This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Cooling takes place when real gas expands adiabatically at |
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Answer» INVERSION temperature`= (2a)/(RB)` |
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| 2. |
Cooling of a gas in an adiabatic expansion is due to ________ . |
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Answer» FALL in temperature |
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| 3. |
Coolent used in car radiator is aqueous solution of ethylene glycol. In order to prevent the solution from freezing at - 0.3 ^(@)C. How much ethylene glycol must be added to 5 kg 18. of water ? (K _(f) =1.86 k kg mol ^(-1)) |
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Answer» Solution :`Delta T_(F) =0.3^(@)C` `Delta T_(f) =0.3^(@)C =(K_(f)xxW_(B) xx1000)/( M _(B)xx W_(A))` `= (1.86xxW_(B) xx1000)/( 62xx500)` `therefore W _(H)=50g` The ammmt used should be more than 50 g. |
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| 4. |
Convulsions is caused due to deficiency of |
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Answer» VIT-`B_6` |
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| 5. |
Cooking is fast in a pressure cooker because : |
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Answer» 1. water boils at a higher TEMPERATURE in a pressure cooker. |
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| 7. |
Converting a freshly precipitated substance into colloidal state by shaking with suitable electrolyte is called……….. |
| Answer» SOLUTION :PEPTIZATION | |
| 8. |
Convert the following into metre (i) 40 Em (thickness of Milky way galaxy) (ii) 1.4 Gm (diameter of Sun) (iii) 41 Pm (distance of nearest star) |
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Answer» |
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| 9. |
Convert the following into kilograms : (i) 500 Mg (mass of loaded jumbo jet) (ii) 1 fg (mass of human DNA molecule) |
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Answer» (II) 1 fgi.e. femto gram `=10^(-15)g=10^(-18)kg` |
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| 10. |
Convert the following (ii) Ethanal to but-2-enal. |
| Answer» Solution :`2CH_(3)CHOoverset(NAOH)underset(dil)toCH_(3)overset(OH)overset(|)CHCH_(2)CHOoverset(H_(3)O^(+)//DELTA)toCH_(2)CH=CHCHO`. | |
| 11. |
Convert the following: (i) Nitro benzene to Benzene (ii) Benzene to Benzic acid |
Answer» SOLUTION :
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| 12. |
Convert the following (i) Ethyl benzene to benzoic acid |
| Answer» SOLUTION :`C_(6)h_(5)C_(2)H_(5)OVERSET(K_2Cr_(2)O_(7)//H^(+))to C_(6)H_(5)COOH`. | |
| 13. |
Convert the following: a, t- Butyl chloride to isobutyl bromide b. Chloroentane to butane c. 2- Chloropropane to 1- bromopropane d. Bromo benzene to p- nitrophenol e. Isopropyl alchol to iodofrom f. 2- Chloropropane to 1- Propanal g. Butene to n- butyliodite h. Ethyl bromideto propanoic acid. i. 2- Methyl prop -1 ene to 2- Chloro -2- methyl propane j. 2- Bromonbutane to 3,4- dimethyl hexane k. Anline to propanenitrile m. Benzyl alcohol to phenyl ethonaic acid n. Benzene to 4- bromo nitro benzene o. Toulenet benzylalchohol p. I- Bromopropane to 2- bromobnpropane q. Ethanol to but -1- yne r. Propane to propan -1-ol |
Answer» SOLUTION :
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| 14. |
Convert propanone into 2-methy-propan-2-o. |
Answer» SOLUTION :
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| 15. |
Convert phenyl magnesium bromide to phenyl methanol (or) How would you prepare phenyl methanol from Grignard reagent? |
| Answer» Solution :`underset("Phyenyl magnesium BROMIDE")(C_(6)H_(5)MgBr) + underset("Methane or Formaldehyde")(HCHO) overset("Ether")to C_(6)H_(5) -overset(H)overset(|)underset(H)underset(|)C - OMgBr overset(H_(2)O//H^(+)) to underset("PHENYL Methanol")(C_(6)H_(5) - CH_(2)OH) + Mg(OH)BR` | |
| 16. |
Convert propanoic acid into 2-Bromopropanoic acid. |
| Answer» Solution :`underset("PROPANOIC ACID")(CH_(3)-CH_(2))-COOH+Br_(2) underset(NaOH)overset("RED P")to underset("2-Bromoproapnoic acid")(CH_(3)-underset(Br)underset(|)(CH)-COOH)` | |
| 17. |
Convert phenyl magnesium bromide into Benzoic acid? |
Answer» SOLUTION :
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| 18. |
Convert phenol into aniline. |
Answer» Solution :PHENOL REACTS with ammonia at `300^(@)C` in the PRESENCE of anhydrous `ZnCl_(2)` to GIVE aniline.
