I gt III gt IV`

Paulling scale (E.N. of F-atom)gtMulliken scale (E.N. of F-atom)
`Cl_(2)O_(7)` (E.N. of CL-atom) `gtCl_(2)O_(5) ` (E.N. of C-atom)
`CH_(4)` (E.N. of C-atom) `gtCO_(2)` (E.N. of C-atom)
`CU^(2+)` (E.N.) `gtCu^(+)` (E.N.)

`B_(3)N_(3)H_(6)gtC_(6)H_(6)`


trans-1,2-dibromoethene GT cis-1,2-dibromoethene

`COCl_(2)gtCOF_(2)` : `XCX` bond ANGLE
`NO_(2)FgtNO_(2)Cl` : `ONO` bond angle
`SO_(2)F_(2)ltSOF_(2)` : `FSF` bond angle
`N_(2)F_(2)ltN_(2)(CH_(3))_(2)` : `N-N` bond length