Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Properties of elements X: (i) Its amide is used as a reducing agent (ii) Its amalgam is used as reducing agent Properties of element Y: (i) It is an octaatomic molecule (ii) It is diamagnetic in ground state but paramagnetic in vapour phase Properties of element Z: (i) Its diatomic molecule is paramagnetic (ii) Its allotrope is an absorber of UV radiation (iii) IT supports combustion Compound of X and Z + Compound of Y and Z rarr product(s). Oxidation number of Y in the final compound may be:

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`+4` or `+6`
0 and `+2`
`+3` and `+5`
`-2` and `+4`

Answer :A
2.

Properties like variety of oxidation states, formation of coloured ions and complex compound formation are due to

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PARTLY FILLED s-orbitals.
partly filled p-orbitals.
partly filled d-orbitals.
completely filled d-orbitals.

ANSWER :C
3.

Properties common to the elements manganese, iron, cobalt, nickel nad copper include the ready formation by them all of (I) coloured ions in aqueous solution (II)oxides of nitrogen are formed on reaction with concentrated HNO_(3) (III) chlorides of formula MCl_(2) and MCl_(3)

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I, II, III
I, II
II, III
I only

Answer :B
4.

Properties of elements are periodic function of number of present in the nucleus

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Protons
Electrons
Neutrons
Mesons

Answer :A
5.

Properties associated with teflon are

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It is chemically merit.
It is used in MAKING oil SEEDS.
It is used for non-stick surface COATED utensils
All the above.

Answer :D
6.

Propene when heated with chlorine at about 500^@ C forms

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`CH_2Cl.CH=CH_2`
`CH_3.CHCl.CH_2Cl`
`CH_2Cl. CHCl. CH_2Cl`
All of three

Solution :`CH_3-CH=CH_2+Cl_2overset(500^@C)to undersetunderset(Cl)(|)CH_2-CH=CH_2+HCl`
This REACTION is called allylic HALOGENATION reaction because halogenation OCCURS at the allylic POSITION of an alkene
7.

Propene,CH_3CH=CH_2 can be converted into 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion:

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`H_2O`
`B_2H_6,H_2O_2`
`H_2SO_4`
None

Answer :B
8.

Write the relavant chemical equations : Propene to propyne

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Solution :`CH_(3)-CH=CH_(2) underset(C Cl_(4))overset(Br_(2))rarr CH_(3)-overset(overset(BR)(|))(CH)-overset(overset(Br)(|))(CH_(2)) underset(KOH)overset("Alc")rarr CH_(3)-C -= CH`
9.

Write the relavant chemical equations : Propene to nitropropane

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Solution :`CH_(3)-CH= CH_(2) UNDERSET("peroxide")overset(HBr)rarr CH_(3)-CH_(2)-CH_(2)-BR overset(AgNO_(2))rarr CH_(3)-CH_(2)-CH_(2)-NO_(2)`
10.

Propene to 1-bromopropane

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Solution :PROPENE to 1-bromopropane :
`underset("Propene")(CH_(3)-CH)=CH_(2)+HBroverset("PEROXIDE")rarrunderset("1-Bromopropane")(CH_(3)-CH_(2))-CH_(2)-Br`
11.

Write the relavant chemical equations : Propene to 1-propanol

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Solution :`CH_(3)-CH=CH_(2) underset(2.H_(2)O_(2)//OH^(-))overset(1.BH_(3))RARR CH_(3)-CH_(2)-CH_(2)-OH`
12.

Propene to 2-bromopropane

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SOLUTION :PROPENE to 2-bromopropane :
`UNDERSET("Propene")(CH_(3))-CH=CH_(2)+HBroverset("dark")rarrunderset("2-Bromopropane")(CH_(3)-overset("Br ")overset("|")(CH)-CH_(3))`
13.

Propene on treatment with HI gives

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Only `CH_(3)CH_(2)CH_(2)I`
Only `CH_(3)CHICH_(3)`
`CH_(3)CH_(2)CH_(2) ("MINOR ") + CH_(3)CHICH_(3) `(MAJOR)
`CH_(3)CH_(2)CH_(2)I ("major") + CH_(3) CHI CH_(3)` (minor)

Answer :c
14.

Propene reacts with HBr in the presence of a peroxide to form :

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n-propyl bromide
isopropyl bromide
1, 3-dibromopropane
propane

Solution :`CH_(3) - CH = CH_(2) UNDERSET("PEROXIDES")overset(HBR)rarr underset("n-Propyl bromide")(CH_(3)CH_(2)CH_(2)Br)`
15.

