Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

KMnO_(4)gets reduced to

Answer»

`K_(2)MnO_(4)` in neutral medium
`MnO_(2)` in acidicmedium
`MN^(2+)` in ALKALINE medium
`MnO_(2)` in neutralmedium

SOLUTION :`KMnO_(4)` is reduced to `MnO_(2)` in neutral medium
`2KMnO_(4) + H_(2)O rarr 2MnO_(2)+ 2KOH+3(O)`
or `MnO_(4)^(-) + 2H_(2)O+ 3E^(-) rarr MnO_(2) + 4OH^(-)`
In alkaline medium, it is reduced to `K_(2)MnO_(4)` or `MnO_(2)` . In acidic medium, it is reduced to `Mn^(2+)`
2.

KMnO_(4),and K_(2)Cr_(2)O_(7) are replaced in volumetric analysis by

Answer»

LA(III) salts
Ce (III) salts
Ce (IV) salts
Gd (III) salts

Answer :C
3.

KMnO_(4)acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is:

Answer»

`(2)/(5)`
`(3)/(5)`
`(4)/(5)`
`(1)/(5)`

ANSWER :a
4.

KMnO_4 will oxidised acetylene to

Answer»

ETHYLENE glycol
Ethyl alcohol
Oxalic ACID
Acetic acid

Solution :`{:(CHoverset(KMnO_4)to,COOH),("|||","|"),("Acetylene","Oxalic acid"):}`
5.

KMnO_(4) reacts with oxalic acid according to the equation 2MnO_(4)^(-)+5C_(2)O_(4)^(2-)+16H^(+) to 2Mn^(2+)+10CO_(2)+8H_(2)O Here, 20 mL of 0.1 M KMnO_(4) is equivalent to:

Answer»

120 ML of 0.25 M `H_(2)C_(2)O_(4)`
150 mL of 0.10M `H_(2)C_(2)O_(4)`
25 mL of 0.20 M `H_(2)C_(2)O_(4)`
50 mL of 0.20 M `H_(2)C_(2)O_(4)`

Answer :C
6.

KMnO_(4) reacts with KI in basic medium to from I_(2) and MnO_(2). When 250 mL of 0.1 M KI solution is mixed with 250 mL of 0.02 M KMnO_(4) in basic medium, what is the number of moles I_(2)formed ?

Answer»

0.015
0.0075
0.005
0.01

Answer :B
7.

KMnO_4 oxidises oxalic acid in acidic medium. The number of CO_2 molecules produced as per the balanced equation is

Answer»

10
8
6
3

Solution :(a) 10 MOLES of CO, are PRODUCED.
8.

KMnO_(4) on heating to red hot gives

Answer»

`K_(2)MnO_(4)+ MnO_(2)+O_(2)`
`K_(2)MnO_(3) + MnO_(2)+ O_(2)`
`K_(2)O+ MnO_(2)+ O_(2)`
None of these

Answer :B
9.

KMnO_4 oxidises oxalates to ____

Answer»

CO
`CO_3^(2-)`
`CO_2`
`HCO_3^-`

ANSWER :C
10.

KMnO_4 oxidation of which of the following will produce terephthalic acid?

Answer»

o-xylene
m-Diemethyl BENZENE
p-Diethyl benzene
m-xylene

Solution :
In this (A) gives phthalic ACID while (B) and (D) GIVE isophthalic acid.
11.

KMnO_(4) on reaction with KOH does not give…

Answer»

`H_(2)O`
`MnO_(2)`
`K_(2)MnO_(4)`
`[O]`

Solution :`K_(2)MnO_(4), H_(2)O and [O]` are OBTAINED as products
12.

KMnO_4 on heating above 200@C gives:

Answer»

`K_2MnO_3 + O_2 + MnO_2`
`K_2MnO_4 + MnO_2 + O_2`
`MnO_2 + O_2`
None

Answer :A
13.

KMnO_(4) is prepared by

Answer»

passing `Cl_(2)` through `K_(2)MnO_(4)` SOLUTION
passing `O_(2)` through `K_(2) MnO_(4)` solution
reaction of KOH with `KMnO_(4)`
Fusion of KOH with `MnO_(2)`

Solution :Passing `Cl_(2) ` through `K_(2) MnO_(4)` solution.
14.

KMnO_4 is prepared by:

Answer»

PASSING `Cl_2` through `K_2MnO_4` solution
Passing `O_2` through `K_2MnO_4` solution
Reaction of KOH with `KMnO_4`
FUSING KOH with `MnO_2`

ANSWER :A
15.

