Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Methyl cyanide on dilution with HCl produces

Answer»

`CH_(3)COOH`
`HCOOH`
`CH_(3)-CO-CH_(3)`
`CH_(3)-CHO`

ANSWER :A
2.

Methyl cyanide is less basic than methylamine because

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there is a triple bond between CARBON and NITROGEN atoms.
molecular weight is higher than methylamine.
the lone pair of electrons in nitriles belongs to sp - orbital and lone pair of electrons in AMINES belongs to `sp^(3)-` orbital.
None of these

Solution :`CH_(3)-C-= underset(sp)overset(* *)(N)""CH_(3)-underset(sp^(3))(overset(* *)NH_(2))`
3.

Methyl chloride reacts with silver acetate to yield

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Acetaldehyde
Acetyl chloride
Methyl acetate
Acetic acid

Answer :C
4.

Methyl chloride reacts with silver acetate to yield :

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ACETIC acid
Methyl acetate
Acetyl chloide
Acetaldehyde

Answer :B
5.

Methyl cyanide can be converted into acetic acid by :

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REDUCTION
Hydrolysis
Electrolysis
Decarboxylation

Answer :B
6.

Methyl carboium ion si isoelectronic with,

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`CH_(4)`
`:C Cl_(2)`
`CH_(3)^(-)`
`F^(-)`

Solution :`CH_(3)^(+)`is a methyl carboniumion having SIX electrons in outer most ORBIT. It is isoelectronic with `C Cl_(2)` (dicholor carbene), it ALSO contains six electrons in outer most orbit.
7.

Methyl chloride on treatment with Potassium cyanide followed by hydrolysis yields:

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HCOOH
`CH_3`COOH
`CH_3`CN
`CH_3`COOK

Answer :B
8.

Methyl carbinol is

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ETHANOL
propan-2-ol
propan-1-ol
methanol

Answer :A
9.

Methyl butane on reacting with bromine in the presence of sunlight gives mainly

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1- BROMO -2- methyl butane
2- bromo -2- methyl butane
2- bromo -3- methyl butane
1- bromo -3- methyl butane

Answer :B
10.

Methyl bromide when heated with zinc in closed tube, produces

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Methane
Ethylene
Ethane
Methanol

Answer :C
11.

Methyl bromide is not used :

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As an insectiside
A DISINFECTANT
For DYEING clothes
As disinfectant for YOUNG FRUIT trees.

Answer :C
12.

Methyl bromide reacts with silver acetate to give :

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Acetic acid
Acetyl chloride
METHYL acetate
Acetaldehyde

SOLUTION :`CH_(3)Br+CH_(3)COOAgrarrunderset("Methyl acetate")(CH_(3)COOCH_(3))+AgBr`
13.

Write the relavant chemical equations : Methyl bromide to propanone

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SOLUTION :`CH_(3)-Br overset(KCN)RARR CH_(3)-CN overset(H_(3)O^(+))rarr CH_(3)COOH overset(Ca)rarr (CH_(3)COO)_(2)Ca overset("distillation")rarr CH_(3)COCH_(3)`
14.

Methyl bromideis convertedintoethanebyheatingitinethermediumwith :

Answer»

Al
Zn
Na
Cu

Answer :C
15.

Methyl bromide is converted into ethane by heating it in ether medium with

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Al
Zn
Na
Cu

Solution :An ether solution of alkyl halide when treated with sodium, it removes the HALOGEN of alkyl halide and the two alkyl radicals join together to FORM an alkane. This reaction is CALLED Wurtz reaction.
`CH_(3)Br+2Na+Br CH_(3) overset("DRY ether")rarr UNDERSET("ethane")(CH_(3)-CH_(3))+2NaBr`
16.

Methyl bromide when heated with zinc in a closed tube produces:

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Methane
Ethane
Ethylene
Methanol

Answer :B
17.

Methyl benzoate is reduced by di - isobut aluinium hydride gives

Answer»




ANSWER :C
18.

Methyl benzoate can prepared by

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`C_(6)H_(5)COOH+CH_(3)OH overset(H^(+))to`
`C_(6)H_(5)COCl+CH_(3)OH overset("Pyridine")to`
`C_(6)H_(5)COOH+CH_(2)N_(2) to`
all the above methods

Solution :All OPTION is correct
19.

Methyl benzoate can be prepared by :

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`C_6H_5COOH + CH_3 OH OVERSET(H^(+))to`
`C_6H_5COCl + CH_3OH overset("PYRIDINE")to `
`C_6H_5COOH + CH_2N_2 to`
All the above methods.

Answer :D
20.

Methyl amineis formedby reduction of

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NITROETHANE
METHYL cyanide
FORMAMIDE
Acetaldoxime

ANSWER :C
21.

Methyl amine on heating with CHCl_3 and KOH gives:

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Methanol
Carbylamine
Methanamide
Methyl cyanide

Answer :B
22.