Propene reacts with Cl_2 at 400-600^@Cto give:

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1,2 - dichloropropane
Allyl chloride
No REACTION
POLYVINYL chloride

Answer :B
16.

Propene is treated with bromine in the presence of brine (aqueous NaC).Choose the correct statement regarding the above reaction.

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TOTAL TWO products are formed.<BR>Total THREE products are formed.
Total six products are formed.
Total eight products are formed.

Solution :`C-overset(H)overset(|)underset(Br)underset(|) C-C-Br, C-overset(Br)overset(|)underset(H)underset(|)C-Br,C-overset(H)overset(|)underset(Cl)underset(|)C-C-Br,`
`C-overset(Cl)overset(|)underset(H)underset(|)C-C-Br,C-overset(H)overset(|)underset(OH)underset(|)C-C-Br,C-overset(OH)overset(|)underset(H)underset(|)C-C-Br,`
17.

Propene on hydroboraction-oxidation produces

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`CH_(3)CH_(2)CH_(2)OH`
`CH_(3)CHOHCH_(3)`
`CH_(3)CHOHCH_(2)OH`
`CH_(3)CH_(2)CHO`

Solution :`UNDERSET("Propene")(CH_(3)CH=CH_(2)) underset(("Hydroboration"))overset(B_(2)H_(6)//THF)to underset("Tri-n-propylborane")((CH_(3)CH_(2)CH_(2))_(3)B) underset(("Oxidation"))overset(H_(2)O_(2)//OH^(-))to underset("1-Propanol")(CH_(3)CH_(2)CH_(2)OH)`
18.

Propene on hydration gives

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propan-1-ol
propan-2-ol
PROPANE
PROPYNE

ANSWER :B
19.

Propene is not the product obtained by dehydration of :

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2-Propanol
1-propanol
Propanal
n-propyl alcohol

Answer :A
20.

Propene is the product obtained by dehydration of

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2-propanol
1-propanol
Propanal
n-propyl alcohol

Answer :A
21.

Propene is more reactive than ethene towards HBr because :

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propene can more readily undergo a FREE RADICAL chain reaction
propene gives rise to more stable carbonium ion
the double bond in CASE of propene is unstable
the methyl group attached to double bond WITHDRAWS the electrons and facilitates the attack.

ANSWER :B
22.

Propene, CH_(3) - CH = CH_(2) can be converted to 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion

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Alkaline `KMnO_(4)`
`B_(2)H_(6)` and alkaline `H_(2)O_(2)`
`O_(3) / /Zn` dust
`OsO_(4) // CH_(4) , Cl_(2)`

Solution :Hydroboration oxidation (INDUSTRIAL PREPARATION of alcohol)
`3CH_(3)CH=CH_(2)+(1)/(2)B_(2)H_(6)underset("ETHER")overset("dry")to (CH_(3)CH_(2)CH_(3))B`
`(CH_(3)CH_(2)CH_(3))B overset(H_(2)O_(2))to 3CH_(3)CH_(2)CH_(2)-OH`
23.

Propene, CH_(3)-CH = CH_(2), can be converted to 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion?

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ALKALINE `KMnO_4`
`B_2H_6` and alkaline `H_2O_2`
`O_3//Zn ` DUST
`OsO_4//CH_2Cl_2`

ANSWER :B
24.

Propene can be converted into 2-propanol by hydration. Which of the following reagents is ideal to affect the conversion ?

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Alkaline `KMnO_4`
ZN DUST+ `H_2O`
conc. `H_2SO_4`
conc. HCI

ANSWER :C
25.

Propanone reacts with iodine in acid solution as shown in this equation. CH_(3)C(O)CH_(3)+I_(2)overset(H^(+))rarrCH_(3)C(O)CH_(2)I+HI These data were obtained when the reaction was studied. |{:([CH_(3)C(O)CH_(3)]","M,[I_(2)]","M,[H^(+)]","M,"Relative Rate"),(0.010,0.010,0.010,1),(0.020,0.010,0.010,2),(0.020,0.020,0.010,2),(0.020,0.010,0.020,4):}| What is the rate equation for the reaction?

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RATE =`k[CH_(3)C(O)CH_(3)][I_(2)]`
Rate =`k[CH_(3)C(OH)CH_(3)]^(2)`
Rate = `k[CH_(3)C(O)CH_(3)]I_(2)][H^(+)]`
Rate = `k[CH_(3)C(O)CH_(3)]H^(+)]`

ANSWER :D
26.

Propanone to propene

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SOLUTION :
27.

