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601.

Mg can reduce NO−3 to NH3 in basic medium. NO−3(aq)+Mg(s)+H2O→Mg(OH)2(s)+OH−(aq)+NH3(g)A 25.0 mL sample of NO−3 solution was treated with Mg(s). The NH3(g) was passed into 100 mL of 0.15 N HCl. The excess of HCl required 32.10 mL of 0.10 N NaOH for neutralization. What was the molarity of NO−3 ions in the original sample?

Answer»

Mg can reduce NO3 to NH3 in basic medium.

NO3(aq)+Mg(s)+H2OMg(OH)2(s)+OH(aq)+NH3(g)

A 25.0 mL sample of NO3 solution was treated with Mg(s). The NH3(g) was passed into 100 mL of 0.15 N HCl.

The excess of HCl required 32.10 mL of 0.10 N NaOH for neutralization. What was the molarity of NO3 ions in the original sample?

602.

A compound X with molecular formula C3H8O can be oxidised to a compound Y with the molecular formula C3H6O2. X is most likely to be [MP PMT 1991]

Answer»

A compound X with molecular formula C3H8O can be oxidised to a compound Y with the molecular formula C3H6O2. X is most likely to be [MP PMT 1991]



603.

The Edison storage cell is represented as :Fe(s)/FeO(s)/KOH(aq)/Ni2O3 (s)/Ni(s)The half-cell reactions are:Ni2O3(s)+H2O(l)+2e−→2NiO(s)+2OH−;E∘+0.40FeO(s)+H2O(l)+2e−→Fe(s)+2OH−;E∘=−0.87, What is the maximum amount of electrical energy that can be obtained from one mole of Ni2O3 ?

Answer»

The Edison storage cell is represented as :

Fe(s)/FeO(s)/KOH(aq)/Ni2O3 (s)/Ni(s)

The half-cell reactions are:

Ni2O3(s)+H2O(l)+2e2NiO(s)+2OH;E+0.40

FeO(s)+H2O(l)+2eFe(s)+2OH;E=0.87,

What is the maximum amount of electrical energy that can be obtained from one mole of Ni2O3 ?



604.

Find the amount of water present, if the total number of protons is 1.8069×1025.

Answer»

Find the amount of water present, if the total number of protons is 1.8069×1025.

605.

Which one of the following elements, in its diatomic molecular state, has the least bond energy?

Answer»

Which one of the following elements, in its diatomic molecular state, has the least bond energy?



606.

Equal masses of two samples of charcoal A and B are burnt separately and the resulting carbon dioxide are collected in two vessels. The radioactivity of 14C is measured for both the gas samples. The gas from the charcoal A gives 2100 counts per week and the gas from the charcoal B gives 1400 counts per week. Find the age difference between the two samples. Half-life of 14C = 5730 y.

Answer» Equal masses of two samples of charcoal A and B are burnt separately and the resulting carbon dioxide are collected in two vessels. The radioactivity of 14C is measured for both the gas samples. The gas from the charcoal A gives 2100 counts per week and the gas from the charcoal B gives 1400 counts per week. Find the age difference between the two samples. Half-life of 14C = 5730 y.
607.

The solubility of Mg(OH)2 in a particular buffer is found to be 0.95 gL−1. What is the pH of the buffer solution? [Ksp(Mg(OH)2)=1.8×10−11]

Answer»

The solubility of Mg(OH)2 in a particular buffer is found to be 0.95 gL1. What is the pH of the buffer solution? [Ksp(Mg(OH)2)=1.8×1011]

608.

Which of the following is the least stable?

Answer»

Which of the following is the least stable?

609.

Of the following, the one with the largest size is?

Answer»

Of the following, the one with the largest size is?



610.

The correct order of dipole moment is _____

Answer»

The correct order of dipole moment is _____



611.

If we consider 1 and 2 as priority, then which of the following is Z?

Answer»

If we consider 1 and 2 as priority, then which of the following is Z?



612.

Reactivity of Tertiary H, Secondary H and Primary H towards elimination is:

Answer»

Reactivity of Tertiary H, Secondary H and Primary H towards elimination is:

613.

The integrating factor of the differential equation dydx=y tan x−y2 sec x is [MP PET 1995; Pb. CET 2002]

Answer»

The integrating factor of the differential equation dydx=y tan xy2 sec x is


[MP PET 1995; Pb. CET 2002]




614.