Methyl amine in water reacts with ferric chloride to precipitate ferric hydroxide. Why ?

Answer»

SOLUTION :`CH_3NH_2 + H_2O RARR CH_3NH_3 + OH^-`
`FeCl_3 + 3OH^- rarr Fe(OH)_3 + 3CL^- 1`
23.

Methyl-alpha-D-glucoside and methyl- beta-D- glucoside are

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epimers
anomers
enantiomers
conformational diastereomers

Answer :B
24.

Methyl-alpha-D-glucoside and methyl-beta-D-glucoside are

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EPIMERS
anomers
ENANTIOMERS
conformational DIASTEREOMERS

SOLUTION : The isomers which are DIFFERING in configuration at asymmetric carbon produced due to ring formations are known as anomers.
25.

Methyl alcohol when reacted with carbon monoxide using cobalt or rhodium as catalyst , compound underlineA is formed . underlineA on heating with HI in the presence of red phosphorus as catalyst underlineB is formed . Identify underlineB

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`CH_(3) COOH`
`CH_(3) CHO`
`CH_(3) CH_(2) I`
`CH_(3) CH_(3)`

Answer :D
26.

Methyl alcohol reacts with phosphorus trichloride to from:

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METHANE
METHYL chloride
Accetyl chloride
Dimethyl ether

Answer :B
27.

Methyl alcohol on oxidation with acidified K_2Cr_2O_7 giyes

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`CH_3COCH_3`
`CH_3CHO`
HCOOH
`CH_3COOH`

ANSWER :C
28.

Methyl alcohol on oxidation with acidified K_2Cr_2O_7 gives

Answer»

`CH_3OH`
HCOOH
`CH_3COCH_3`
`CH_3COOH`

ANSWER :B
29.

Methyl alcohol on oxidation with acidified K_2Cr_2O_7 gives :

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`CH_3COCH_3`
`CH_3CHO`
HCOOH
`CH_3COOH`

ANSWER :C
30.

Methyl alcohol is used ________.

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for DRY cleaning
PREPARATION of perfumesand VARNISHES
as an antifreeze AGENT for AUTOMOBILE radiators
in all of these

Answer :D
31.

Methyl alcohol is toxic. The reason assigned is

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It stops respiratory track
It reacts with nitrogen and forms `CN^(-)` in the lungs
It INCREASE `CO_(2)` content in the blood
It is reduction PRODUCT of formaldehyde

Answer :B
32.

Methyl alcohol is toxic. The reason assigned is:

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It stops RESPIRATORY track
It reacts with nitrogen and forms `CN^(-)` in the lungs
It increases `CO_(2)` content in the blood
It is a reduction PRODUCT of formaldehyde

Answer :B
33.

Methyl alcohol is perpared from heatingof

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`(CH_(3))_(4)NH`
`(CH_(3))_(3)N -C_(2)H_(5) OH`
`CH_(3) - NH-CH_(3)`
`CH_(3) - CH_(2) -NH_(2)`

SOLUTION :`(CH_(3)) - NOH overset(Delta)to CH_(3) - OH + (CH_(3))N `
34.

Methyl alcohol is _______acidic than ethyl alcohol :

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Less
More
Equally
None

Answer :B
35.

Methyl alcohol can be distinguished from ethyl alcohol using

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Fehling solution
Schiff's reagent
Sodium HYDROXIDE and iodine
Phthalein fusion test

Solution :`C_(2)H_(5)OH UNDERSET("IODOFORMTEST")overset(NaOH//I_(2))to CHI_(3))` (yellow PPT)
`CH_(3)OH overset(NaOH//I_(2))to ` No ppt
36.

Methyl acetate is hydrolyzed with 0.1 N HCl at 25^(@)C. 5mL of the reacting mixture is withdrawn at various time intervals and is quickly titrated is withdrawn NaOH. The volume of NaOH consumed are as follows: |{:("Time (s)",339,1242,2745,4546,oo),("vol of NaOH (mL)",26.34,27.80,29.70,31.81,39.81):}| Show that the hydrolyiss is a first order reaction. Also find the rate constant (k).

