This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Gutta percha is |
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Answer» trans-Polyisoprene |
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| 2. |
Gutta -Percha and natural rubber are : |
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Answer» MADE up of same MONOMER |
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| 3. |
Natural rubber is a: |
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Answer» A TRANS 1,4-polyisoprene polymer |
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| 4. |
Gutta parcha rubber is : |
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Answer» A trans 1,4-polyisoprene polymer |
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| 5. |
Gun shots are made of lead with a little arsenic. The function of as is to increase: |
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Answer» RANGE of fire |
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| 6. |
Gun powder is: |
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Answer» `KNO_3 + CHARCOAL + S` |
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| 7. |
Gun-cotton is obtained when conc. Nitric acid reacts with |
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Answer» GLYCERINE |
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| 8. |
Gun-cotton is |
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Answer» Nitrosucrose |
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| 9. |
Gun metal is an alloy of |
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Answer» Cu and AI |
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| 10. |
Gun metal is an alloy of ..... |
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Answer» Cu and FE |
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| 11. |
Guanidine, (NH_2)_2 C=NH is said to be the strongest nitrogen containing organic base because |
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Answer» it has two `NH_2` groups Unusual stability of the conjugate acid of GUANIDINE explains why guanidine is the strongest organic known base. |
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| 12. |
Gum is |
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Answer» disaccharide |
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| 13. |
gt C = O is converted into -CH_(2)- by |
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Answer» Clemmenson reduction |
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| 14. |
Gums are : |
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Answer» POLYSACCHARIDES of more than |
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| 15. |
Guanine is held by three hydrogen bonds with the base : |
| Answer» Answer :C | |
| 16. |
Growing more trees help to : |
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Answer» REDUCE OXYGEN in the environment |
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| 17. |
Basic structure of all Chlorophylls comprises |
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Answer» `-CH_3,-C_2H_5,-CH=CH_2,-COOCH_3 and -CH_2CH_2COOC_20H_39` |
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| 18. |
Group VIII of Mendeleef's periodic table contains |
| Answer» Answer :D | |
| 19. |
Group reagent for group-1 basic radicals is |
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Answer» DIL. HCL |
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| 20. |
Group I filtrate is made moderately acidic before proceeding to group II. Expain. |
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Answer» Solution :precipitation of the sulphide can occur only when the ionic product `[M^(2+)][S^(2)]` exceeds the solubility product of the sulphides. MS In the presenc of acid, the ionisation of `H_(2)S` is suppressed due to the INCREASED concentration of `H^(o+)`. As a result, there are only few `S^(2-)` ions in solution which are enough to precipitate only group II cations as sulphides e.g., `Cus,PbS` etc. But for the precipitation of CDS, the concentration of `S^(2-)` is not enough. HENCE the concentration of `(H^(o+))` should be further decreased by diluting the solution so that the `H_(2)S` is ionised extensively As a result `S^(2-)` ions are made available in sufficient quantity which can precipitate thhe `Cd^(2+)` ions i.e., ionic product `[Cd^(2+)][S^(2-)]` exceeds solubility product of CdS. |
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| 21. |
Group 15 elements are commonly known as. |
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Answer» Halogens |
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| 22. |
Group 14 elements have general electronic configuration ________ |
| Answer» Answer :D | |
| 23. |
Group 15 elements exhibit + 3 and + 5 oxidation states + 3 oxidation state is more stable than + 5 in case of : |
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Answer» N |
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| 24. |
Group 14 elements exhibit +2 and +4 oxidation states. +2 oxidation states is more stable than +4 in case of : |
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Answer» C |
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| 25. |
Group 11 or IB elements are commonly known |
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Answer» COINAGE metals |
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| 26. |
Grignared reagent on reaction with ketones forms |
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Answer» TERTIARY alcohol |
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| 27. |
Grignards reagent may be obtained by reacting Mg metal with, |
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Answer» ACETALDEHYDE |
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| 28. |
Grignard's reagent reacts with ethanal (acetaldehyde) and propanone to give |
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Answer» Higher aldehydes with ethanal and higher ketones with propanone `CH_(3)MgBr + CH_(3)-underset(" "CH_(3))underset(|)(C )=O overset(H_(2)O)rarr`
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| 29. |