2.8 g of a gas at 1 atm and 273 K occupies a volume of 2.24 litres. The gas cannot be:

Answer» 2.8 g of a gas at 1 atm and 273 K occupies a volume of 2.24 litres. The gas cannot be:
615.

For the reactions (i) H2(g) + Cl2(g)⟶2HCl(g) + xKJ(ii) H2(g) + Cl2(g)⟶2HCl(l) + yKJWhich of the following statements is correct?

Answer»

For the reactions (i) H2(g) + Cl2(g)2HCl(g) + xKJ

(ii) H2(g) + Cl2(g)2HCl(l) + yKJ





Which of the following statements is correct?

616.

The decreasing order of solubility of silver halides is:

Answer»

The decreasing order of solubility of silver halides is:

617.

What is the correct order of basic strengths of the given amines in aqueous medium?

Answer»

What is the correct order of basic strengths of the given amines in aqueous medium?

618.

The electrons which take part in order to exhibit variable oxidation states by transition metals are:

Answer»

The electrons which take part in order to exhibit variable oxidation states by transition metals are:



619.

The most stable ion is:

Answer»

The most stable ion is:



620.

A and B are two wires. The radius of A is twice that of B. they are stretched by the same load. Then the stress on B is

Answer» A and B are two wires. The radius of A is twice that of B. they are stretched by the same load. Then the stress on B is
621.

For a reaction, N2O5⟶2NO2+12O2Given:−d[N2O5]dt=k1[N2O5]d[NO2]dt=k2[N2O5]d[O2]dt=k3[N2O5]The relation between k1,k2 and k3 are:

Answer»

For a reaction, N2O52NO2+12O2

Given:

d[N2O5]dt=k1[N2O5]

d[NO2]dt=k2[N2O5]

d[O2]dt=k3[N2O5]

The relation between k1,k2 and k3 are:

622.

The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes is 120 cm with an area of cross section of 1cm2. The conductance of this solution was found to be 5×10−7S. The pH of the solution is 4. The value of limiting molar conductivity (Λ∘m) of this weak monobasic acid in aqueous solution is Z×102Scm−1mol−1. The value of Z is___

Answer» The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes is 120 cm with an area of cross section of 1cm2. The conductance of this solution was found to be 5×107S. The pH of the solution is 4. The value of limiting molar conductivity (Λm) of this weak monobasic acid in aqueous solution is Z×102Scm1mol1. The value of Z is___
623.

The enthalpy of formation of methane at constant pressure and 300K is −75.83KJ. What will be the heat of formation at constant volume? (R=8.3JK−1mol−1)

Answer»

The enthalpy of formation of methane at constant pressure and 300K is 75.83KJ. What will be the heat of formation at constant volume? (R=8.3JK1mol1)



624.

Which of the following shows the correct order of increasing bond dissociation energies?

Answer»

Which of the following shows the correct order of increasing bond dissociation energies?

625.

Which of the following reagents could be used to distinguish between prop-2-en-1-ol and propan-1-ol?

Answer»

Which of the following reagents could be used to distinguish between prop-2-en-1-ol and propan-1-ol?



626.

Osmotic pressure of 0.1 M solution of NaCl and Na2SO4 will be

Answer»

Osmotic pressure of 0.1 M solution of NaCl and Na2SO4 will be



627.

For the process, H2O(l)→H2O(g) at T=100∘C and 1 atmosphere pressure, the correct choice

Answer» For the process, H2O(l)H2O(g) at T=100C and 1 atmosphere pressure, the correct choice
628.

Which of the following pairs does not have the same shape?

Answer»

Which of the following pairs does not have the same shape?

629.

3 g of an oxide of a metal is converted to form 5 g of its chloride. The equivalent weight of the metal is:

Answer» 3 g of an oxide of a metal is converted to form 5 g of its chloride. The equivalent weight of the metal is:
630.

2-butyne and 1,3-butadiene exhibit?

Answer» 2-butyne and 1,3-butadiene exhibit?
631.

The % of dissociation of water at 25∘C is 1.9×10−7 and density is 1.0 g cm−3 The ionic constant for water is :

Answer»

The % of dissociation of water at 25C is 1.9×107 and density is 1.0 g cm3 The ionic constant for water is :

632.

C6H14 has 2 tertiary carbon atoms. What would be its IUPAC name?

Answer»

C6H14 has 2 tertiary carbon atoms. What would be its IUPAC name?



633.

What hybridization is expected on the central atom of each of the following molecules?(i) BeH2(ii) CH2Br2(iii) PF−6(iv) BF3

Answer»

What hybridization is expected on the central atom of each of the following molecules?

