Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Among the following compounds C_(5)H_(7)NH_(2),NH_(3),CH_(3)NH_(2),C_(2)H_(5)NH_(2) and C_(6)H_(5)NH, the least basic compound is

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`C_(3)H_(7)NH_(2)`
`NH_(3)`
`CH_(3)NH_(2)`
`C_(6)H_(5)NH_(2)`

Solution :`C_(6)H_(5)NH_(2)` is least basic compound DUE to RESONANCE by which the lone PAIR of nitrogen TAKES part in resonance `&` due to unavailability of lone pair on N. Aniline become less basic. The lone pair of N is delocalized into benzene ring by resonance
2.

Among the following compound which one is planar in shape

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methane
Acetylene
BENZENE
isobutane

Solution :All 6 CARBONS of Benzene are `sp^2`- hybridised so it is PLANAR
3.

Among the following compound, the weakest acid is-

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`HC-=CH`
`C_(6)H_(6)`
`C_(2)H_(6)`
`CH_(3)OH`

ANSWER :C
4.

Among the following compound. (a) Number of compounds which are aromatic = w (b) Number of compounds which are non-aromatic = x (c) Number of compounds which are anti-aromatic = y (d) Number of compounds which readily undergo Dimerzation at room temperature = z Sum of w + x + y + z =....

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Solution :`w rArr a, B, f, h, I, j`
`x rArr d, E, g, l`
`y rArr c, K`
`d rArr c, k`
SUM of `w + x + y + z = 14`
5.

Among the following compound the reactivity order is (1)H - CHO""(2) CH_(3) - CHO (3) CH_(3) - overset(O)overset(||)(C) - CH_(3)""(4) C_(2)H_(5)-COCH_(3)

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` 1 gt 2 gt 4 gt 3`
`4 gt 3 gt2 gt 1 `
` 1 gt 2 gt 3 gt 4`
` 1 gt 3 gt 4 gt 2`

ANSWER :C
6.

Among the following compound s that is bothparamagnetic and colouredis

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`K_(2)Cr_(2)O_(7)`
`(NH_(4))_(2)[TiCl_(6)]`
`VOSO_(4)`
`K_(3)[Cu(CN)_(4)]`

Solution :For a compoun to be coloured, the CENTRAL atom should have INCOMPLETELY filled d-orbital and to be a pramagnetic , there should be at least one unpaired electron Here, we have
`{:("Compound","Central atom","Electronic config."),(K_(2)Cr_(2)O_(7),._(24)Cr(VI),3s^(2)3p^(6)),((NH_(4))_(2)[TiCl_(6)],._(22)Ti(IV),3s^(2)3p^(6)),(VOSO_(4),._(23)V(IV),3s^(2)3p^(6)3d^(1)),(K_(3)[Cu(CN)_(4)],._(29)Cu(I),3s^(2)3p^(6)3d^(10)):}`
7.

Among the following compound. (a) Number of compounds which are aromatic = P (b) Number of compounds which are anti-aromatic = Q (c) Number of compounds which are non-aromatic = R (d) Number of compounds which readily undergo dimerization at room temperature = S (e) Number of compound which reacts with active metal = T Sum of P + Q + R + S + T=

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SOLUTION :`P + Q + R = 12`
`S = (B + d) = 2`
`T = (b + d + f + I + 1) = 5`
Sum of `P + Q + R + S + T = 19`
Due to STERIC hindarance dimerization does not take place.
8.

Among the following complexes the one which shows Zero crystal field stabilization energy (CFSE) is

Answer»

`[Ni(CO)_(4)]` and `[NiCl_(4)]^(2-)` are diamagnetic and `[Ni(CN)_(4)]^(2-)` is paramagnetic
`[NiCl_(4)]^(2-)` and `[Ni(CN)_(4)]^(2-)` are diamagnetic and `[Ni(CO)_(4)]` is paramagnetic
`[Ni(CO)_(4)]` and `[Ni(CN)_(4)]^(2-)` are diamagnetic and `[NiCl_(4)]^(2-)` is paramagnetic
`[Ni(CN)_(4)] ` is diamagnetic while `[NiCl_(4)]^(2-)` and `[Ni(CN)_(4)]^(2-)` are paramagnetic .

