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For the following cell Zn(s)|ZnSO_(4)(aq)||CuSO_(4)(aq)|Cu(s) when the concentration of Zn^(2+) is 10 times the concentration of Cu^(2+), the expression for DeltaG (in 1 mol^(-1)) is [F is faraday constant, R is gas constant, T is temperature, E^(@)(cell)=1.1V]

For the following compounds, which is the strongest base and which the strongest acid ?

For the following compounds, the correct statement(s) with respect to nucleophilic substitution reaction is(are)

For the following cell Zn(s)|ZnSO_4 (aq) ||CuSO_4 (aq)|Cu(s) When [Zn^(2+)] is ten times of [Cu^(2+)] the expression Delta G( in J mol^-1) is

For the following cell Zn//Zn^(2+) // Cd^(2+) // CdE_("cell") = 0.30V and E_("cell")^@ = 0.36V. Then the value of [Cd^(2+)]//[Zn^(2+)] is

Forthe followingcell reaction Ag|Ag^(+)|AgCI|CI^(-)|CI_(2) Pt triangle G_(f)^(@)(Ag^(+))=78 Kj // mol E^(@) of the cellis E^(@) ofthe cell is

For the following cell reaction, Ag|Ag^(+)|AgCl|Cl^(Theta)|Cl_(2),Pt DeltaG_(f)^(o)(AgCl)=-109kJ//mol DeltaG_(f)^(o)(Cl^(Theta))=-129kJ//mol DeltaG_(f)^(o)(Ag^(+))=78kJ//mol E^(o) of the ell is:-

For the following cell reaction,Ag | Ag^(+) | AgCl | Cl^(-) | Cl_(2) , PtDelta G_(f)^(0) (AgCl) =-109 kJ//molDelta G_(f)^(0) (Cl ) = -129kJ//molDelta G_(f)^(0) (Ag^(+)) = 78 kJ//mol E^@ of the cell is

For the following acids the rate of decarboxylation on heating would be I. CH_(6)H_(5)-overset(O)overset(||)(C)-CH_(2)-COOH "" (II) C_(6)H_(5)-overset(O)overset(||)(C)-COOH III. CH_(3)-CH_(2)-COOH "" IV. HOOC-CH_(2)-COOH

For the following: (a) I^(-) (b) Cl^(-) (c) Br^(-) The increasing order of nucleophilicity would be

For the following Assertion and Reason the correct option is: Assertion: For hydrogenation reactions, the catalytic activity increases from Group 5 to Group 11 metals with maximum activity shown by Group 7-9 elements. Reason: The reactants are most strongly adsorbed on group 7-9 element

For the following : (a) I^(-) (b) Cl^(-) (c ) Br^(-) the increasing order of nuclkeophilicity would be ……

For the fission reaction ._(92)U^(235) + ._(0)n^(1) rarr ._(56)Ba^(140) + ._(y)E^(x) + 2 ._(0)n^(1) The value of x and y will be

For the folliwng reaction if equal mass of A and B are taken : A+2BrarrC Which of the following is/are correct? (M_(A) and M_(B) are molar masses of A and B respectively)

For the first row transition metals, the E^(@) values are {:(e^(@),V,Cr,Mn,Fe,Co,Ni,Cu),((M^(2+)//M),-1.18,-0.91,-1.18,-0.44,-0.28,-0.25,+0.34):} Explain the irregularity in the above values.

For the first row transition metals, the E^(@) values are {:(,E^(@),V,Cr,Mn,Fe,Co,Ni,Cu),(,(M^(2+)//M),-1.18,0.90,-1.18,-0.44,-0.28,-0.25,+0.34):} What is the reason for the non regularity in the above values?

For the first order thermal decomposition reaction, the following data were obtained: C_(2)H_(5)Cl(g) to C_(2)H_(4)(g)+HCl(g) {:("Time/second","Total pressure/atm"),(""0,""0.30),(""300,""0.50):} Calculate the rate constant. [Given : log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021]

For the first order thermal decomposition reaction, following data was obtained: Calculate the rate constant.

