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For an van der Waals' gas, the term ((ab)/(V^(2))) represents some

For an octahedral radius ratio limit is

For an octahedral arrangement the lowest radius ratio limit is

For an nth order reaction the half life period t_(1//2) is proportional to (initial conc = C_(0)) :

for an isomerisation reaction A LeftrightarrowB , the temperature dependence of equilibrium constant is given by log_(e)K =4.0 -2000/T .the value of DeltaS^(@)at 300 K is therefore,

For an isolated system, DeltaU = 0, then

For an irreversible process, if P-V graphs are plotted simply to represents the work involved in the process as the area under the P-V curve.Then which of the following options has/have the correct P-V curve for the mentioned process on an ideal gas placed in a cylinder fitted with a piston.

For an ionic crystal of the general formula AX and co- ordination no. 6, the radius ratio value will be

For an ideal solution of two components A and B, If x_A and y_A are mole fractions of component 'A' in solution and vapour phase respectively, then the slope of linear line in the graph drawn between 1//x_A and 1//y_A is

For an ideal system at thermal equilibrium, the velocity distribution of the constituting particles will be governed by

For anionic crystal of the general formula A^+B^- and coordination number 6, the radius ratio will be:

For an ideal solution containing a nonvlatile solute , which of the following expressions is correctly represented ?

For an ideal monoatomic gas during any process T = kV, find out the molar heat capacity of the gas during the process. (Assume vibrational degree of freedom to be active)

Foran idealmonoatic gas duringanyprocess T= kV, find outthe molar heatcapacityod the gas during the process. (Assme vibrational degree of freedom to beactive )\

For an ideal gas three adiabatic processes are carried out upto same final pressure from same initial state. If adiabatic reversible process ends up at point B and adiabatic single step irreversible process ends up at point C then adiabatic free expansion upto same final pressure will end up at :

For an ideal gas undergoing isothermal change :

For an ideal gas, the relation between the enthalpy change and internal energy at constant temperature is given by

For an ideal gas, the Joule Thomson co-efficient is equal to

For an ideal gas, the heat of reaction at constant pressure and constant volumee are related as

For an ideal-gas reaction 2A + B rarr C + D the value of K_(p) will be :

For an ideal gas four processes are marked as 1,2,3 and 4 on P-V diagram as shown in figure. The amount of heat supplied to the gas in the process 1,2,3 and 4 are Q_(1),Q_(2),Q_(3) and Q_(4) respectively, then correct order of heat supplied to the gas is:

For an ideal gas, number of moles per litre interms of its pressure p, gas constant R and temperature T is :

For an ideal gas, C_(p) and C_(v) are related as

For an ideal binary solution with p_(A)^(@)//p_(B)^(@) which relation between X_(A) ( mole fraction A in liquid phase) and Y_(A) ( mole fraction of A in vapour phase) is correct, X_(B) and Y_(B) are mole fraction of B in liquid and vapour phase respectively: (Given : p_(A)^(@)gtp_(B)^(@))

For an ideal binary liquid with P_(A)^(@) gt P_(B)^(@), which relation between X_(A)? (mole fraction of A in liquid phase) and Y_(A) (mole fraction of A in vapour phase) is correct.

For an ideal gas, compressibility factor is

For an ideal binary liquid solution with P_A^@> P_B^@which relation between X_A (mole fraction of A in liquid phase) and Y_A (mole fraction of A in vapour phase) is correct, X_B and Y_B are mole fraction of B in liquid and vapour phase respectively

For an exothermic reaction, which is true

For an ideal binary liquid mixture

Foran exothermicreactionanactivationenergyof 70 KJ"mole " ^(-1 )andtheenthalpychangeofreactionis 30 KJ"mole" ^(-1). Theorderofthereactionis

For an exothermic reaction, following two steps are involved. "Step 1. "A +B rarrI"(slow)" "Step 2. "IrarrAB"(fast)" Which of the following graphs correctly represent this reaction ?

For an exothermic reaction, equilibrium constant at T_1 and T_2 are respectively K_1 and K_2 If K_1 lt K_2then : -

For an exothermic reaction

For an exothermic chemical process occurring in two steps as (i) A+BtoX (slow) (ii) XtoAB (fast) The progress of the reaction can be best described by

For an exothermic reaction :

For an exothermic chemical process occurring in two steps as i) A+BtoX" (slow)" ii) XtoAB" (fast)" The progress of the reaction can be best described by

The process 2A + B toCtaking place in two steps:1:2A toD"" 2: D + B to C(slow) then rate of reaction gets

For an exothermic chemical process occuring in 2 steps as (i) A+B rarr X (slow) , (ii) X rarr AB (fast) The progress of the reaction can be best described by (x - intermediate).

For an exothermic chemical process occuring in two steps as :A+BrarrX(slow),A+BrarrX(slow)The progress of the reaction can be described by :

For an equilibrium state,

For an equilibrium reaction, if the value of standard Gibb's free energy, AG° is zero, then the value of equilibrium constant, K will be equal to

For an equilibrium [2A(g)

For an endothermic reaction where DeltaH represents the enthalpy of the reaction in kJ/mole, the minimum value for the energy of activation will be

For an endothermic reaction where DeltaH represents the enthalpy of the reaction, the minimum value for the energy of activation will be

For an endothermic reaction where, Delta H represent the enthalpy of the reaction in "kJ"//"mol", the minimum value for energy of activation will be

For an endothermic reaction, where DeltaH represents the enthalpy of the reaction in kJ/mol, the minimum value for energy of activation will be

For an endothermic reaction , energy of activation is E_(a) and enthalpy of reaction is DeltaH (both of these in KJ/mol). Minimum value of E_(a) will be

For an endothermic reaction, where DeltaH represents the enthalpy of the reaction in "kJ"//"mol", the minimum value for the energy of activation will be

For an endothermic reaction, DeltaH represents the enthalpy of the reaction in kJmol^(-1). The minimum of activation energy will be: