Explore topic-wise InterviewSolutions in Current Affairs.

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1.

Resistance of 0.2M solution of an electrolyte is 50Omega. The specific conductance of the solution of 0.5M solution of the same electrolyte is 280Omega. The molar conductivity of 0.5M solution of the electrolyte is S m^(2)mol^(-1) is

Answer»

`5xx10^(-4)`
`5xx10^(-3)`
`5xx10^(3)`
`5xx10^(2)`

SOLUTION :`x=1.4S//m`
`R=50Omega`
`M=0.2 `
`K=(1)/(R)xx(l)/(A)`
`implies(l)/(A)=1.4xx50m^(-1)`.
Now, NEW solution has M=0.5, `R=280Omega`
`impliesK=(1)/(R)xx(l)/(A)=(1)/(280)xx1.4xx50=(1)/(4)`
`implies lamda_(M)=(K)/(1000xxM)=((1)/(4))/(1000xx0.5)=(1)/(2000)=5xx10^(-4)`
2.

Resistance of 0.2 M solution of an electrolyte is 50 Omega. The specific conductance of the solution of 0.5 M solution of same electrolyte is 1.4 S m^(-1) and resistance of same solution of the same electrolyte is 280 Omega. The molar conductivity of 0.5 M solutions of the electrolyte is 5 m^(2) mol^(-1) is

Answer»

`5 XX 10^(-4)`
`5 xx 10^(-3)`
`5 xx 10^(3)`
`5 xx 10^(2)`

ANSWER :A
3.

Resistance of 0.2 m solution of an electrolyte is 50 Ohm^(-1). The specific conductance of the solution is 1.3 Sm^(-1). If resistance of 0.4 m solution of the same electrolyte is 260 Ohm^(-1), its molar conductivity is ………… .

Answer»

`62.5 Sm^2 mol^(-1)`
`6250 Sm^2 mol^(-1)`
`62.5 XX 10^(-4) Sm^2 mol^(-1)`
`625 xx 10^(-4) Sm^2 mol^(-1)`

ANSWER :C
4.

Resistance of 0.2 M electrolytic solution is 50Omega. And its specific conductivity is 1.4 S m^(-1). If specific resistance of 0.5 M same electrolytic solution is 280Omega. Then what is the molar conductivity of 0.5 M electrolytic solution in S m^(2) ?

Answer»

`5XX10^(3)`
`5xx10^(2)`
`5xx10^(-4)`
`5xx10^(-3)`

SOLUTION :`5xx10^(2)`
5.

Resistance of 0.05 M electrolytic solution at 298K temperature is 30.0 Omega. The cross sectional area of conductivity cell having Pt electrode is 3.8cm^(2) and distance between two electrode is 1.5 cm, then what is the molar conductivity of electrolytic solution ?

Answer»

SOLUTION :Conductivity constant for cell :
`G^(**)=(l)/(A)=(1.5cm)/(3.8cm^(2))=0.3947cm^(-1)`
Where, R=resistance of solution=`30.0Omega`
c=concentration of solution=0.05 mol `L^(-1)`
Conductivity of solution :
`kappa=(G^(**))/(R)=(1.5cm)/(3.8cm^(2))xx(1)/(30Omega)`
`=0.013158cm^(-1)Omega^(-1)~~0.0132" S "CM^(-1)`
Molar conductivity :
`Lamda_(m)=(1000kappa)/(c)=(1000xx0.0132" S "cm^(-1))/(0.05" mol "cm^(-3))`
`=264" S cm"^(2)mol^(-1)`
6.

Resemblance between Nb and Ta is because they

Answer»

belong to same group of perioidc table
have the same MINERAL SOURCE
have almost same IONIC and covalent RADII
are transition metals

ANSWER :C
7.