For the first order reactions:

For the first order reaction. N_2O_5(g) rightarrow N_2O_4(g) + 1/2 O_2(g), the volume of O_2 produced is 15 mL and 40 mL after 8 minutes and at the end of the reaction respectively. The rate constant is equal to

For the first order reaction ,the time required for completion of 50% reaction is 100 seconds.The rate the constant will be…..

Forthe firstorderreactionwithhalf lifeis 150seconds ,thetimefortheconcentration of thereactant tofallfromm/ 10tom/100willbeapproximately

For the first order reaction , plot of log_(10)(a-x) against tine 't' is a straight line with slope equal to __________.

For the first order reaction the half life period is (if k is rate constant and a is initial concentration ) :

For the first order reaction, half-life is 14 s. The time required for the initial concentration to reduce to 1//8th of its value is

For the first order reaction, calculate the ratio of the time taken to complete 99% of the reaction to the time taken to complete 90% of the reaction.

For the first order reaction Following observation is made:where V_(t) (in ml) is volume of N_(2) collected at time t and V_(oo) (in ml) is volume of N_(2) collected after a long time. what is the time taken (in minutes) for 75% reaction completion? (log 2 = 0.3)

For the first order reaction Ato product. When the concentration of A is 2.5xx10^(-2) M the activation energy is 20K. Cal/mole. If the conc. of [A] is doubled, at same temperature the activation energy becomes equal to

For the first order reaction, A(g) to B(g) + C(g) + D(s) taking place at constant pressure and temperature condition. Initially, volume of the container containing only A, was found to be 100 l and after time 13.86 minute. it was 150 l. Rateconstant for the reaction is (Use ln 2 = 0.693).

For the first order reaction ArarrB+C , carried out at 27^(@)C if 3.8xx10^(-16)% of the reactant molecules exists in the activated state, the E_(a)(activation energy) of the reaction is :

For the first order reaction :A(g) to 2B(g) + C(g) the half life for the decomposition of Ais 3 min at300 K . Calculate the time (in min ) in which partialpressure of A(g) will drop from 2 bar to 0.5 bar at 400 K. Given activation energy of the reaction is 840 R. [Take : In 2=0.7]

For the first order reaction A to Products, which one of the following is the correct plot of log[A] versus time?

For the first order reaction 2" N"_(2)"O"_(5)(g)to4" NO"_(2)(g)+O_(2)(g)

For the first order reaction:

For the first order reaction 2N_(2)O_(5(g))to4NO_(2(g))+O_(2(g))

For the first order reaction 2 N_(2)O_(5)(g) to 4 NO_(2) (g) + O_(2)(g)

For the first order gas phase decomposition reaction, A(g) to B(g) +C(g) if P_0 is the initial pressure of A and P_t is total pressure after time t, then

For the first order reaction,

For the feasibility of a redox reaction in a cell, the e.m.f. should be

For the extraction of chromium from Cr_(2)O_(3) the process adopted is ___________ process.

For the expression: dG = Vdp - SdT, which of the following is correct?

For the exothermic reaction, A + B to C +D. Delta H is the heat of reaction and Ea is the activation energy. The activation energy for the formation of A + B will be

For the estimation of nitrogen, 1.4 g of an organic compound was diagesed by Kjeldahl method and the evolved ammonia was absorbed in 60 mL of M/10 sulphuric acid. The unreacted acid required 20 mL of M/10 sodium hydroxide for complex neutralization. The percentage of nitrogen in the compound is

For the estimation of N, 1.4g of an organic compound was digested by Kjeldahl method and the evolved ammonia was absorbed in 60mL of (M)/(10)H_(2)SO_(4). The unreacted acid required 20mL of (M)/(10) NaOH for complete neutralisation. The percentage of N in the compound is

For the estimation of potassium permangnate using standard ferrous ammonium sulphate solution: (i) Write the chemical equation for the reaction involved. (ii) Write the equivalent mass of potassium permanganate. (iii) Name the indicator used. (iv) Mention the colour change at the end point.