Explore topic-wise InterviewSolutions in Current Affairs.

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1.

Oxidation states of the metal in the minerals haematite and magnetite, respectively, are

Answer»

II, III in HAEMATITE and III in magnetite
II, III in haematite and II in magnetite
II in haematite and II, III in magnetite
III in haematite and II, III in magnetite

Solution :(i) Haematite is `Fe_(2)O_(3)` in which Fe is present in III OXIDATION state.
(ii) Magnetite `(Fe_(3)O_(4))` is an EQUIMOLAR MIXTURE of FeO and `Fe_(2)O_(3)`.
Oxidation state of Fe in FeO is II.
Oxidation state of Fe in `Fe_(2)O_(3)` is III.
2.

Oxidation states of P in H_(4)P_(2)O_(5), H_(4)P_(2)O_(6) and H_(4)P_(2_)O_(7), respectively are

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<P>`+3,+5` and +4
`+5,+3` and +4
`+5,+4` and +3
`+3,+4` and `+5`

Solution :Oxidation state of H is `+1` and that of O is `-2`.
LET the oxidation state of P in the GIVEN compounds is x.
In `H_(4)P_(2)O_(5)`
`(+1)xx4+2xx x+(-2)xx5=0`
`4+2X - 10 = 0`
`2x = 6`
`:. x = +3`
In `H_(4)P_(2)O_(6)`
`(+1) xx4+2xx x + (-2)xx6=0`
`4+2x-12=0`
`2x=8`
`:. x = +4`
In `H_(4)P_(2)O_(7)`
`(+1)xx4+2xx x + (-2)xx7=0`
`4+2x-14=0`
`2x=10`
`:. x = +5`
Thus the oxidation states of `P` in `H_(4)P_(2)O_(5)`. `H_(4)P_(2)O_(6)` and `H_(4)P_(2)O_(7)` are `+3,+4` and `+5` respectively.
3.

Oxidation states of P in H_(4)P_(2)O_(5), H_(4)P_(2)O_(6), H_(4)P_(2)O_(7) are respectively ________

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`+3,+4,+5`
`+3,+5,+4`
`+5,+3,+4`
`+5,+4,+3`

ANSWER :A::C::D
4.

Oxidation states of carbon atoms in methane and ethane are :

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`+ 2, + 4`
`+4,+2`
`-4,4`
ZERO, zero

Answer :D
5.

Oxidation state/s exhibited by Ce is / are

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`+2` only
`+3,+4`
`+4` only
`+2,+3,+4`

ANSWER :B
6.

Oxidation state of uranium in UO _(2)^(2+) is

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`+4`
`+5`
`+6`
`+7`

ANSWER :C
7.

Oxidation state of the metal in the minerals haematite and magnetite, respectively are

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II, III in HAEMATITE and III in magnetite
II, III in haematite and II in magnetite
II in haematite and ll, III in magnetite
III in haematite andll, III in magnetite

Answer :D
8.

Oxidation state of the metal in the minerals haematite and magnetite respectively are

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II, III in HAEMATITE and III in magnetite
II, III in haematite and II in magnetite
II in haematite and II,III in magnetite
III in haematite and II,III in magnetite

Answer :D
9.

Oxidation state of sulphur in H_2 S is

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`-1`
`+1`
`+2`
`-2`

SOLUTION :`-2`
10.

Oxidation state of S in H_(2)SO_(5) and H_(2)S_(2)O_(8) respectively are

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`+6, +6`
`+6, +4`
`+8, 7`
`+4, +4`

ANSWER :A
11.

Oxidation state of S in compound 'Z' is

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`+1`
`+4`
`+6`
`+2`

ANSWER :B
12.

Oxidation state of phosphorus is least in

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HYPOPHOSPHORIC ACID
Hypophosphorus acid
METAPHOSPHORIC acid
Pyrophosphoric acid

ANSWER :2
13.

Oxidation state of P in H_(4)P_(2)O_(5), H_(4)P_(2)O_(6), H_(4)P_(2)O_(7) are respectively

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`+3, +5, +4`
`+5, +3, +4`
`+5, +4, +3`
`+3, +4, +5`

ANSWER :4
14.