Solution :c)it is the CORRECT answer.
9.

Among the following componds which have more than one type of hybridisation for carbon atom (i)CH_3CH_2CH_2CH_3 (ii)CH_3-CH=CH-CH_3 (iii)CH_2=CH-C-=CH (iv)H-C-=C-H

Answer»

(II) and (III)
(ii)
(iii) and (IV)
(iv)

ANSWER :A
10.

Among the following complexes which one shows zero CFSE ?

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`[Mn(H_(2)O)_(6)]^(3+)`
`[FE(H_(2)O)_(6)]^(3+)`
`[CO(H_(2)O)_(6)]^(2+)`
`[Co(H_(2)O)_(6)]^(3+)`

Answer :B::C
11.

Among the following complexes the one which shows zero crystal field stabilisation energy is

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`[MN(H_2O)_6]^(3+)`
`[Fe(H_2O)_6]^(3+)`
`[Co(H_2O)_6]^(2+)`
`[Co(H_2O)_6]^(3+)`

Answer :B
12.

Among the following complexes, the one which shows zero crystal field stabilization energy (CFSE) is

Answer»

`[Mn(H_(2)O)_(6)]^(3+)`
`[Fe(H_(2)O)_(6)]^(3+)`
`[Co(H_(2)O)_(6)]^(2+)`
`[Co(H_(2)O)_(6)]^(3+)`

Solution :`H_(2)O` is a weak field LIGAND. Hence,
`Delta_(0) lt` PAIRING ENERGY.
CFSE = `(-0.4x+0.6y) Delta_(0)`
where x and y are no. of electrons OCCUPYING `t_(2g)` and `e_(g)` orbitals respectively.
For `[Fe(H_(2)O)_(6)]^(3+)` complex ion, `Fe^(3+)(3d^(5)) = t_(2g)^(3) e_(g)^(2)`
`therefore CFSE=-0.4xx3+0.6xx2=0Dq`
13.

Among the following complexes (K - P) : K_(3) [Fe(CN)_(6)] - K , [Co(NH_(3))_(6)]Cl_(3)- L , Na_(3)[Co("oxalate")_(3)]-M , [Ni(H_(2)O)_(6)]Cl_2 - N, K_(2) [Pt(CN)_(4)]-O and [Zn(H_(2)O)_(6)] (NO_(3))_(2)-P, the diamagnetic complexes are

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K , L , M , N
K , M , O , P
L , M , O, P
L , M , N , O

Solution :For COMPLEXES L and M , i.e, `[Co(NH_(3))_(6)]^(3+)` and `[Co("OX")_(3)]^(3-)`
`Co^(3+) (3D^(6)) is d^(2) sp^(3)` hybridised .

For complex K , i.e, `[Fe(CN)_(6)]^(3-) , Fe^(3+) (3d^(5)) is d^(2) sp^(3)` hybridised .

For complex O i.e., `[PT(CN)_(4)]^(2-)` ,
`Pt^(2+) (5d^(8)) is DSP^(2)` hybridised.

For complexP , i.e, `[Zn(H_(2)O)_(6)]^(2+)`
`Zn^(2+) (3d^(10)) is sp^(3) d^(2)` hybridised .

For complex N, i.e., `[Ni(H_(2)O)_(6)]^(2+)` ,
`Ni^(2+) (3d^(8)) is sp^(3) d^(2)` hybridised .

Hence , complexes L, M , Oand P are diamagnetic .
14.