Propanone on reaction with alkyl magnesium bromide followed by hydrolysis will not produce.

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PRIMARY alcohol
Secondary alcohol
Tertiary alcohol
Carboxylic acid

Answer :A::B::D
28.

Propanone is usually characterised by ________

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FEHLING's solution
iodoform test
Schiff's test
Tollen's reagent

Answer :B
29.

Propanone is the product obtained by dehydrogenation of …………………. .

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Propan-2-ol
Propan-1-ol
Propanal
n-propyl alcohol

Solution :Propan-2-ol
30.

Propanone is the product obtained by dehydrogenation of

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propanal
n-propyl alcohol
2-propanol
1-propanol

Solution :`underset("2-propanol")(CH_(3) - overset(overset(OH)(|))(CH) - CH_(3)) overset(-H_(2))rarr underset("PROPANONE")(CH_(3) - overset(overset(O)(||))(C )-CH_(3))`
`2^(@)` alcohols on dehydrogenation i.e., removal of `H_(2)` gives OXIDATION product-ketones.
31.

Propanone does not undergo:

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OXIME FORMATION
Hydrazone formation with hydrazine
Cyanohydrin formation with HCN
Reduction of FEHLING's solution

Answer :D
32.

Propanone can be prepared from ethyne by

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passing a mixture of ethyne and steam over a catalyst, magnesium at `420^(@)C`
passing a mixture of ethyne and ethanol over a catalyst zinc chromite
boiling ethyne with water and `H_(2)SO_(4)`
treating ethyne with lodine and NaOH.

Solution :`2CH-=CH+3H_(2)Ooverset(420^(@)C)underset("Mg or Zinc vanadate")to CH_(3)COCH_(3)+CO_(2)+2H_(2)`
33.

Propanone can be obtained from oxidation of what ?

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propan -2-ol
propan - 1-ol
BUTAN - 2- ol
2-methylbutan - 1 -ol

SOLUTION :`CH_(3)CHOHCH_(3) overset("oxidation") to CH_(3)COCH_(3)+H_(2)O`
34.

Propanol is heated with conc. H_(2)SO_(4) at 170^(@)C and the gas produced is reacted with HBr. What is the formula of the final product ?

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`CH_(3) - CH_(2) CH_(2)Br`
`CH_(3) underset(Br)underset(|)(CH)-underset(Br)underset(|)(CH_(2))`
`CH_(3) - underset(Br)underset(|)(CH) - CH_(2)OH`
`CH_(3) - underset(Br)underset(|)(CH) - CH_(3)`

SOLUTION :Dehydration of propanol with CONC. `H_(2)SO_(4)` gives propene which reacts with HBr to form
`CH_(3) underset(Br)underset(|)(CH) - CH_(3)` (Markovnikov.s rule).
35.

Propanoic acid to acetic acid

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Solution :`CH_(3) COOH overset(NAOH)(to) CH_(3) CH_(2) COONa overset(NaOH)underset(CaO)(to) C_(2) H_(6) overset(Cl_(2)//h epsilon) (to) C_(2) H_(5) CL overset(AGOH) (to) C_(2) H_(5) OH overset((O))underset(KMnO_(4)//H^(+))(to) CH_(3) COOH`
36.

Propanoic acid is the oxidative product of ,

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ethanol
3- pentanone
1- butanol
2- PROPANOL

Answer :B
37.

Propanoic acid on warming withCl_2 in presence of red P gives :

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`CH_3CH_2Cl`
`CH_3CH_2Cl`
`CH_3CHClCOOH`
`CH_2ClCH_2COOH`

ANSWER :C
38.

Propanoic acid is slightly weaker than acetic acid because

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methyl GROUP is ELECTRON with drawing
`+I ` EFFECT of `C_2H_5 ` is more than `-CH_3`
ACETIC acid is stronger than propanoic acid
propanoic acis has three carbon ATOMS

Answer :B
39.

Propanenitrile is obtained by the action of alcholic KCN and what ?

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`CH_(3)CL`
`C_(2)H_(5)Cl`
`(CH_(3))_(2)CHCL`
`C_(2)H_(5)OH`

SOLUTION :`C_(2)H_(5)Cl+KCN overset(Delta) to C_(2)H_(5)CN+KCl`
40.

Propanoic acd undergoes HVZ reaction to give chloropopanoic acid.The product obtained is

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as stronger as PROPANOIC acid
stronger acid than propanoic acid
stronger than dichloropropanoic acid
weaker acid than propanoic acid

Solution :`CH_(3)-CH_(2)-COOHtoCH_(3)-underset(Cl)underset(|)(CH)-COOH`
Stonger acid than propanoic acid because of the presence of electron WITHDRAWING -Cl group
41.