Required amount of crystalline oxalic acid (eq. eq.=63) to prepare N/10 250 ml oxalic acid solution is

Answer»

0.158 g
1.575 g
15.75 g
6.3 g

Solution :`N=(W_(B)xx1000)/(ExxV)IMPLIES(N)/(10)=(X xx1000)/(63xx250)""thereforex=1.575gm`
8.

Representative elements are elements of

Answer»

s - BLOCK
s-block and p-block
d-block or TRANSITION ELEMENTS
d-block and f-block

ANSWER :B
9.

Representative elements belong to

Answer»

s and p-block
d-block
d and f-block
f-block

ANSWER :A
10.

Represent the galvanic cell in which the reaction Zn(s)+Cu^(2+) (aq) to Zn^(2+) (aq)+Cu(s) takes place.

Answer»

SOLUTION :MAY be represented as:
`ZN(s)//Zn^(2+) (aq)||CU^(2+) (aq) |Cu(s)`
11.

Represent the galvanic cell in which the following reaction takes place : Zn(s)+2Ag^(+)(aq)toZn^(2+)(aq)+2Ag(s) (i) The reaction taking place at each of its electrodes. (ii) The carriers of current within this cell.

Answer»

SOLUTION :(i) At ANDOE, `ZntoZn^(2+)+2E`
At cathode, `Ag^(+)+etoAg`
(ii) `Zn^(2+)andAg^(+)ions`.
12.

Represent the galvanic cell based on the cell reaction given below:Cu+2Ag^+to Cu^(2+)+2Ag

Answer»

SOLUTION :`Cu|Cu^(+2)||Ag^+|Ag`
13.

Represent the chemical forula of iron rust.

Answer»


ANSWER :
14.

Represent the cell in which the following reaction takes place: Mg(s)+2Ag^(+)(0.0001M)toMg^(2+)(0.130M)+2Ag(s) Calculate its E_(cell). Given that E_(Mg^(2+)//Mg)^(@)=-2.37V and E_(Ag^(+)//Ag)^(@)=+0.80V

Answer»

Solution :Here, we are given reduction potential as `E_(Mg^(2+),Mg)=-2.37,E_(AG^(+),Ag)=+0.80V`
As the emf of the cel must be positive, this can be so only if oxidation takes PLACE at the MAGNESIUM electrode, hence, the electrode reaction will be
`MgtoMg^(2+)+2e^(-)` (At anode)
`2Ag^(+)+2e^(-)to2Ag` (At cathode)
Thus, the cell may be REPRESENTED as `Mg|Mg^(2+)(0.130M)||Ag^(+)(0.0001M)|Ag`
Standard emf of the cell will be:
`E_(cell)^(@)=`Std. Red. Pot. Of R.H.S. electrode-Std. Red. Pot. Of L.H.S. electrode=0.80-(-2.37)=3.17V
The overall reaction is: `Mg+2Ag^(+)hArrMg^(2+)+2Ag""(n=2)`
Applying nernst eqn., we get
`E_(cell)=E_(Cell)^(@)-(0.0591)/(n)"log"([Mg^(2+)])/([Ag^(+)]^(2))`
`E_(cell)=E_(cell)^(@)-(0.0591)/(2)"log"(0.130)/((10^(-4))^(2))=E_(Cell)^(@)-(0.0591)/(2)"log"(0.130)/(10^(-8))`
`=3.17-0.02955log(1.30xx10^(7))=3.17-0.02955xx(7.1139)=3.17-0.21=2.96`volt.
ALTERNATIVELY, this problem may be solved by first calculating the electrode potentials of the two electrodes separately and then calculating the emf from the electrode potentials.
15.