Among the following complexes (K-P) K_(3)[Fe(CN)_(6)] (K), [Co(NH_(3))_(6)]Cl_(3) (L), Na_(3)[Co("oxalate")_(3)] (M), [Ni(H_(2)O)_(6)]Cl_(2) (N), K_(2)[Pt(CN)_(4)](O) and [Zn(H_(2)O)_(6)](NO_(3))_(2)(P) the diamagnetic complexes are

Answer»

<P>K, L, M, N
K, M, O, P
L, M, O, P
L, M, N, O

Solution :K : `K_(3)[Fe(CN)_(6)],Fe^(3+)=3d^(5), d^(2)sp^(3)` HYBRIDIZATION, number of unpaired ELECTRONS = 1, paramagnetic.
L : `[Co(NH_(3))_(6)]Cl_(3), Co^(3+)=3d^(6), d^(2)sp^(3)` hybridization, number of unpaired electrons = 0, diamagnetic.
15.

Among the following complexes : K_(3)[Fe(CN)_(6)],[Co(NH_(3))_(6)]Cl_(3) , Na_(3)[Co ( o x )_(3)],[Ni(H_(2)O)_(6)]Cl_(2),K_(2)[Pt(CN)_(4)] and [Zn(H_(2)O)_(6)(NO_(3))_(2)] The diamagnetic are .

Answer»

K, M, O, P
K, L, M, N
L, M, N, O
L, M, O ,P

Answer :D
16.

Among the following complexes , how many have 'spin only' magnetic moment of 2.83 B.M. ? [Ni(CO)_4],[Ni(CN)_4]^(2-),[NiCl_2( P Ph_3)_2], [NiCl_4]^(2-),[NiF_6]^(2-),[NiF_6]^(4-),[Ni(NH_3)_6]^(2+),[Ni(en)_3]^(2+),[Ni(H_2O)_6]^(2+)

Answer»


SOLUTION :
17.

Among the following chemical reactions, the one representing homogenous catalysis is :-

Answer»

`N_(2)(g) + 3H_(2) (g) overset(Fe) to2NH_(3)(g) `
`2 SO_(2)(g) + O_(2)(g) overset(2NO) to2 SO_(3) (g)+2NO(g) `
CO(g) + 2H2(g) `overset(Ni)to ` CH4(g) + H2O
2 SO2(g) + O2(g) `overset(V_(2) O_(5))to` 2SO3(g)

Answer :B
18.

Among the following, chain transfer reagent(s) is/are

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CARBON tetrachloride
benzoyl peroxide
benzoquinone
carbon tetrabromide.

Solution :Carbon tetrachloride and carbon tetrabromide ACT as chain TRANSFER reagents in VINYL polymerisation.
19.

Among the following cells Leclanche cell (I) Nickel-cadmium cell (II), Lead storage battery (III) and Mercury Cell (IV), primary cells are …………. .

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I & II
I & III
II & III
I & IV

Answer :D
20.

Among the following cells Lechanche cell (I), Nickel-cadmium cell (II), Lead storage battery (III), Mercury (IV), primary cells are

Answer»

I and II
I and III
II and III
I and IV

Solution :Leclanche cell and MERCURY CELLS are PRIMARY cells.
21.

Among the following cells I. Leclanche cell "" II. Nickel - Cadmiun cell III. Lead storage battery "" IV. Mercury cell Primaru cells are ………….. .

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I and IV
I and III
III and IV
II and III

Answer :A
22.

Among the followingcellsi) Leclanche cell II) Nickel - Cadmium cell (iii) Leadstoragebattery (iv) Mercury cell Primarycellsare

Answer»

I and IV
I and III
III and IV
II and III

SOLUTION :(iv) , (i) , (ii) , (iii)
23.

Among the following cells I) Leclanchecell II) Nickel - Cadmium cell III) Lead storage battery (IV) Mercury cell Primary cells are

Answer»

I and IV
I andIII
III and IV
II and III

Answer :A
24.

Among the following carbocations : "(I) "Ph_(2)C^(+)CH_(2)Me"(II) "PhCH_(2)CH_(2)CH^(+)Ph "(III) "Ph_(2)CHCH^(+)Me"(IV) "Ph_(2)C(Me)CH_(2)^(+) The order of stability is

Answer»

`IVgtIIgtIgtIII`
`IgtIIgtIIIgtIV`
`IIgtIgtIVgtIII`
`IgtIVgtIIIgtII`

ANSWER :B
25.

Among the following carbocations : (I) Ph_(2) C^(+) CH_(2) Me(II) PhCH_(2) CH_(2) CH^(+)Ph (III)Ph_(2) "CHCH"^(+) Me(IV) Ph_(2) "C(Me)CH"_(2)^(+)the order of stability is

Answer»

`IV gt II gt I gt III `
`I lt II lt III lt IV`
`II gt I gt IV gt III`
`I gt IV gt III gt II`

SOLUTION :
Stability of carbocation DEPENDS upon NUMBER of resonating structures and extent of +1, -I effect.
26.

Among the following bonds which has the most polar character :

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C-O
C-Br
C-F
C-S

Answer :C
27.

Among the following anions overset-CH_3 overset-NH_2 OH^- F^-, the order of basicity is:

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agtbgtcgtd
bgtagtcgtd
cgtbgtagtd
cgtagtbgtd

Answer :A
28.

Which of the following is an acidic salt ?

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`NaH_(2)PO_(2)`
`NaH_(2)PO_(3)`
`Na_(2)HPO_(3)`
`Na_(3)PO_(4)`

ANSWER :2
29.

Among the following amino acids, the (R)-enantiomer is represented by:

Answer»




ANSWER :B
30.

Among the following amines, the strongest Bronsted base is….

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`NH_3`

Solution : Aniline is a weaker base than NH, due to delocalization of lone pair of electrons on the N ATOM into the benzene ring. Pyrrole (c)is not at all basic because the lone pair of electrons on the N-atom is DONATED towards aromatic sextet formation. Therefore, PYRROLIDINE (d) has a strong TENDENCY to accept a proton and is hence it is the strongest Bronsted base.
31.

Among the following amines, the strongest Bronsted base is

Answer»

`NH_(3)`


Solution :In (c), electrons on the N ATOM are delocalized over two double bonds but in (d), electrons are more strongly delocalized over the benzene RING but in (b), electrons are not delocalized at all, therefore, it is the strongest BASE. Further, being a `2^(@)` amine, it is more basic than EVEN `NH_(3)`. THUS, option (b) is correct.
32.

Among the following amines, the strongest Bronsted base is____

Answer»


`NH_(3)`

ANSWER :D
33.

Among the following actinide pairs, the maximum oxidation states is shown by

Answer»

U and NP
Np and PU
Pu and An
U and Pa

Solution :Both Np and Pu show HIGHEST oxidation state of `+7`
34.

Among the following amines the correct order of decreasing basic strength is:

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IVltIIltIIIltI
IltIIltIIIltIV
IIltIltIIIltIV
IIIltIIltIltIV

Answer :A
35.

Among the following acids which has the lowest pK_a value

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`CH_3 COOH`
`HCOOH`
`(CH_3)_2 CH - COOH`
`CH_3CH_2 COOH`

Answer :B
36.

Among the following acidic strength is (1) CH_(3) - CH_(2) - COOH ""(2) CH_(3) - underset(CN) underset(|) (CN) - COOH (3)CH_(3) - underset(Cl) underset(|) (CH) - COOH""(4) CH_(3) - underset(NO_(2))underset(|) (CH) - COOH

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`4 gt 1 gt 2 gt 3`
` 3 gt 4 gt 2 gt 1`
` 4 gt 2 gt 3 gt 1`
` 4 gt 3 gt 2 gt 1`

Answer :C
37.

Among the following acids, the one which can form an anhydride most easily is :

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`{:(COOH),(|),(COOH):}`
`{:(CH_(2)CH_(2)COOH),(|),(CH_(2)CH_(2)COOH):}`

ANSWER :C
38.

Among the following acids, which has the lowest pK_a value-

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`(CH_3)_2CHCO_2H`
`C_2H_5CO_2H`
`CH_3CO_2H`
`HCO_2H`

ANSWER :D
39.