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| 19. |
Convert methyl amine (1^(@) " primary amine ) to "2^(@),3^(@) amine and Quarternary ammonium salt. |
Answer» SOLUTION :
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| 20. |
Convert methanamine into Ethanamine. |
| Answer» SOLUTION :`underset("Methanamine")(CH_(3)NH_(2))overset(HNO_(2))(to) underset("Methanol")(CH_(3)OH)overset(PCl_(5))(to)underset("METHYL CHLORIDE")(CH_(3)Cl) overset(KCN)(to) underset("ETHANE nitrile")(CH_(3)CN)overset(Na//C_(2)H_(5)OH)(to) underset("Ethanamine")(CH_(3)CH_(2)NH_(2))` | |
| 21. |
Convert m- dinitrobenzene to m-nitro aniline. |
Answer» SOLUTION :
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| 22. |
Convert in not more than four steps. Also mention the temperature and reaction conditions. |
| Answer» SOLUTION :` (##KSV_CHM_ORG_P2_C15_E01_183_S01.png" WIDTH="80%">. | |
| 23. |
Convert in exactly four steps. Select the regent from the given set and write the four digit number in correct sequence. {:(,(1),"Aqueous KOH",(2),CH_(2)N_(2)//Ag","Delta//H_(2)O),(,(2),CHCl_(3)//KOH,(4),CO_(2)//H^(+)),(,(5),KCN,(6),SOCl_(2)),(,(7),Br_(2)//KOH,(8),Mg//dry " ether"):} |
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| 24. |
Convert : (iii) Acetaldehyde to-2-butanol |
Answer» SOLUTION : .
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| 25. |
Convert: (i) Ethanoic acid to propanoic acid. (ii) Ethanol to propanone. |
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Answer» SOLUTION :The conversion are carried out as under: (i) `underset("Ethanoic acid")(CH_(3)COOH)overset(LiAlH_(4))(to)underset("Ethanol")(CH_(3)CH_(2)OH)overset(PCl_(5))(to)underset("Chloroethane")(CH_(3)CH_(2)Cl)overset(KCN)(to)underset("Propane nitrile")(CH_(3)CH_(2)C-=N) overset(H_(2)//H^(+))(to)underset("Propaoic acid")(CH_(3)CH_(2)COOH)`
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| 26. |
Convert : (ii) Malonic acid to acetic acid |
Answer» SOLUTION : .
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| 27. |
Convert : (i) Benzaldehyde to acetophenone |
Answer» SOLUTION : .
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| 28. |
Convert (i) 3-Methylaniline into 3-nitrotoluene (ii) Aniline into 1,3,5-Triboromobenzene. |
Answer» SOLUTION :
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| 29. |
Convert : (i)Acetophenone to ethylbenzene (ii) Ethanal to 2-aminoethanoic acid (iii) Methyl chloride to ethanoic acid. |
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Answer» Solution :The given conversions can be carried out as under : (i) `underset("Acetophenone")(C_(6)H_(5)-overset(O)overset(||)C-CH_(3)) overset(NH_(2)-NH_(2))underset(KOH, "Glycol")to underset("Ethylbenzene")(C_(6)H_(5)CH_(2)CH_(3))` This reaction can also be carried out USING Zn — Hg/HCl (ii) `underset("Ethanol")(CH_(3)CHO) overset([O])underset(KMnO_(4)//H_(2)SO_(4))to CH_(3)COOH overset("RED" P//Cl_(2))to underset("2-chloroethanoic acid")(underset(Cl)underset(|)(CH_(2)COOH)) overset(NH_(2))to underset("2-Aminoethanoic acid")(underset(NH_(2))underset(|)(CH_(2)COOH)` (iii) `underset("Methyl CHLORIDE")(CH_(3)Cl+ KCN) to CH_(3)CN + H_(2)O overset(H^(+))to underset("Ethanoic acid")(CH_(3)COOH)` |
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| 30. |
Convert hex-4-ennitrile to hex-4-enal. |
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Answer» Solution :Diisobutyl aluminium HYDRIDE (DIBAL - H) selectively reduces the alkyl cyanides to form imines which on hydrolysis GIVES aldehydes. Example : `underset("hex-4-ennitrile")(CH_(3)-CH=CH-CH_(2)-CH_(2)-CN)underset("II)"H_(2)O)OVERSET("i)"ALH(t-bu)_(2))tounderset("hex-4-enal")(CH_(3)-CH=CH-CH_(2)-CH_(2)-CHO)` |
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| 31. |
Convert : (i) 3-Methylamiline into 3-nitrotoluene "(ii) " Aniline into 1, 3, 5-tribromobenzene. |
Answer» SOLUTION :STEPS INVOLVED in the CONVERSIONS are GIVEN below :
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| 32. |
Convert : Ethyl alcohol into diethyl ether. (ii) Acetone to tertiary butyl alcohol. |
