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A compound (A) is greenish crystalline salt which gave the following results `:` `i)` Addition of `BaCl_(2)` solution to solution of (A) results in the formation of a white ppt. (B), which is insoluble in dil. HCl. `ii)` On heating (A), water vapours and two oxides of sulphur, (C ) and (D) are liberated leaving a red brown residue (E). `iii)` (E) dissolves in warm conc. HCl to give a yellow solution (F). `iv)` With `H_(2)S`, the solution (F) yields a pale yellow ppt. (G), which when filtered, leaves a greenish filtrate (H). `v)` Solution (F) on treatment with thiocyanate ions gives blood red coloured compound (I). Identify the substances from (A) to (I). Yellow ppt (G) is a `:`A. Solution (F)B. Solution (H)C. A and B bothD. None of these |
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Answer» Correct Answer - A `Fe^(2+)+K_(4)[Fe(CN)_(6)]rarr`White ppt `Fe^(3+)+K_(4)[Fe(CN)_(6)]rarr` Blue colouration `Fe^(2+)+K_(4)[Fe(CN)_(6)]rarr `Blue colouration `Fe^(3+)+K_(3)[Fe(CN)_(6)]rarr ` Red - brown colouration |
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