Represent the cell in which the followig reaction takes place, Mg_((s))+2Ag_((0.0001M))^(+)to Mg_((0.130M))^(2+)+2Ag_((s)) Calculate its E_(cell) if E_(cell)^(Theta)=3.17V

Answer»

Solution :In this cell `Mg_((s))|Mg^(2+)` is anode because Mg get oxidized and also `Ag^(+)` is reduced in Ag so on cathode `Ag^(+)|Ag` will be on RIGHT side. Between these two ELECTRODES salt bridge is DENOTED by two verticle line || and hence the symbolic representation of cell will be
`Mg_((s))|Mg_((0.130M))^(2+)||Ag_((0.0001M))^(+)|Ag_((s))`
Calculation for `E_(cell)` potential is as follows:
`E_(cell)=E_(cell)^(Theta)-(RT)/(nF)LN([Mg^(2+)])/([Ag^(+)]^(2))`
`therefore E_(cell)=3.17V-(0.0591)/(2)"log"([Mg^(2+)])/([Ag^(+)]^(2))`
`=3.17V-(0.0591)/(2)"log"(0.130)/((0.0001)^(2))`
`=3.17-0.2955log(1.33xx10^(+7))`
`=3.17-0.2955(+7.1139)`
`=3.17-0.2099=3.17-0.21=2.96V`
16.

Represent the cell in which the following reaction takes place Mg(s)+2Ag^(+)(0.001M) to Mg^(2+)(0.130)+2Ag(s) Calculate E_("cell")" if "E_("cell")^(0)=3.17V.

Answer»

Solution :Represent of the cell
`Mg//Mg^(2+)(0.130M)||Ag^(+)(0.01M)//Ag`
Cell reaction `Mg+2Ag^(+) to Mg^(2+)+2Ag`
FORMULA: `E_("cell")=E_("cell")^(0)-(0.059)/(N)LOG""([Mg^(2+)])/([Ag^(+)]^(2)]`
Substitution `E_("cell")=3.17-(0.059)/(2)log"" ([0.130])/([0.0001)]^(2))`
=2.96V
17.

Replacement of -N_2^+Cl^- from benzene diazonium chloride by iodine can be done by using

Answer»

HI
NaOI
`PI_3`
KI

Answer :D
18.

Replacement of N_2^+ X^- can be done by

Answer»

`H_3O^+`
AQ. NaOH
alc. KOH
moist `Ag_2O`

ANSWER :A
19.

Replacement of Cl of chlorobenzene to give phenol requires drastic conditions but chlorine of 2,4-dinitrochlorobenzene is readily replaced because

Answer»

`NO_(2)` make ring electron rich at ORTHO and para
`NO_(2)` withdrawn `e^(-)` from METAL POSITION
`-NO_(2)` donates `e^(-)` at META position
`NO_(2)` WITHDRAWS `e^(-)` from ortho/para position

Solution :
20.

Replacement of diazonium group by halogen atom can be done by the reaction

Answer»

Ullmann reaction
Fitting reaction
Sandmeyer's reaction
Friedel CRAFT reaction

Answer :C
21.

Replacement of diazonium group by chlorine atom can be carried but by use of

Answer»

AgCl
CuCl
`Cu_(2)Cl_(2)`
`PCl_(5)`

ANSWER :C
22.

Replacement of Cl of chlorobenzene to give phenol requires drastic conditions, but Cl of 2,4-dinitrochlorobenzene is readily replaced. This is because

Answer»

`-NO_(2)` group makes the RING electron rich at ORTHO and para position
`-NO_(2)` group withdraws ELECTRONS from position
`-NO_(2)` donates electrons at META position
`-NO_(2)` withdraws electrons from ortho and para position.

Answer :D
23.

Replacement of CI of chloro benzene to give phenol requires drastic condition but CI of 2. 4-6-trinitro chloro benzene is really replaced because

Answer»

`NO_2`makes ring electrons RICH at ortho and para positions
`NO_2`with DRAWS electrons from meta position
`NO_2`donates electrons at meta position
`NO_2`WITHDRAWS electrons from ortho, para positions

Answer :D
24.

Replacement- N_(2)^(+)Cl^(-) frombenzene diazonium chloride byhydrogenatomcanbedone by using

Answer»

`H_(3)PO_(2)`
`C_(2)H_(5)-OH`
`CH_(3) - CHO`
both a andb

Answer :D
25.

