This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
In reaction of alcohols with alkali metal which of the following alcohols will react fastest |
|
Answer» secondary |
|
| 2. |
In reaction of alcohols with alkali metal, acid etc. which of the following alcohol will react fastest |
|
Answer» Secondary |
|
| 3. |
In reaction N_(2(g))+3H_(2(g))hArr2NH_(3(g)),DeltaH=-93.6kJ, the yield of ammonia does not increase when |
|
Answer» PRESSURE is INCREASED |
|
| 4. |
In reaction of alcohols with alkali metal, acid etc. which of the following alcohol will react fastest ? |
|
Answer» Secondary |
|
| 5. |
In reaction H_2(g) + Cl_2(g) = 2HCl (g) relation between K_p and K_c is _____. |
|
Answer» |
|
| 6. |
Name the reaction where Lewis acid is used as catalyst for aromatic alkylation. |
|
Answer» |
|
| 7. |
In reaction CaF_(2)+H_(2)SO_(4)rarrCaSO_(4)+2HF 6kg of CaF_(2) are treated with an excess of H_(2)SO_(4) and yield 2.0kg of HF. Percentage yield of reaction is: |
|
Answer» 0.5 `n_(CaF_(2))"USED"=(0.1)/(2)` `w_(CaF_(2))"used"=3.9kg` `% "yiled"=(3.9)/(6)xx100=65%` |
|
| 8. |
In reaction, CO(g) +2H_2(g) hArrCH_3OH(g)DeltaH=-92kJ//mol^(-1) Concentrations of hydrogen, carbon monoxide and methanol become constantat equilibrium . What will happen if (a) volume of the reaction vessel in which reactants and products are contained is suddenly reduced to half ? (b) partial pressure of hydrogen is suddenly doubled ? (c ) an inert gas is added to the system at constant pressure ? (d) the temperature is increased ? |
|
Answer» Solution :For the equilibrium, `CO(g) +2H_2 (g) hArr CH_3 OH(g)` `K_c=([CH_3OH])/([CO][H_2]^2)` `K_p=(P_(CH_3OH))/(P_(CO)xxP_(H_2)^2)` (a) When the volume of the vesselis suddenly reduced to half , the PARTIAL pressures of VARIOUS species gets doubled . Therefore, `Q_p=(2P_(CH_3OH))/(2P_(CO)xx(2P_(H_2))^2)=1/4K_p` SINCE `Q_P` is less than `K_p` , the equilibrium shifts in the forward direction producing more `CH_3OH`. (b) When partial pressure of hydrogen is suddenly doubled, `Q_p` changes and is no longer equal to `K_p`. `Q_p=(2P_(CH_3OH))/(2P_(CO)xx(2P_(H_2))^2)=1/4K_p` Equilibrium will shift from left to RIGHT. When and inert gas is added to the system at constant pressure, equilibrium shift from lower number of moles to higher number of moles(in backward direction). (d) By increasing the temperature, `K_p` will decrease and equilibrium will shift from right to left. |
|
| 9. |
In reaction A(g) to B(g) + C(g) if initial pressure fo A(g)is 100 m.m. of Hg half-life of reaction is found to be 10 minute but if initial pressure of A is 200 mm of Hg half-life of reaction is found to be 2.5 minute then what will be order of reaction ? |
|
Answer» |
|
| 10. |
In reaction 8BF_(3)+6LiH overset(Delta) to X+LIBF_(4) |
|
Answer» `B_(4)H_(10)` |
|
| 11. |
In reaction C_6H_5CH_3overset"oxidation"to A overset"NaOH"to B overset"sodalime"toC Then C is |
|
Answer» `C_6H_6` |
|
| 12. |
In Rast method, Camphor is used as a solvent to determine molecular weight of non-volatile solutes because |
|
Answer» It is readily available |
|
| 13. |
In ramsay - Raylighs second method, the mixture of N_2 and O_2 can be seperated by dissolving in NaOH in the form of |
|
Answer» NITRATES |
|
| 14. |
In Raschig method, chlorobenzene is converted to phenol by ________ |
|
Answer» catalytic OXIDATION |
|
| 15. |
In Ramsay - Ray leight first method, which of the following are used to remove CO_2, O_2 and N_2 respectively |
|
Answer» Soda lime + Potash SOLUTION, red hot Cu & HEATED MG |
|
| 16. |