Oxidation state of oxygen is + 1 in .......... And +2 in ,.......

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SOLUTION :`O_2F_2,OF_2`
15.

Oxidation state of oxygen in super oxide is

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O
0.5
1
1.5

Answer :B
16.

Oxidation state of oxygen in H_2O_2 IS

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`-1`
2
S
`-2`

ANSWER :A
17.

Oxidation state of oxygen atom in sodium peroxide is :

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`-1`
`-2`
0
`-1//2`

ANSWER :B
18.

Oxidation state of oxygen atom in potassium superoxide (KO_2) is

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`1//2`
ZERO
`+1//2`
`-2`

ANSWER :A
19.

Oxidation state of nitrogen is incorrectly given for

Answer»

`{:(,"COMPOUND","Oxidation State"),((a),Mg_(3)N_(2),""-3):}`
`{:(,"Compound","Oxidation State"),((b),NH_(2)OH,""-1):}`
`{:(,"Compound","Oxidation State"),((C),(N_(2)H_(5))_(2)SO_(4),""+2):}`
`{:(,"Compound","Oxidation State"),((d),[Co(NH_(3))_(5)Cl]Cl_(2),""-3):}`

Answer :C
20.

Oxidation state of nitrogen is not correctly given for the compound

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`[CO(NH_3)_5Cl]Cl_2`
`NH_2OH(-1)`
`(N_2H_5)_2So_4(-2)`
`Mg_3N_2(-3)`

Answer :A
21.

Oxidation state of N in HNO_(3) is ………………….. .

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`+2`
`+3`
`+4`
`+5`

SOLUTION :`+5`
22.

Oxidation state of mercury in amalgams is:

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ZERO
One
Two
Three

Answer :A
23.

Oxidation state of Iron and the charge on the ligand NO in [Fe(H_(2)O)_(5)NO]SO_(4) are …………. .

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`+2` and `0` respectively
`+3` and `0` respectively
`+3` and `-1` respectively
`+1` and `+1` respectively

Answer :A::C::D
24.

Oxidation state of Fe in Fe_(3)O_(4) is

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`3/2`
`4/5`
`5/4`
`8/3`

Solution :`overset(**)(F)e_(3)O_(4)`
`3X+(-8)=0, 3x-8=0`
`3x=8 implies x=8/3`.
25.

Oxidationstate of Fe in compound (F) is

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`+ 1`
`+2`
`+ 3`
`+4`

ANSWER :a
26.

Oxidation state of copper is +1 in

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MALACHITE
cuprite
azurite
chalcopyrite.

Solution :(B,d) : Oxidation state of CU in both cuprite `(Cu_(2)O)` and chalcopyrite `(CuFeS_(2))` is + 1.
27.

Oxidation state of cobalt in [Co(NH_(3))_(4)(H_(2)O)Cl]SO_(4) is

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0
`+4`
`-2`
`+3`

ANSWER :D
28.

Oxidation state of chromium is CrO_(5) is

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`+6`
`+5`
`+3`
`+10`

ANSWER :A
29.

Oxidation state of chromium in

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`+10`
`+6`
`+3`
`+2`

SOLUTION :
`x-6=0"" thereforex=+6`
30.

Oxidation state of chlorine is highest the compound :

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`CI_2`
HCI
`CI_2O`
`CI_2O_7`

ANSWER :D
31.

Oxidation state of chlorine in Belacing powder

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`-2`
`-1`
`+1`
`-1AND +1`

ANSWER :D
32.

Oxidation state of carbone in its hydrides…………..

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`+4`
`-4`
`+3`
`+2`

SOLUTION :`CH_(4)^(+)` in which the OXIDATION state of carbon is 4.
33.

Oxidation state of carbon in its hydrides

Answer»

`+4`
`-4`
`+3`
`+2`

ANSWER :A::D
34.

Oxidation state of +1 for phosphorus is found in:

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`H_3PO_3`
`H_3PO_4`
`H_3PO_2`
`H_4P_2O_7`

ANSWER :C
35.