Repeateduse of which one of the following fertilizers would increase the activity of the soil ________

Answer»

AMMONIUM sulphate
Superphosphate of lime
Urea
Potassium nitrate

Answer :A
26.

Repeating units teflon is

Answer»

`-CF_3-CF_3-`
`-CHF_2-CHF_2-`
`-CF_2-CF_2-`
`-CH_2-CF_2-`

ANSWER :C
27.

Replacement by -N_(2)^(+)Cl^(-) frombenzenediazonium choridebycan bedone byusing

Answer»

HI
NaOI
`PI_(3)`
Kl

Answer :D
28.

Reonance is due to

Answer»

Delocalization of SIGMA ELECTRONS
Delocalization of PI electrons
MIGRATION of H atoms
Migration of protons

ANSWER :B
29.

Remsay was awarded Noble Prize for the discovery of rare gases in

Answer»

`1900`
`1902`
`1904`
`1910`

SOLUTION :N//A
30.

Removal of unwanted meterial from the ore is called…………….

Answer»

SOLUTION :CONCENTRATION
31.

Removal of unreacted oxide ore, other metals, non metals associated with isolated crude metal is called ________

Answer»

leaching
bleaching
REFINING
liquation

Solution :refining
32.

Removal of hydrogen atom is easier when it is attached to:

Answer»

`1^@` CARBON
`2^@` carbon
`3^@` carbon
Same in all

Answer :C
33.

Removal of a hydride ion from a methane molecule will give a:

Answer»

METHYL radical
Carbonium ion
Carbanion
Methyl group

Answer :B
34.

..............relieve pain and produces steeps and they are additive.

Answer»

SOLUTION :NARCOTIC Analgegics (or) OPIOIDS
35.

Relative rate of SN^(1) reaction for t-butyl bromide?

Answer»

37
0.02
`10^(6)`
1

Solution :`CH_(3)^(-)` has a total of 8 electrons in VALENCE shell of central carbon ATOM like NITROGEN atom in ammonia.
36.

Relative rate of methyl bromide in SN^(2) reaction is

Answer»

1
0.02
`10^(6)`
37

Solution :Bronotrifluoride is an electron defficent molecule having SIX ELECTRONS around CENTRAL boron ATOM.
37.

Relative lowering of vapour pressure of a dilutesolutionof glucose dissolved in 1 kgof wateris 0.002. The molality of the solution is .

Answer»

0.004
0.222
0.111
0.021

Solution :Relativeloweringin vapoure PRESSURE , `(p^(@) - p)/(p^(@)) = x_(2) = 0.002`
Molalityof solution MEANS the numberof MOLES of glucose PRESENTIN 100 g of water .
`w_(1)= 1000 g, n_(1) = (1000)/(18) = 55.55`
`(n_(2))/(n_(2) + 55.55) = 0.002`
For dilutesolution , 55.55 + `n_(2) = 55.55`
`THEREFORE n_(2) = 0.002 xx 55.55 = 0.1111`
38.

Relative lowering of vapour pressure is ____ the mole fraction of the solute.

Answer»

EQUAL to
equal to half
twice
THREE times

Solution :equal to
39.

Relative lowering of vapour pressure of al dilute solution of gluscose dissolved in 1kg of water is 0.002.The molality of the solution is

Answer»

`0.004`
`0.222`
`0.111`
`0.021`

Solution :(c) : RELATIVE lowering of vapour PRESSURE for dilute solution i.e., `(p^(@) -p_(s))/(p^(@)) ~~ (n_(2))/(n_(1))`
Given: `(p^(@)-p_(s))/(p^(@)) = 0.002, n_(1(H_(2)O)) = (1000)/(18)` moles For dilute solution, `n_(2)` is molality `= 0.002 XX = (1000)/(18)` m
= 0.111 m
40.