Among the following, achiral amino acid is'

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GLYCINE
ALANINE
PROLINE
TRYPTOPHAN

ANSWER :A
40.

Among the following a refrigirant is

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`CHCl_3`
`CH_2 F_2`
`C Cl_4`
`C Cl_4 F_2`

ANSWER :D
41.

Among the following, a naturalpolymer is

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CELLULOSE
PVC
polyethylene
TEFLON

SOLUTION :Cellulose is a NATURAL POLYMER .
42.

Among the folllowing the weakest lewis base is…….

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`H^-`
`OH^-`
`CL^-`
`HClO_3^-`

Solution :`Cl^-` is a CONJUGATE base of STRONG acid HCl.
43.

Among the fluorides given which will further react with F_2 :

Answer»

NAF
`CaF_2`
`SF_6`
`IF_5`

ANSWER :D
44.

Among the enlisted compounds, which one is used as a froth stabilizer in the froth floatation process?

Answer»

Aniline
Phenol
Benzaldehyde
Anisole

Answer :A
45.

Among the elements from atomic number 1 to 36, the number of elements which have an unpairedelectron in their S subshell is

Answer»

4
7
6
9

Solution :`""_(1)H=1s^(1),""_(3)Li=2s^(1),""_(11)Na=3s^(1),""_(19)K=[Ar]`
`4s^(1)""_(24)Cr=[Ar]3D^(5) 4s^(1)""_(29)Cu=[Ar]3d^(10)4s^(1)`
46.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is

Answer»

`MgltCaltClltP`
`CL ltPltMgltCa`
`PltCl ltCaltMg`
`CaltMgltPltCl`

SOLUTION :In a period SIZE decreases from left to RIGHT.
47.

Among theelectrolytes Na_(2)SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3)and NH_(4)Cl_(4), the mosteffective coagulating agent for Sb_(2)S_(3) sol is .

Answer»

`Na_(2)SO_(4)`
`CaCl_(2)`
`Al_(2)(SO_(4))_(3)`
`NH_(4)Cl`

SOLUTION :`Sb_(2)S_(3)` is a negative sol and according to HardySchulze rule:
(i)Ions carrying charge OPPOSITE to that of sol particles are effective in causing coagulation.
(ii) Coagulating power of an electrolyte is directly proportional to the valency of the active ions.
`therefore ` Outof the given options the mosteffective coagulatingagentis `Al_(2)(SO_(4))_(3) ` or `Al^(3+)` ion.
48.

Amongthe electrolytes Na_(2)SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3) and NH_(4)Cl, the most effective coagulating agent for Sb_(2)S_(3) sol is

Answer»

`Na_(2)SO_(4)`
`CaCl_(2)`
`Al_(2)(SO_(4))_(3)`
`NH_(4)Cl`

Solution :`Sbg_(2)S_(3)` is a negatively charged SOL. The most effective coagulating agent will be electrolyte with HIGHEST positive cfharge on the cartion, vz, `AL_(2)(SO_(4))_(3).` The order is
`Al^(3+)gt Ca^(2+)gt Na^(+)gt NH_(4)^(+).`
49.

Amongthe electrolytes Na_2SO_4 , CaCl_2, Al_2(SO_4)_3 and NH_4Cl , the most effectivecoagulating agent for Sb_2S_3 sol is................

Answer»

`Na_2SO_4`
`CaCl_2`
`Al_(2)(SO_4)_3`
`NH_4Cl`

SOLUTION :`Al_(2)(SO_4)_3`
50.

Among the electrolytesNa_(2)SO_(4) , CaCI_(2), AI_(2)(SO_(4))_(3) and NH_(4)CIthe most effctive oagulating agent for Sb_(2)S_(3) sol is

Answer»

`Na_(2)SO_(4)`
`CaCI_(2)`
`AI_(2)(SO_(4))_(3)`
`NH_(4)CI`

Answer :C