In Ramsay and Rayleigh's isolation of noble gases from air,the nitrogen of the air is finally converted into |
|
Answer» `NaNO_(2)` only `N_(2)O_(2)to2NO` `2NO+O_(2)to2NO_(2)` `2NO_(2)+2NaOHtoNaNO_(2)+NaNO_(3)+H_(2)O` |
|
| 17. |
In R-S configuration -C-=N group can be represented as |
|
Answer» `-C=N-C` |
|
| 18. |
In radioactive decay which one of the following moves the fastest |
|
Answer» `alpha`-particle |
|
| 19. |
In R '-O-R, the R' is a higher alkyl group, it is come from |
|
Answer» alkane |
|
| 20. |
In quick vinegar process of acetic acid, the temperature of mixture is |
|
Answer» 300 K |
|
| 21. |
In question no. (23) as given above, what would be the molecularity of elementary reaction [a] and [b] respectively? |
|
Answer» 3,3 |
|
| 22. |
In Question pH of the final solution will be |
|
Answer» 12 `pOH=2,pH=14-2=12` |
|
| 23. |
In question 5 rate of use of H^(+) is x mol L^(-1) S^(-1) than (a) Rate of use of Br^(-1) (b)How much is the average rate of formation of Br_(2)? |
| Answer» Solution :`(6)/(5)X mol L^(-1) s^(-1)` (B) 2x mol `L^(-1) s^(-1)` | |
| 24. |
In question 266 step(2) can be thought of an/a: |
|
Answer» Neutralisation |
|
| 25. |
In Question above, the number of ampere hours for which the battery is used containing 1L of the acid is 16.08x ampere hour. Calculate the value of x. |
|
Answer» Decrease in amount of `H_(2)SO_(4)` as batteryyield current `=` Change in molarity `xxMw_(2)xx`VOLUME of ACID in `L` `=(3xx98xx1L)g` Overall change `:` `2F-=2 mol of H_(20SO_(4)` or `1F-=1 mol of H_(2)SO_(4)=98G` `98g H_(2)SO_(4)` requires `=1F` Ampere` //` hour `=(3Fxx96500A-s)/(3600 s h^(-1))` `=80.4 A-h` `:. 16.08x=80.4` `x=(80.4)/(16.08)=5` |
|
| 26. |
When methyl amine is treated with NaNO_2 and HCl, the product obtained is― |
|
Answer» `NO_2` |
|
| 27. |
Which of the mass extinctions are thought to be manmade. |
|
Answer» Neutralisation |
|
| 28. |
Genes involved in cancer are |
|
Answer» `R-CH_2CO_2H` |
|
| 29. |
In Question 266 step (4) can be carried out with NaNO_2 + dil,HCL,The other products of the step is: |
|
Answer» `NO_2` |
|
| 30. |
In Question 266 an intermediate involved in step (3) is: |
|
Answer» `R-CH_2CO_2H` |
|
| 31. |
In qualitative inorganic analysis of basic radicals ydochioric acid is preferred to nitric acid forpreparing a solution of given substance .This is because : |
|
Answer» NITRATES are notdecomposed to selphides |
|
| 32. |
In qualitative inorganic amalysis phosphan , if present is to be elemenated in the apperopriate grest in order to detect the radical : |
|
Answer» `PB^(2+)` |
|
| 33. |
In qualitative analysis when H_(2)S is passed through an aqueous solution ofsalt acidified with dil. HCL, a block precipitate is obtainned .On boiling the precipitate with dil. HNO_(3) it forms a solution of blue colour . Addition of excess ofaqueous solution of ammonia to this solution given ....... . |
|
Answer» deep blue precipitate of Cu `(OH)_(2)` `CuSO_(4)+H_(2)Soverset(dil. HCl)tounderset("blackppt")( CuS +)H_(2)SO_(4)` On boiling CuS with dil. `HNO_(3)` it FORMS a blue coloured solution and the following reactions OCCUR `3CuS+8HNO_(3)to3Cu(NO_(3))_(2)+2NO+3S+4H_(2)O` `S+2HNO_(3)toH_(2)SO_(4)+NO` `2Cu^(2+)+SO_(4)^(2-)+2NH_(3)+2H_(2)OtoCu(OH)_(2)*CuSO_(4)+2NH_(4)OH` `Cu(OH)_(2)*CuSO_(4)+8NH_(3)tounderset("Tetraammine copper"(||)("Deep blue solution"))(2[Cu(NH_(3))_(4)]SO_(4)+2OH^(-)+SO_(4)^(2-)` |
|
| 34. |
In qualitative analysis, when H_2S is passed through an aqueous solution of salt acidified with dil.HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO_3, it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives |
|
Answer» deep BLUE PRECIPITATE of`Cu(OH)_2` `Cu^(2+) + H_(2)S overset(dil HCl) rarr underset("(Black ppt.)")(CuS) + 2H^(+) , "" CuS + underset("(dil)")(2NHO_3) rarr underset("(Blue solution)")(Cu(NO_3)_2) + H_2S` `Cu(NO_3)_2 + 4NH_3 rarr underset("(Deep blue solution)")([Cu(NH_3)_4]^(2+)) + 2NO_(3)^(-)` |
|
| 35. |
In qualitative analysis when H_2S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO_3, it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives ............. |
|
Answer» Deep blue PRECIPITATE of `CU(OH)_2` `underset("dilute")(Cus + 10HNO_(3))to underset("Blue")(Cu(NO_(3))_(2) + 8NO_(2) + 4H_(2)O + H_(2)SO_(4) to NH_(3)(aq) [Cu(NH_(3))_(4)]^(2+)` (Deep blue colour) |
|
| 36. |
In qualitative analysis when H_(2)S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO_(3), it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives........ . |
|
Answer» deep blue precipitate of `Cu(OH)_(2)` `Cu(NO_(3))_(2) + 4NH_(3) rarr underset(("Deep blue solution"))([Cu(NH_(3))_(4)]^(2+)) + 2NO_(3)^(-)` |
|
| 37. |
In qualitative analysis, the metals of Group I can be separated from other ion by precipitating them as chloride salts. A solution initially contains Ag^(+) and Pb^(2+) at a concentration of 0.10 M. Aqueous HCl is added to this solution until the Cl^(-) concentration is 0.10 M. What will the concentrations of Ag^(+) and Pb^(2+) be at equilibrium (K_(sp) for AgCl = 1.8 xx 10^(-10), K_(sp) fr PbCl_(2) = 1.7 xx 10^(-5)) |
|
Answer» `[AG^(+)] = 1.8 xx 10^(-9) M, [Pb^(2+)] = 1.7 xx 10^(-3)M` |
|
| 38. |
In qualitative analysis, in order to detect second group basic radical, HS gas is passed in the presence of dilute HCI to |
|
Answer» increase the dissociation of `H_(2)S` |
|
| 39. |
In Q.No. 11, which of the following reagents can be used to convert (A) to (B)? |
|
Answer» <P>a.Conc. `H_(2)SO_(4)` at `413 K (140^(@)C)` and `P_(2)O_(5)` can be used for the dehydration of alcohols to alkene. So the answers are `(b)` and `(c )`. |
|
| 40. |
In pyrophosphoric acid the number of hydroxy groups present are: |
|
Answer» 4 |
|
| 41. |
In pyranose of glucose oxide (ether) linkage is formed between |
|
Answer» `C_1` and `C_6` |
|
| 42. |
In purine nucleoside, C-1 of sugar from glycosidic linkage with which position of purine |
|
Answer» 1 |
|
| 43. |
In Pt(C_(2)H_(4))_(2)""(C_(2)F_(4)) molecule, in which the platinum and all six carbon atoms are almost coplanar, choose the correct statement(s). |
|
Answer» C-C distance is greater in `C_(2)F_(4)" than "C_(2)H_(4)` .Due to synergic bonding M-C bond (of `C_(4)F_(4)`) becomes stronger. . `C_(2)(CN)_(4)` also has synergic bonding. Due to back donation from metal to `pi^(*)`orbital ,C=C approaches c-c behaviour `(sp^(3))` |
|
| 44. |
In [Pt(NH_(3))_(2)Cl_(2)], pt-Cl bond length is 2 Å and Cl-Cl distance is 2.88 Å then the compound is: |
|
Answer» tetrahedral |
|
| 45. |
In public urinals, we observe some pungent smell. This smell is due to : |
|
Answer» HYDROLYSIS of urea of urine by urease of atmosphere into `NH_3` and `CO_2` |
|
| 46. |
In proteins , the alpha - amino acids are linked by …………........... |
|
Answer» Amide LINKAGE |
|
| 48. |
In pseudo - order reactions |
|
Answer» The actual order of reaction is different from that expected using rate law expression |
|
| 49. |
In problem 8 as mentioned above the wavelength of light emitted in the visibleregion by He^(+)ions after collisions with H atoms is |
|
Answer» `6.5 xx10^(-7)` m |
|