Relative lowering of vapour pressure is a colligative property because …………….. .

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It DEPENDS on the CONCENTRATION of a non-electrolyte solute in solution and does not depend on the nature of the solute MOLECULES
It depends on NUMBER of particles of electrolyte solute in solution and does not depend on the nature of the solute particles
It depends on the concentration of a non-electrolyte solute in solution as on the nature of the solute molecules
It depends on the concentration of an electrolyte or non-electrolyte solute in solution as well as on the nature of solute molecules

Answer :a,b
41.

Relative lowering of vapour pressure is a colligative property because

Answer»

It depends on the xoncentration of a non-electrolytesolute in solution and does not depend on the NATURE of the SOLUTE MOLECULES
It depends on number of PARTICLES of electrolyte solutein solution and does not depend on the nature of the solute particles.
It depends on the concentration of a non-electrolyte solute in solution as well as on the nature of the solute molecules.
It depends on the concentration of an electrolyte or non-eletrolyte solute in solution as well as on the nature of solute molecules.

Solution :are both CORRECT.
42.

Relative lowering of vapour pressure, elevation of boiling point, depression of freezing point and osmotic pressure are important colligative properties of dilute solutions. Relative lowering of vapour pressure of an aqueous dilute solution of glucose is 0.018 What is the mole fraction of glucose in the solution ?

Answer»

Solution :Mole fraction of glucose-Relative LOWERING of VAPOUR PRESSURE= 0.018
43.

Relative lowering of vapour pressure is a colligative property because ……..

Answer»

It depends on the concentration of a non - ELECTROLYTE solute in SOLUTION and does not DEPEND on the nature of the solute molecules.
It depends on number of particles of electrolyte solute in solution and does not depend on the nature of the solute particles.
It depends on the concentration of a non - electrolyte solute in solution as well as on the nature of the solute molecules.
It depends on the concentration of an electrolyte or non - electrolyte solute in solution as well as on the nature of solute molecules.

Solution :Explanation : Colligative PROPERTY depends on (A) the concentration of a nonelectrolyte solute in solution, (B) the number of particles of electrolyte solute in solution, & (C ) It does not depend on the nature of solute molecules / particles.
44.

Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH_(3))_(3)Cl]Cl in 3 moles H_(2)O is 0.50. on reaction with AgNO_(3), this solution will from

Answer»

`1 MOL AGCL`
`0.25 mol AgCl`
`2 mol AgCl`
`0.40 mol AgCl`

ANSWER :A
45.

Relationship between products (Q) and (S) is

Answer»

POSITIONAL isomer
chain isomer.
stereoisomer.
FUNCTIONAL isomer.

Answer :D
46.

What is relation between K_p and K_c?

Answer»


ANSWER :`k_P`=`K_c`, `(RT)^DELTAN`
47.

Relationship between DeltaG^(@) and K_(P) is…….

Answer»

<P>`DeltaG^(@)`=RT In `K_(P)`
`DeltaG^(@)` =-RIN `K_(p)`
`DeltaG^(@)`=-T In `K_(P)`
`DeltaG^(@)`=-RT In `K_(P)`

Answer :A
48.

Relation between standard cell potential and equilibrium constant is

Answer»

`E^(@) = (N RT)/(F)` In K
`E^(@)= (RT)/(NF)` In K
`E^(@)=(nRF)/(T)` In K
`E^(@)=(RF)/(nT)` In K

Solution :Nernst EQUATION.
49.

Relation between standard e.m.f. of a cell and equilibrium constant is ________.

Answer»

SOLUTION :`(E_(CELL)=(2.303RT)/(NF)IogK_c)`
50.

Relation between non standard cell potential and concentration of solution at constant temperature is given by. . . . Scientist.

Answer»

Faraday
Daniell
Leclanche
Nernst

Solution :`E_(cell)=E_(cell)^(THETA)-RT" ln "KAPPA`