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Answer» Solution :(i) `underset("Ethyl alcohol")(2C_(2)H_(5)OH)overset("conc. "H_(2)SO_(4))underset("413 K")rarrunderset("Diethyl ether")(C_(2)H_(5)OC_(2)H_(5))+H_(2)O` (ii) `underset("Acetone")(CH_(3)-overset(O)overset(||)C-CH_(3))+CH_(3)MgBrrarr CH_(3)-overset("OMgBr")overset("|")underset(CH_(3))underset("|")"C "-CH_(3)overset(H_(2)O //H^(+))rarr underset("Tertiary butyl alcohol")(CH_(3)-underset(CH_(3))underset("|")overset(OH)overset("|")"C "-CH_(3))` |
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| 33. |
How will youconvert ethylamine to methylamine ? |
Answer» SOLUTION :
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| 34. |
Convert Ethanamine into Methanamine. |
Answer» SOLUTION :
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| 35. |
Convert: Cyanobenzene to Cinnamaldehyde |
Answer» SOLUTION :
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| 36. |
Convert D-erythrose to next higher aldose. |
Answer» SOLUTION :
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| 37. |
Convertchloroform tochlorobenzenein threestepsusingappropriatereagents |
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Answer» SOLUTION : |
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| 38. |
Convert C_(6)H_(6) "to" C_(6)H_(5)D. |
Answer» SOLUTION :
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| 39. |
Convert C_(6)H_(5)COOH TO C_(6)H_(5)NH_(2). |
Answer» SOLUTION :
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| 40. |
Convert benzene to aniline using the following reagents in correct order: alkaline KMnO_(4) followed by HC,NH_(3), heat, Br_(2)//KOH,CH_(3)Cl//anhyd. AlCl_(3). |
Answer» SOLUTION :
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| 41. |
Convert benzene to adjacent trimethyl benzene. |
Answer» SOLUTION : `(Me-)` group is `o,p-` directing, so `p-` POSITION has to be BLOCKED by SULPHONATION or by bulky `t-` butyl group.
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| 42. |
Convert benzene to a-tetralone. |
Answer» SOLUTION :
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| 43. |
Convert benzene diazonium chloride to benzoic acid. |
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Answer» Solution :`UNDERSET("Renzene DIAZONIUM chloride")(C_(6)H_(5)N_(2)^(+)Cl^(-))+underset("HYDRO FLUORO boric acid")(HBF_(4))tounderset("Benzenediazonium fluoroborate")(C_(6)H_(5)N_(2)^(+)BF_(4)^(-))` `C_(6)H_(5)N_(2)^(+)BF_(4)^(-)+CH_(3)COOHto underset("Benzoic acid")(C_(6)H_(5)COOH)+BF_(3)+CH_(3)F` |
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| 44. |
Convert Benzene diazonium chloride into phenol. |
| Answer» Solution :`underset("Benzerne diazonium CHLORIDE")(C_(6)H_(5)N_(2)Cl)+H_(2)O underset(283K)OVERSET(Delta)(to) underset("Phenol")(C_(6)H_(5)OH)+N_(2)+HCL` | |
| 45. |
Convert benzene diazonium chloride into : (i) Benzene (ii) Phenol(iii) Iodobenzene ? |
Answer» SOLUTION :![]()
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| 46. |
Convert: Benzaldehyde to acetophenone |
Answer» SOLUTION :
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| 47. |
Convert aniline to sulphanilic acid. |
Answer» SOLUTION :
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| 48. |
Convert aniline to phenylisocyanide. |
Answer» SOLUTION :
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| 49. |
Convert aniline to p-nitro aniline. |
Answer» Solution :To get PARA product, the `-NH_2` group is protected by acetylation with acetic anhydride. Then, the NITRATED product is HYDROLYSED to form the product.
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| 50. |
Convert aniline into the following compounds (i) N-phenyl benzamide (ii) Phenyl isothiocyanate (iii) 2,4,6- tribromo aniline (iv) Sulphanilinic acid(v) Phenyl isocyanide. |
Answer» Solution :(i) `underset("Aniline")(C_(6)H_(5)NH_(2)+C_(6)H_(5)COCL overset("Pyridine")(to)C_(6)H_(5)NH-underset(N-"PHENYL benzamide")underset(O)underset(||)(C)-C_(6)H_(5)+HCl` (v) `C_(6)H_(5)+underset("Chloroform")(CHCl_(3))+3KOH to underset("PHenyl isocyanide")(C_(6)H_(5)NC+3KCl+2H_(2)O` |
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