Grignard's reagent is prepared by the reaction between |
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Answer» zinc and alkyl HALIDE |
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| 30. |
Grignard regentgivesalkanewith : |
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Answer» `H_(2)O` |
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| 31. |
Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) Grignard reagent can't be prepared from |
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Answer»
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| 32. |
Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) The function of tetrahydrofuran in the preparation of Grignard reagent is that it |
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Answer» acts as a solvent |
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| 33. |
Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) H_(2)N(CH_(2))_(3)Br can't be converted into corresponding Grignard reagent because |
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Answer» reaction between `-NH_(2)andBr` GROUP present in the same molecule |
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| 34. |
Grignard reagents should be prepared under anhydrous conditions ? |
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Answer» Solution :Grignard reagents are very reactive. They react with moisture present in the apparatus or the staring materials, i.e., R - X and MG. `underset("Grignard reagent ") OVERSET(delta - delta + delta - ) (R - MgX + H ) - OH to R - H + Mg(OH) X ` Therefore, Grignard reagents MUST be prepared under anhydrous conditions. |
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| 35. |
Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) Griganrd reactions generally occur in dry ether because |
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Answer» the stronger ACID diethly ether will DISPLACE the weaker RH acid from its salt |
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| 36. |
Grignard reagents and organolithium compounds on addition to dry ice separately, followed by hydrolysis gives |
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Answer» KETONES and carboxylic acids respectively `R-MgX+O=C=Oto[R-overset(O)overset(||)(C)-OMgX] underset(-Mg(OH)X)overset(H^(+)//H_(2)O)to underset("Carboxylic acids")(R-overset(O)overset(||)(C)-OH)` Organolithium compounds being more nucleophilic add to C=O of addition product (I) to GIVE addition product (II) which upon SUBSEQUENT hydrolysis gives a ketone. `R-Li+O=C=Otounderset((I))([R-overset(O)overset(||)(C)-Oli ]) overset(R-Li)to [R-underset(R)underset(|)overset(O" "Li)overset(|)(C)-OLi]overset(H^(+)//H_(2)O)to[R-underset(R)underset(|)overset(OH)overset(|)(C)-OH underset(-H_(2)O)to]underset("Ketone")(R-overset(O)overset(||)(C)-R)`. |
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| 37. |
Grignard reagents are highly reactive and react with any source of__________to give hydrocarbons. |
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Answer» |
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| 38. |
Grignard reagents are prepared in |
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Answer» Benzene |
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| 39. |
Grignard reagent with hydrogen cyanide gives: |
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Answer» ALDEHYDE |
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| 40. |
Grignard reagent undergoes : |
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Answer» NUCLEOPHILIC substitution |
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| 41. |
Grignard reagent, PhMgBr on treatment with ethylene oxide followed by acid hydrolysis gives |
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Answer» `C_6H_5CH_2CH_2OH`
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| 42. |
Grignard reagent on reaction with acetone forms |
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Answer» TERTIARY alcohol |
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| 43. |
Grignard reagent of C_(6)H_(5)Cl can be prepared in THF but not in ether. Explain why? |
| Answer» Solution :DUE to +R-effect of Cl, the C-Cl bond has some double bond character and hence little more difficult to break. In other WORDS,ENERGY of activation for cleavage of C-Cl bond is little higher which cannot be supplied by the low boiling point (b.p. 308 K) of ether but can be easily supplied by the little higher b.p. (340 K) of THF. | |
| 44. |
Grignard reagent on addition with dry ice followed by hydrolysis gives _______. |
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Answer» ALDEHYDES and acids |
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| 45. |
Grignard reagent is prepared by the reaction between : |
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Answer» ZINC and ALKYL halide |
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| 46. |
Grignard reagent is not prepared in aqueous medium but it is prepared in ether medium, because. |
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Answer» the reagent FORMS complex with water
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| 47. |
Grignard reagent is not prepared in aqueous medium but prepared in ether mediumbecause the reagent |
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Answer» REACTS with water |
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| 48. |
Grignard reagent is not prepared in aqueous medium but prepared in ether medium because the reagent |
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Answer» REACTS with water |
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| 49. |
Grignard reagent is not prepared in aqueous medium but prepared in ether medium. Because |
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Answer» the reagent reacts with water
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| 50. |
Grignard reagent gives carbonyl compounds with |
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Answer» ROH |
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