Answer»

Solution :For ester hydrolyiss, equation`k = (2.303)/(t)LOG.(V_(oo)-V_(0))/(V_(oo)-V_(t))`
Since `V_(0)` is not given
Let `V_(oo)-V_(0) = c_(0)` and `V_(oo) - V_(t) = c_(t)`.
When `t = t_(1)`
`:. k = (2.303)/(t_(1))log.(c_(0))/(c_(t_(1)))`...(i)
ismilarly, when `t = t_(2)`
`k = (2.303)/(t_(2))log.(c_(0))/(c_(t_(2)))`...(ii)
Oprating EQ.(i) Eq. (ii), we GET
`k(t_(1)-t_(2)) = 2.303log.(c_(t_(2)))/(c_(t_(1)))`
or
`k = (2.303)/((t_(1)-t_(2)))log.(c_(t_(2)))/(c_(t_(1)))` ...(iii)
Now find `c_(t)`.

and `t_(1) - t_(2) = 339 - 1242 = -903 s`
`t_(1)-t_(3) = 339 - 2745 = -2406 s`
`t_(1)-t_(4) = 339-4546=-4207 s`
Uisng relation given in Eq. (iii),
`:. k_(1) = (2.303)/(-903)log.(12.0)/(13.47) = -0.0025 XX log(0.89)`
`= -0.0025 xx -0.0506 = 1.27 xx 10^(-4) s^(-1)`
`k_(2) = (2.303)/(-2406)log.(10.11)/(13.47) = -0.00095 xx log(0.75)`
`= -0.00095 xx -0.1249 = 1.19 xx 10^(-4) s^(-1)`
`k_(3) = (2.303)/(-4207)log.(8.0)/(13.47) = -0.00054 xx log(0.59)`
`= -0.00054 xx -0.2291 = 1.23 xx 10^(-4) s^(-1)`
`k_("avergae") = 1.23 xx 10^(-4) s^(-1)`
37.

Methyl alcohol.

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Solution :(1) Methyl ALCOHOL is used as an industrial SOLVENT for dissolving OILS, fats, gums ETC.
(2) It is used for dry CLEANING and preparation of perfumes and varnishes.
(3) It is used as antifreeze agent for automobile radiators at low temperature.
(4) It is used in the preparation of methyl chloride, dimethyl sulphate and formaldehyde.
(5) It is used to denature ethyl alcohol.
38.

Methyl acetate is formed from methyl alcohol and what?

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ACETIC acid
Acetic unhydride
Acetyl chloride
All of these

Answer :D
39.

Methyl acetate and ethyl acetate can be distinguished by:

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hot alakline `KMnO_(4)`
NEUTRAL `FeCl_(3)`
Iodoform test
none of these

Answer :C
40.

Methyl 2 -methyl propanoate is reduced by DIB-Al-H gives

Answer»

2-METHYL PROPANOIC acid
3-methyl butan-2-one
`ALPHA`-methyl propionic acid
2-methyl propanal

Answer :D
41.

methyl acetate and ethyl acetate can be distinguished by

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Hot ALKALINE `KMnO_(4)`
Neutral `FeCl_(3)`
Iodoform TEST
None of the above

Solution :Iodoform test is carried out in hot alkaline medium, under these CONDITIONS the esters will hydrolyse to give CORRESPONDING alcohols. Now ethyl alcohol will respond to iodoform test to give yellow ppt. of iodoform whiel methanol will give no iodoform test.
42.

Methoxy methane and ethanol are of which type isomers ?

Answer»

FUNCTIONAL GROUP
Optical
Position
Chain

SOLUTION :Functional group
43.

Methoxybenzene on treatment with HI Produce

Answer»

IODOBENZENE and methanol
PHENOL and METHYL IODIDE
iodobenzene and methyl iodide
phenol and methanol.

Solution :
44.

Methoxy ethane is obtained by C_2H_5OH and what ?

Answer»

`CH_3Cl`
`CH_3ONa`
`CH_2N_2`
`CH_2Cl_2`

ANSWER :C
45.

Methoxy benzene is prepared from CH_3-Cl and what?

Answer»

phenol
sodium benzoate
sodium phenoxide
benzyl chloride

Answer :C
46.

Methoxy ethane does not react with

Answer»

HI
HBr
dil. `H_2SO_4`
Na

Answer :D
47.

Methoxy benzene is called anisole How many more structure can be drawn for the same formula ?

Answer»

5
4
3
2

Answer :B
48.

Method used for obtaining highly pure silicon which is used as a semiconductor material, is

Answer»

oxidation
electrochemical
crystallization
zone REFINING

SOLUTION :Siobtainedbyreductionof `SI CI_2 ` with ` H_2 `is furtherpurifiedbyzonerefiningto getSI ofveryhighpuritySiliconispurifiedbyzone- refininf processbecausetheimpuritiespresentin it aremoresolublein thehliquidphasethan INTHE soledphase .
49.

Method used for obtaining highly pure silicon used as a semiconductor material is

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Oxidation
Electrochemical
Crystallization
ZONE refining

Solution :By the process of zone refinig PURE silicon is obtained which is USED in SEMICONDUCTOR.
50.

Method used for obtaining highly pure silicon used as a semiconductor material, is

Answer»

Oxidation
Electrochemical
Crystallization
Zone refining

Solution :SI obtained by reduction of `SiCl_(4) with H_(2)` is further purified by zone refining method to get Si of very high purity. Silicon is purified by zone-refining process because the impurities PRESENT in it are more soluble in the liquid phase than in the solid phase.