This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Mention a chemical property in which methanoic acid differs from acetic acid. |
| Answer» SOLUTION :Methanoic ACID is a reducing agent. It gives silver MIRROR with Tollen.s reagent. Ethanoic acid is not a reducing agent and does not respond to TOLLENS. reagent. | |
| 2. |
Mental diseases like schizophrenia are treated using ______ drugs. |
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Answer» tranquilizers |
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| 3. |
Mention a chemical property in which formic acid (methanoic acid) differs from acetic acid (ethanoic acid). Or Formic acid reduces Tollens' reagent but acetic acid does not. |
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Answer» Solution :Formic ACID contains a H-atom attached to a gtC=O group and hence can be regarded as an aldehyde. THEREFORE, it acts as a reducing agent and hence decolourises pink-violet colour of `KMnO_(4)` solution. Acetic acid, on the other hand, contains an alkyl (i.e., `CH_(3)`) group attached to gtC=O group. therefore, it does not acts as a reducing agent and hence does not decolourise `KMnO_(4)` solution. `underset("Formic acid")(5HCOOH)+underset("Pink-violet")(2KMnO_(4))+3H_(2)SO_(4) to 5 CO_(2)+K_(2)SO_(4) + underset("Colourless")(2MnSO_(4))+8H_(2)O` `underset("Acetic acid")(CH_(3)COOH) overset(KMnO_(4)//H_(2)SO_(4))to` No change in pink-violet colour of `KMnO_(4)` SOLN. ltrgt Similarly, methanoic acid reduces Tollens' reagent and fehling's solution but `CH_(3)COOH` does not. `underset("Formic acid")(H-overset(O)overset(||)(C)-OH)+underset("Tollens' reagent")(2[AG(NH_(3))_(2)]^(+))+2OH^(-)(Heat)to underset("Silver mirror")(2Ag darr)+4NH_(3)+CO_(2)+2H_(2)O` `underset("Formic acid")(H-overset(O)overset(||)(C)-OH)+underset("Fehling's solution")ubrace(2Cu^(2+)+4OH^(-)) overset (Heat)to underset("Red ppt.")(Cu_(2)Odarr)+CO_(2)+3H_(2)O` `underset("Acetic acid")(CH_(3)-overset(O)overset(||)(C)-OH) underset("or Fehling's solution") overset("Tollens' reagent")to`No reaction. |
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| 4. |
Mendius method of preparation of amines consists of : |
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Answer» CATALYTIC reduction of alkyl cyanides |
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| 5. |
MeMgX react with D_2 O to produce |
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Answer» `CD_(2)` |
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| 6. |
Melting points NaCl, NaBr, Nal and NaF will be in order |
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Answer» `NAL gt NaBr gt NaCl gt NAF` |
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| 7. |
Members of the oxygen family are called halogens. |
| Answer» Solution : MEMBERS of the OXYGEN FAMILY are CALLED CHALCOGENS. | |
| 8. |
Melting point order is not correct is :- |
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Answer» `NAF lt MgF_(2) lt AlF_(3)` |
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| 9. |
Melting point of pure acetanilide is about : |
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Answer» `82^@ C ` |
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| 10. |
Melting point of any solid depends on pressure as (P_(2)-P_(1))=(DeltaH_("fusion"))/(V_(l)-V_(s))cdotln"T_(2)/(T_(1). calculate freezing point of water ("in"^(@) C ) at a pressure of 1001 bar if freezing pooint of water at 1 bar is 0^(@) C. Molar volume of ice and liquid water is 19.65 mL and 18 mL respectively and increase in enthalpy due to melting is 6600 J//mole [In 0.975=-0.025] [Instruction : Neglect sign of the temperature therefore if your answer is -8.65^(@) C, express answer is 9] |
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Answer» |
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| 12. |
Melting point is higher for: |
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Answer» Be |
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| 13. |
Melting point is highest for: |
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Answer» B |
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| 14. |
Melting of Zn metal and then ouring it into cold water gives: |
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Answer» ZN dust |
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| 16. |
Melamine plastic crockery is a codensation polymer of |
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Answer» HCHO and MELAMINE |
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| 17. |
Melamine. |
| Answer» SOLUTION :It is USED in the MAKING CROCKERIES. | |
| 18. |
Mehtanecan beconvertedintoethaneby thereaction: |
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Answer» CHLORINATION floowedby thereactionwithalocholicKOH |
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| 19. |
Medius reduction converts an alkyl cyanide to |
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Answer» a PRIMARY amine |
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| 20. |
Medicines used to reduce tension are called …………….. . |
| Answer» SOLUTION :TRANQUILIZERS | |
| 21. |
Medicine which is antibiotic is : |
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Answer» AMPICILLIN |
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| 22. |
Medicine which is antibiotic is_____ . |
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Answer» ibuprofen |
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| 24. |
Medicinal name of H_(2)O_(2) is |
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Answer» PERHYDROL |
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| 25. |
MeCH(CN)Co underset(Delta)overset(aq.H_(2)SO_(4))rarr Me P |
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Answer» P GIVING +ve iodofrom TEST and -ve test with FEHLING solution . |
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| 26. |
Mechanism of hypothetical reaction X_(2) + Y_(2) to 2 XY is given below (i) X_(2) to X + X(fast ) (ii) X + Y_(2) hArr XY + Y (slow) (iii)X + Y to XY (fast) The overall order of the reaction will be |
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Answer» 2 R = `K [X] [Y_(2)] "" … (i)` From fast step `K_(eq) = ([X]^(2))/([X_(2)])` `[X]^(2) = K_(eq) [X_(2)]` [X] = `sqrt(K_(eq))[X_(2)]^(1//2) …. (ii)` From equation (i) & (ii) `r = K [X_(2)]^(1//2) [Y_(2)]` `r = K[X_(2)]^(1//2) [Y_(2)]` . OVERALL order of reaction = 1 + 0.5 = 1.5 |
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| 28. |
Mechanisms for hydrolysis of A will be : |
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Answer» `A_(AC^(2))`
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| 29. |
Mechanism of formation of A and B is |
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Answer» `A_(AC^(2))`
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| 30. |
Mechanism of formation of A and B is : |
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Answer» `A_(AC^(2))`
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| 31. |
Mechanism of acid catalysed hydration reaction involves (i) Protonation of alkene toform carbocation by electrophilic attack of H_(3)O^(+) (ii) Nucleophilic attack of water on carbocation. (iii) Deprotonation to fonn alcohol. |
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Answer» (i) and (ii) Step: 1 protonation of alkene to form carbocation by electrophilic ATTACK of `H_(3)O^(+)` `H_(2)O+H^(+) to H_(3)O^(+)` Step 2: Nucleophilic attack of water on carbocation. Step 3: Deprotonation to form an alcohol.