KMnO_(4) is iso stuctural with

Answer»

`KClO_(4)`
`HClO_(4)`
`K_(3)BO_(3)`
None

Solution :`KMnO_4` has tetrahedral structure, Same for `KClO_4, HClO_4`
16.

KMnO_(4) is oxo salt of….

Answer»

`MnO_(2)`
`MnO_(3)`
`Mn_(2)O_(7)`
`Mn_(2)O_(3)`

Solution :`Mn_(2)O_(7) + 2KOH rarr 2KMnO_(4) + H_(2)O`
17.

KMnO_(4) in alkaline medium changes to ….

Answer»

`MN^(3+)`
`MnO_(2)`
`MnO_(4)^(2-)`
`Mn(OH)_(4)^(-)`

Solution :`2KMnO_(4) + H_(2)O overset(-OH)rarr 2MnO_(2) + 2KOH + 3[O]`
18.

KMnO_(4) is powerful oxidant where it converts into

Answer»

`MnO_(4)^(2-)`
`MnO_(2)`
`MN^(2+)`
`Mn^(3+)`

Answer :B
19.

KMnO_(4) does not act as oxidising agent in the presence of HCI. Why?

Answer»

SOLUTION :HCl cannot be used for making ACIDIFIED `KMnO_(4)` as OXIDISING agent, since it reacts with `KMnO_(4)` as FOLLOWS
`2MnO_(4)^(-)+10CI^(-) + 16H^(+) to2Mn^(2+) + 5Cl_(2) +8H_(2)O`
20.

KMnO_(4) can be prepared from K_(2)MnO_(4) as per the reaction 3MnO_(4)^(2-) + 2H_(2)O hArr 2MnO_(4)^(2-) + MnO_2 + 4OH^- The reaction can go to completion by removing OH^(-) ions by adding.

Answer»

KOH
`CO_2`
`SO_2`
HCl

Answer :B
21.

KMnO_(4) does not act as oxidising agent in the presence of HCl. Why ?

Answer»

Solution :HCL cannot be used for making acidified `KMnO_(4)` as oxidising AGENT, SINCE it reacts with `KMnO_(4)` as FOLLOWS.
`2MnO_(4)^(-) + 10 Cl^(-) + 16H^(+) rarr 2Mn^(2+) + 5Cl_(2) + 8H_(2)O`
22.

KMnO_4 can not oxidize

Answer»

`NO_(2)^(-)`
`FE^(2+)`
`CL^(-)`
`F^(-)`

ANSWER :D
23.

KMnO_(4) can be prepared from K_(2)MnO_(4)as per the reaction : 3MnO_(4)^(2-) + 2H_(2)O hArr2MnO_(4)^(-) + 4OH^(-) Thereaction can go to completion by removing OH^(-) ions by adding

Answer»

HCl
KOH
`CO_(2)`
`SO_(2)`

Solution :`3MnO_(4)^(2-) + 2H_(2)O hArr 2MnO_(4)^(-) + MnO_(2) + 4OH^(-)`
The reactioncan GOTO completion by removing `OH^(-)` ions by adding `CO_(2)` as it reacts with `OH^(-)` ion to form `CO_(3)^(2-)` ions
`4OH^(-) + 2CO_(2) rarr2CO_(3)^(2-) + 2H_(2)O`
24.

KMnO_(4) can be prepared from K_(2)MnO_(4) as per the reaction, 3MnO_(4)^(2-)+2H_(2)O hArr 2MnO_(4)^(2-)+MnO_(2)+4OH^(-) The reaction can go to completion by removing OH^(-) ions by adding.

Answer»

KOH
`CO_(2)`
`SO_(2)`
`KCl`

Solution :HCl and `SO_(2)` are reducing AGENTS and can REDUCE `MnO_(4)^(-).CO_(2)` which is neither oxidising and nor reducing will provide only acidic medium. It can shift reaction in forward direction and reaction can go to COMPLETION.
25.

KMnO_(4) can be prepared from K_(2)MnO_(4) as per reaction 3MnO_(4)^(2-)+2H_(2)OhArr2MnO_(4)^(-)+MnO_(2)+4OH^(-)

Answer»

HCl
KOH
`CO_(2)` is formed as the product
`sO_(2)`

Solution :Since,`OH^(-)` are generated from weak acid`(H_(2)O)`. A weak acid (like `CO_(2)`) should be used to remove it because strong acid (HCl) reverse the reaction . KOH INCREASES the concentration of `OH^(-)`,thus again sgifts the reaction in backward side . `Co_(2)` COMBINES with `OH^(-)` to give carbonate which is easily removed. `SO_(2)`react with water to give strong acid , so it cannot be used.
26.