Oxidation state of +1 for phophorous is found in

Answer»

<P>`H_(3)PO_(3)`
`H_(3)PO_(4)`
`H_(3)PO_(2)`
`H_(4)P_(2)O_(7)`

Answer :3
36.

Oxidation state, covalency of sulphur and total number of lone pairs of electrons in S_(8) molecule are respectively

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`+6,6,16`
ZERO,`2,16`
Zero,`6,12`
`-2,2,16`

ANSWER :B
37.

Oxidation state if iron in ferric is

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`+2`
`+5`
`+3`
`+6`

SOLUTION :It is the correct answer.
38.

Oxidation state exhibited by group 13 elements is ___________

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`+1,+2` and `+3`
`+1` and `+3`
`+1` and `+4`
`+2+3` and `+4`

Answer :B
39.

Oxidation products of glucose are

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Sucrose
glucaric acid
gluconic acid
b' and 'C' both

Answer :D
40.

Oxidation product of .X. (molecular formula C_3H_6O is .Y. (molecular formula C_3H_6O_2). The compound .Y. is:

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ACETIC ACID
FORMIC acid
Propionic acid
Butyric acid

Answer :C
41.

Oxidation product 1,2-cyclopentanediol with HIO_(4) gives

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`Hunderset(O)UNDERSET(||)C-CH_(2)-CH_(2)-CH_(2)-underset(O)underset(||)C-H`

`O= underset(OH)underset(|)C-CH_(2)-CH_(2)-CH_(2)-underset(OH)underset(|)C=O`
NONE of these

Solution :
42.

Oxidation potential of given hydrogen half cell at 25^(@)C is 0.118V then what is the pH of H^(+) ion solutioin ? P|underset((1" bar"))(H_(2(g)))|H_((xM))^(+)

Answer»

1
2
3
4

Answer :B
43.

Oxidation potential of unimolar calomel electrode is

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`0.242 V`
`-0.28V`
`-0.33 V`
`-0.43 V`

ANSWER :B
44.

Oxidation potential of unimoles of calomel is

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`+ 0.25` V
`0.00`V
`+0.278 V`
`-0.28V`

SOLUTION :CALOMEL is used as a secondary reference electrode. Since Hg is less reactive than H , its STANDARD REDUCTION potential is positive . Hence , its standard oxidation potential must be negative , ie, `-2.28 V` . [As standard reduction potential = -standard oxidation potential.]
45.

Oxidation of which of the following by air in the presence of vanadium pentoxidegivesphenol ?

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TOLUENE
Benzene
benzaldehyde
PHENYL acetic ACID

ANSWER :B
46.

Oxidation oftoluenewith CrO_3 to benzaldehydeis carriedout in thepressureto aceticanhydride

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SOLUTION :DURINGTHE oxidationoftoluenewith ` CrO_3`as soonasbenzaldehyde is FORMED, itreactswithaceticanhydride to frombenzylinediacetatethischecks thefurtheroxidationof benzaldehydre to BENZOICACID
47.

Oxidation of toluene with CrO_(3) in the presence of (CH_(3)CO)_(2)O gives a product 'A' which on treatment with aqueous NaOH produces

Answer»

`C_(6)H_(5)CHO`
`(C_(6)H_(5)CO)_(2)O`
`C_(6)H_(5)COONA`
2,4-diacetyl toluene

Solution :
48.

Oxidation of toluene with CrO_(3) in the presence of (CH_(3)CO)_(2)O gives a product 'A' which on treatment with aq. NaOH gives :

Answer»

2, 4- Diacetyl toluene
`C_(6)H_(5)CHO`
BENZOIC abhydride
`C_(6)H_(5)COOC_(2)H_(5)`.

Answer :B
49.

Oxidation of toluene to benzaldehyde by chromyl chloride is called

Answer»

Rosenmund reaction
WURTZ reaction
Etard reaction
FITTIG reaction

Answer :C
50.

Oxidation of toluene by chromium oxide in acetic anhydride gives

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BENZALDEHYDE
BENZOIC ACID
BENZOPHENONE
acetophenone

Answer :A