(i) BeH2

(ii) CH2Br2

(iii) PF6

(iv) BF3

634.

Magnesium combines with nitrogen to form a nitride, which reacts with water to form a colourless gas. The gas is:

Answer»

Magnesium combines with nitrogen to form a nitride, which reacts with water to form a colourless gas. The gas is:

635.

The density of an ideal gas at 298 K and 1.0 atm is found to be 1.25 kg m−3. Density of the gas at 1.5 atm and at 298 K is:

Answer»

The density of an ideal gas at 298 K and 1.0 atm is found to be 1.25 kg m3. Density of the gas at 1.5 atm and at 298 K is:

636.

An example of pπ−pπ bonding is:

Answer»

An example of pπpπ bonding is:

637.

Match the weight of reactants given in column I with weight of products marked (?) given in column II. Column I Column IIa.2H2+O2→2H2O1.0 g 1.0 g ?p.0.56 gb.N2+3H2→2NH31.0 g 1.0 g ?q.1.333 gc.CaCO3Δ→CaO+CO21.0 g ?r.1.125 gd.C + 2H2 → CH41.0 g 1.0 g ?s.1.214 g

Answer»

Match the weight of reactants given in column I with weight of products marked (?) given in column II.


































Column I Column II
a.2H2+O22H2O

1.0 g 1.0 g ?
p.0.56 g
b.N2+3H22NH3

1.0 g 1.0 g ?
q.1.333 g
c.CaCO3ΔCaO+CO2

1.0 g ?
r.1.125 g
d.C + 2H2 CH4

1.0 g 1.0 g ?
s.1.214 g


638.

The radius of first Bohr's orbit in H-atoms is r1. The corresponding wavelength of an electron in 2nd orbit is:

Answer»

The radius of first Bohr's orbit in H-atoms is r1. The corresponding wavelength of an electron in 2nd orbit is:



639.

The ionisation constant of phenol is higher than that of ethanol because

Answer»

The ionisation constant of phenol is higher than that of ethanol because



640.

Which of the following molecules is not an odd electron species?

Answer»

Which of the following molecules is not an odd electron species?

641.

The strength of sigma bonds formed by the axial overlap of s - or p - orbitals of 2nd shell of the participating atoms decreases as:

Answer»

The strength of sigma bonds formed by the axial overlap of s - or p - orbitals of 2nd shell of the participating atoms decreases as:

642.

For a 3s - orbitalΨ(3s)=1a√3(1a0)32(6−6σ+σ2)ϵ−σ2,Where σ=2rZ3a0What is the maximum radial distance of node from nucleus is

Answer»

For a 3s - orbital

Ψ(3s)=1a3(1a0)32(66σ+σ2)ϵσ2,

Where σ=2rZ3a0

What is the maximum radial distance of node from nucleus is

643.

The electronegativity of the following elements increases in the order of?

Answer»

The electronegativity of the following elements increases in the order of?



644.

The most abundant elements by mass in the body of a healthy human adult are oxygen (61.4%), carbon (22.9%), hydrogen (10.0%) and Nitrogen (2.6%). The weight which a 75 kg person would gain if all the 1H atoms are replaced by 2H atoms is:

Answer»

The most abundant elements by mass in the body of a healthy human adult are oxygen (61.4%), carbon (22.9%), hydrogen (10.0%) and Nitrogen (2.6%). The weight which a 75 kg person would gain if all the 1H atoms are replaced by 2H atoms is:

645.

D2O is used more in

Answer»

D2O is used more in




646.

Based on magic numbers, which nuclide is the most stable ?

Answer»

Based on magic numbers, which nuclide is the most stable ?



647.

List IList IIA. Bi3+⟶(BiO)+p. HeatB. [AlO2]−⟶Al(OH)3q. HydrolysisC. SiO4−4⟶Si2O6−7r. AcidificationD. (B4O2−7)⟶B(OH)3s. dilution by water

Answer»

List IList IIA. Bi3+(BiO)+p. HeatB. [AlO2]Al(OH)3q. HydrolysisC. SiO44Si2O67r. AcidificationD. (B4O27)B(OH)3s. dilution by water



648.

Principle quantum number directly reflects on

Answer»

Principle quantum number directly reflects on



649.

Which of the following options has only amphoteric oxides?

Answer»

Which of the following options has only amphoteric oxides?

650.

Which statement is not true for hydrogen?

Answer»

Which statement is not true for hydrogen?