KMnO_(4) can be prepared from K_(2)MnO_(4) as per the reaction 3MnO_(4)^(2-)+2H_(2)O hArr 2MnO_(4)^(-)+MnO_(2)+4OH^(-) The reaction can go to completion by removing OH^(-) ions by adding

Answer»

`SO_(2)`
`HCL`
`KOH`
`CO_(2)`

ANSWER :D
27.

KMnO_4 acts as oxidising agent in

Answer»

ACIDIC medium
neutral medium
alkaline medium
all of the above

Answer :D
28.

KMnO_(4) acts as an oxidizing agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one moleof sulphide ions in acidic solution is

Answer»

`(2)/(5)`
`(3)/(5)`
`(4)/(5)`
`(1)/(5)`

Solution :`2KMnO_(4)+ 3H_(2)SO_(4) rarr K_(2)SO_(4) + 2MnSO_(4) + 3H_(2)O + 5(O)`
`H_(2)S+ (O) rarrH_(2)OI +S ] xx 5`
`bar ( 2KMnO_(4) + 3H_(2)SO_(4) + 5H_(2)Srarr K_(2)SO_(4) + 8 H_(2)O5S)`
1 mole of `S^(2-)` ions will required`KMnO_(4) = ( 2)/( 5) `moles
29.

KMnO_(4) acts as an oxidising agent in the presence of dil H_2 SO_4. Its equivalent weight is (M is molecular weight)

Answer»

`M/(2)`
`M`
`M/5`
`M/3`

ANSWER :C
30.

KMnO_(4) acts as an oxidising agent in alkaline medium. When alkaline KMnO_(4) is treated with KI, iodide ion is oxidised to "…........."

Answer»


SOLUTION :`2KMnO_(4) + H_(2)O + KIrarr 2MnO_(2) + 2KOH + KIO_(3)`
or `I^(-)+ 6OH^(-) RARR IO_(3)^(-) + 3H_(2)O + 6E^(-)`
31.

KMnO_(4) acts as an oxidising agent in alkaline medium. When alkaline KMnO_(4) is treated with KI, iodide ion is oxidised to …..

Answer»

`I_(2)`
`IO^(-)`
`IO_(3)^(-)`
`IO_(4)^(-)`

SOLUTION :`I^(-) + 2MnO_(4)^(-) + H_(2)O rarr 2OH^(-) + 2MnO_(2) + IO_(3)^(-)`
32.

KMnO_(4) acts as an oxidising agent in acidic medium. When alkaline KMnO_4 is treated with KI, iodide ion is oxidised to

Answer»

`I_2`
`IO^(-)`
`IO_(3)^(-)`
`IO_(4)^(-)`

SOLUTION :`2KMnO_4 + KL + H_2O RARR 2MnO_2 + 2KOH + KIO_3`
33.

KMnO_(4) acts as an oxidising agent in alkaline medium. When alkaline KMnO_(4) is treated with KI, iodide ion is oxidised to……… .

Answer»

`I_2`
`IO^(-)`
`IO_(3)^(-)`
`IO_(4)^(-)`

SOLUTION :`2KMnO_4 + Kl + H_2O rarr 2MnO_2 + 2KOH + KIO_3`
34.

It is found that 16.5 g of metal combine with oxygen to form 35.60 g of metal oxide. Calculate the percentage of metal and oxygen in the compound.

Answer»

SOLUTION :MASS of OXYGEN in OXIDE `=(35.60-16.50)=19.10g`
% of METAL `=(16.50)/(35.60)xx100=46.3`
% of oxygen `=(19.10)/(35.60)xx100=53.7`
35.

It is found that 0.01 M solution of four sodium salts Na, Nal, NaC and NaD have the following pH values: (i) NaD - 10.0 (ii) NaC = 9.0 (iii) NaB - 8.0 (iv) Na4 - 7.0 Which of the corresponding acids is strongest?

Answer»

NAA
NaB
NaC
NAD

Solution :`pH = 10`(NaD )showsthat thesolutionin stronglybasic i.e., NaDis asaltofstrongbaseandweakacid
SimilarlypH=9and pH = 8refertobasicsolution
But pH =7 (NaA) showsthat thesolutionin neutrali.e.,NaA is a saltofstong acidacidstrongbase .
36.

KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is

Answer»

`2//5`
`3//5`
`4//5`
`1//5`

Solution :`underset("2 mol")(2KMnO_4) + 3H_(2)SO_(4) rarr K_2SO_4 + 2MnSO_(4) + 8H_(2)O + 5S`
`therefore `1 MOLE of `S^(2-)` ions will REQUIRE `KMnO_4 = (2)/(5)` moles.
37.

It is easier to prepare alkenes by dehydrohalogenation of ___________.

Answer»

ALKYL bromide
alkyl iodine
alkyl chloride
alkyl fluoride

Answer :B
38.

KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is…..

Answer»

`(2)/(5)`
`(3)/(5)`
`(4)/(5)`
`(1)/(5)`

Solution :`(2)/(5) MnO_(4)^(-) + S^(2-) + (16)/(5) H^(+) rarr (2)/(5) Mn^(2+) + S + (8)/(5) H_(2)O`
39.

It is due to release of _______ from CFCs,CCl_4 depletion of ozone takes place in ________.

Answer»


ANSWER :A::C
40.

KMnO_4acts as an oxidising agent in

Answer»

Acidic MEDIUM only
Neutral and acidic medium
Neutral and ALKALINE medium
Neutral, acidic and fairly BASIC medium

Answer :D
41.

It is easy to substitute -Cl in 2,4-dinitrochlorobenzene than in chlorobenzene because _________.

Answer»

NITRO GROUP donates `E^(-)` at ortho/paraposition.
Nitro group withdraws `e^(-)` at metaposition
Nitro group donates `e^(-)` META position
Nitrogroup donates `e^(-)` at ortho/para position

Answer :D
42.

KMnO_(4) act as oxidising agent in netural medium. It accept how many electrons to convert MnO_(2).

Answer»

2
3
4
5

Answer :B
43.

Why has it been difficult to study the chemistry of radon?

Answer»

SOLUTION :RADON is a radioactive element with very SMALL halflife(3.82 DAYS) . HENCE , it isdifficultto studyits chemistry.
44.

KMnO_(4) acts as an oxidising agent in

Answer»

ACIDIC MEDIUM only
Neutral and acidic medium
Neutral and ALKALINE medium
Neutral, acidic and FAIRLY BASIC medium

Answer :D
45.

It is desired to prepare 100 ml of a buffer of pH 5.00. Acetic, benzoic and formic acids and their salt are availble for use. Which acid should be used for maximum effectiveness against increase in pH ? What acid-salt ratio should be used ? pK_a values of these acids are : acetic 4.74, benzoic 4.18 and formic 3.68.

Answer»


Answer :ACETIC acid, salt-acid MOLAR RATIO 1:8 :1
46.

KMnO_(4) acts as an oxidising agent in alkaline medium. When alkaline KMnO_(4)is treated with KI, iodide ion is oxidised to

Answer»

`I_(2)`
`IO^(-)`
`IO_(3)`
`IO_(4)^(-)`

Solution :`Cr^(3+) : 3D^(3)`
`MU = sqrt(n(n+1)) B.M.`
` = sqrt(3(3+2))`
` = 3.87` B.M.
47.

It is desired to increase of the volume of a gas by 20% without changing the pressure. To what temprature the gas must be heated if the initial temperature of the gas is 27^(@)C.

Answer»

<P>

Solution :Let VOLUME at `27^(@)C=V cm^(3)`
Final volume `=V+V=(20)/(100) =1.2 V`
`therefore V_(1)-v_(1)" "T_(1)=300 K, V_(2)=1.2 V T_(2)=`?
At constant `P, (V_(1))/(T_(1))=(V_(2))/(T_(2)) RARR (V)/(300) =(1.2 V)/(12)`
`therefore T_(2) =360 K =(360-273)^(@)C=87^(@)C`
48.

KMnO_4 act as an oxidising agent in :

Answer»

ACIDIC medium
Alkaline medium
Neutral medium
All of the above media

Answer :D
49.

It is dangerous to leave the car engine running in a closed garage, because it may cause serious pollution due to poisoning by emission of:

Answer»

`CO_2`
`CO`
UNBURNT PETROL
`SO_2`

ANSWER :B
50.

KMnO_(4) (acidic / alkaline ) is not decolurised by

Answer»

MOHR salt
oxalic acid
BENZENE
PROPENE

Solution :Benzene does not decolourise `KMnO_(4)` (acidic/alkaline) It is due to the delocalization of `pi` - electron in benzene. Mohr.s salt and oxalic and give redox reaction with `KMnO_(4)` . Propene decolorise `KMnO_(4)` due to PRESENCE of `C=C` bond.