Propane on dichlorinatin gives......isomers and out of them .....are optically active.

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`4,1`
`3,1`
`4,2`
`3,2`

SOLUTION :
42.

Propanenitrilereactswith Ato giveB . ThecompoundB onadditionof HCNgives C .ThecompoundC onreductiongive 1-Amino-2- ethyl-4-methyl -2- pentanolwhich of thefollowis A gt

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`(CH_(3))_(3)CCH_(2) MgX`
`(CH_(3) )_(2) CHCH_(2) MgX`
`C_(2) H_(5) MgX`
`CH_(3) CH_(2) CH_(2) MgX`

SOLUTION :`CH_(3)CH_(2) CN + (CH_(3)) _(2) CHCH_(2)MgX to`
`(A)`
`CH_(3) CH_(2) C= Ooverset(HCN) (to)CH_(3) CH_(2) - overset(OH) overset(|)underset(CH_(2) CH (CH_(3))_(2))(C )- CH`
`overset("reduction") (to)CH_(3) CH_(2)- overset( OH) overset(|)underset( CH_(2)) CH(CH_(3))_(2) overset(|) (C ) - CH_(2) NH_(2)`
`1-` amino-2-ethyl -4-methyl-2-pentanol
43.

Propane is treated with methyl magnesium bromide and them subjected to hydrolysis. Write the final product.

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SOLUTION :`UNDERSET("2-methylpropan-2-ol")((CH_3)_3-COH)`
44.

Propane + Cl_(2)overset("UV light")toAoverset(Na//"ether")toB. The compound (B) is.

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n-hexane
2-methyl BUTANE
2,3-dimethyl butane
2,2-dimethyl propane

Answer :D
45.

Propane-1-ol and Propane-2-ol are distinguish by which method ?

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Ozonolysis
Reduction
Dehydration
OXIDATION

Solution :Oxidation
46.

Propane cannot be prepared from which reaction

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`CH_3-CH=CH_2underset(OH^-)OVERSET(B_2H_6)to `
`CH_3CH_2CH_2IundersetPoverset"HI"to`
`CH_3CH_2CH_2Cl overset"Na"to`
None of these

Solution :Hydroboration of alkenes FOLLOWED by hydrolysis in basic medium yield ALCOHOLS and not the alkanes .
`R-CH=CH_2overset(B_2H_6)to (R-CH_2-CH_2)_3 -B overset(OH^-)to R-CH_2-CH_2OH`
47.

Propanal is____than propanone towards nucleophiles.

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SOLUTION :More REACTIVE
48.

Propanal on treatment with dilute sodium hydroxide gives

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`CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)CHO`
`CH_(3)CH_(2)CH(OH)CH_(2)CH_(2)CHO`
`CH_(3)CH_(2)CH(OH)CH(CH_(3))CHO`
`CH_(3)CH_(2)COOH`

ANSWER :C
49.

Propanal and propanone undergoes condensation reaction in presence of dil . KOH to form,

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`CH_(3)CH_(2)CH(OH)CH_(2)COCH_(3)`
`CH_(3)C(OH)(CH_(3))CH(CH_(3))CHO`
`CH_(3)CH(OH) (CH_(3))CH_(2)CH_(2)CHO`
NONE of these

Solution :Whenaldehydes condenses with ketone, gives four condensation products. It is the`alpha `- hydrogen ATOM of the ketone which isinvolved in thecondensation reaction and produces major product.
`CH_(3)CH_(2)CHO + HCH_(2)COCH_(3) overset("dil . NaOH") tounderset(" 4- HYDROXY 2- hexanone")( CH_(3)CH_(2)CH(OH) CH_(2)COCH_(3))`
50.

Propan-2-ol to 2-methylpropan-2-ol.

Answer»

Solution :`underset("Propan-2-ol")(CH_(3)-OVERSET(OH)overset(|)(C)H-CH_(3)) underset("or "C_(5)H_(5)NH^(+)CrO_(3)Cl^(-))overset(Cu//573K)to underset("Propanone")(CH_(3)-overset(O)overset(||)(C)-CH_(3)) underset((ii)" "H_(3)O^(+))overset((i)" "CH_(3)MgBr)to underset("2-Methylpropan-2-ol")(CH_(3)-underset(OH)underset(|)overset(CH_(3))overset(|)(C)-CH_(3))`