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| 32. |
Mechanism of a hypothetical reaction X_(2) + Y_(2) rarr 2XY is given below: (i) X_(2) rarr X + X (fast) (ii) X+Y_(2) hArr XY+Y (slow) (iii) X + Y rarr XY (fast) The overall order of the reaction will be : |
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Answer» 2 |
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| 33. |
Mechanism of a hypothetical recation X_(2)+Y_(2) to 2XY is given below (i) X_(2) to X+X("fast") (ii) X+Y_(2) hArr XY+Y("Slow") (iii) X+Y to XY("fast") The overall order of the reaction will be |
| Answer» ANSWER :A | |
| 34. |
Mechanism of a hypothetical reaction X_(2)+Y_(2)iff 2" XY" is given below : (i) X_(2)toX+X" (fast)" (ii) X+Y_(2)iff" XY"+Y" (slow)" (iii) X+Y to" XY (fast)" The overall order of reaction will be |
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Answer» 1 Rate `=k[X]{Y_(2)]` Taking step (i) to be reversible ( not GIVEN), `K_(EQ) = ([X]^(2))/([X_(2)]) or [X] = k_(eq)^(1//2) [X_(2)]^(1//2)` Substituing in (i), Rate `= k_(eq)^(1//2) [X_(2)]^(1//2) [Y_(2)] = k'[X_(2)]^(1//2)[Y_(2)]` OVERALL order `= (1)/(2) + 1 = (3)/(2) = 1.5` |
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| 35. |
Mechanism for hydrolysis of A will be |
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Answer» `A_(AC^(2))`
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| 36. |
Mechanical work is specially important in system that contain |
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Answer» Solid-liquid |
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| 37. |
Measurement of rate of oxygen utillsation by a unit volume of water over a period of time is to measure.: |
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Answer» BIOGAS generation |
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| 38. |
Measurement of the amount of dry gas collected over a water from volume of moist gas is based on : |
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Answer» Gay Lussac's law |
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| 40. |
Measles is a disease whichbelongs to the category of |
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Answer» Veneral disease |
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| 41. |
Measles is a disease which belongs to the category is? |
| Answer» Solution :viral disease | |
| 42. |
Measles is a disease which belong to the category of : |
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Answer» BACTERIAL disease |
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| 43. |
Me_3SiCl is used during polymerisation of organoisilicones because- |
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Answer» chain length of organosilicone polymers can be controlled by ADDING `MeSiCl` |
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| 44. |
Me_(3)C CH_(2)COOH is more acidic than Me_(3)SiCH_(2)COOH. |
Answer» Solution :SI (E.N.=1.8) is more electropositive than C (E.N.=2.5), therefore, `Me_(3)Si` (trimethylsilyl group) has greater +I-effect than that of `Me_(3)C` (t-butyl group). As a result, `Me_(3)Ci` intesifies the -ve charge on the carboxylate ion relative to t-butyl group and HENCE `Me_(3)C CH_(2)COOH` is a stronger acid than `Me_(3)SiCH_(2)COOH`. .
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| 45. |
Me_(2)C=CHCH_(2)-underset(Me)underset(|)C=CH-CH_(3)overset(H^(+))to'P' The main product 'P' is: |
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Answer»
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| 46. |
M(CO)_(x)(NO)_(y)underset(-CO)overset(+NO) to M(NO)_z Where EAN of metal (M) in both produce and reactant is samme and it is 54. then calculate value of (x+y=-z). (where x,y and z are netural numbers and M belong to 6th group according to long form of periodic table) |
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Answer» `Mo(CO)_(x)(NO)_(y) UNDERSET(-co)overset(+NO) to Mo(NO)_(z)` if y=2, then x=3 and z=4, HENCE x=y-z=3+2-4=1 |
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| 47. |
MCI_(2) + K_(2)CrO_(4) rarr yellow ppt what can be MCI_(2) a. If it is soluble in hot water? b. If is gives green colour in flame ? |
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Answer» SOLUTION :(A) `PbCI_(2)` (B) `BaCI_(2)` |
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| 48. |
[M(CO)_(x)(NO)_(y)] in this complex if all NO are replaced by CO can be [M(CO)_(z)] complex and EAN value for M is 36 value of x, y, z and M is respectively : |
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Answer» 3, 2, 5 and Fe `rArr` EAN = 26, 3CO are replaced by 2NO We get, `[Fe(CO)_(2)(NO)_(2)]` `rArr x=y=2` |
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| 49. |
M.C. Bain introduced a term ........... to represent the simultaneous adsorption and absorption. |
| Answer» SOLUTION :SORPTION | |