Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Red and white Phosphorous will differ but not in

Answer»

smell
SOLUBILITY in `CHCl_3`
EXHIBITING phosphorescence
REACTIONS with `HNO_3`

Solution :Allotropes POSSES different physical properties but to different chemical properties
2.

Rectified spirit contains :

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`75.0%` ALCOHOL
`85.5%` alcohol
`95.6%` alcohol
`100.0% `alcohol

Answer :C
3.

Rectified spirit is denatured by adding

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methyl alcohol and formic acid
methyl alcohol and benzene
methyl alcohol and pyridine
methyl alcohol and acetic acid.

Solution :RECTIFIED SPIRIT is DENATURED by ADDING methyl alcohol and pyridine.
4.

Rectified spirit is made unsuitable for drinking by adding

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`CH_(3)OH`
1-propanol
Water
2-propanol

Answer :A
5.

Rectified spirit is a mixture of:

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95% ETHYL ALCOHOL + 5% water
94% ethyl alcohol + 4.53% water
94.4% ethyl alcohol + 5.43% water
95.57% ethyl alcohol + 4.43% water

Answer :D
6.

Rectified spirit contains 95% ethanol by mass. The mole fraction of ethanol will be

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0.881
0.99
0.118
0.81

Solution :95% ethanol `sol^(n)` means 95 g ethanol in 100 g sol., i.e., 5 g WATER
`X_(2)=n^(2)/(n_(2) + n_(1))=(W_(2)//M_(2))/((W_(2)//M_(2))+(W_(1)//M_(1)))`
`x_(2)=(95//46)/(95//46 + 5//18)=2.065/(2.065+0.278)=2.065/2.343=0.881`
7.

Rectifiedspirit can be dried with :

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conc. `H_(2)SO_(4)`
CaO
anhydrous `CaCl_(2)`
slaked lime

Answer :B
8.

Rectified spirit can be converted into absolute alcohol by distilling with

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`Na_2CO_3`
`NA`
`CONC. H_2SO_4`
`CAO`

ANSWER :D
9.

Recharging of lead storage battery involves

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ANODE is REDUCED to pb
cathode is reduced to pb
cathode is oxidised to pb
anode is oxidised to `pbO_(2)`

ANSWER :A
10.

Receptors of hormones are generally

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CARBOHYDRATES
Vitamins
Lipids
Protiens

Answer :D
11.

Receptors are made from ........

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fat
lipid
PROTEIN
carbohydrates 

SOLUTION :Protein.
12.

Recent X-ray work, IR and other spectroscopic methods have proved that Turnbull's blue is identical to Prussian blue. Q. Intense blue colour arises as a result of:

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ELECTRON TRANSFER between `FE(II) and Fe(I)`
electron transfer between Fe(II) and Fe(III)
d-d transition
spin magnetic moment

Answer :B
13.

Receptors are

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Proteins
Lipids
CARBOHYDRATES
Nucleric acids

Answer :A
14.

Recently discovered allotropes of carbon is ………………..

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GRAPHITE
Diamond
Carbon nanotubes
Fullerences

Answer :C
15.

Recent X-ray work, IR and other spectroscopic methods have proved that Turnbull's blue is identical to Prussian blue. Q. What is the common formula of Turnbull's blue and Prussian blue?

Answer»

`Fe_(3)[FE(CN)_(6)]_(2)`
`Fe_(4)[Fe(CN)_(6)]_(3)`
`KF e[Fe(CN)_(6)]`
`KF e_(2)[Fe(CN)_(6)]`

Answer :C
16.

Recent method for the charaterisation of an organic compound is :

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VACUUM distillation
Sepectroscopic method
Sublimation
Fractional crystallisation

Answer :B
17.

Recemic mixture is obtained due to the halogenation of

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isopentane
n-pentane
neopentane
Both(a) and(b)

Solution :If FREE radical halogenation GENERATE a chiralv carbon recemic mixture of halides are always FORMED due to equal PROBABILITY of halogenation from both sides of planar free radical
.
18.

Reason of lanthanoid contraction is…..

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NEGLIGIBLE SCREENING EFFECT of f-orbitals
Increasing NUCLEAR charge
Descreasing nuclear charge
Decreasing screening effect

Answer :A
19.

Reason of lanthanoid contraction is

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Decreasing SCREENING effect
Negligible screening effect of 'F' ORBITALS
Increasing nuclear CHARGE
Decreasing nuclear charge

Solution :Negligible screening effect of .f. orbital is responsible for LANTHANOID contraction
20.

Reason of lanthanoid contraction is -

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negligible screening effect of F - orbitals
increasing NUCLEAR charge
DECREASING nuclear charge
decreasing screening effect

Answer :A
21.

Reason of lanthanodi contraction is

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NEGLIGIBLE screening effect of 'F' orbitals
increasaing nuclear CHARGE
decreasing nuclear charge
decreasing screening effect

Answer :A
22.

Reason for geometrical isomerism shown by 2- butene is

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Chiral carbon
FREE rotation about single bond
Free rotation about double bond
RESTRICTED rotation about double bond

Solution :Restricted rotation is ESSENTIAL condition for GEOMETRICAL isomerism.
23.

Reason for excessive solubility of alcohol in water is due to

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COVALENT BONDING
H- bonding with `H_2O `
IONIC bonding
Lewis base character

Answer :B
24.

Rearrange the following in an increasing order of their basic strengths : ""C_(6)H_(5)NH_(2), C_(6)H_(5)N(CH_(3))_(2), (C_(6)H_(5))_(2)NH" and "CH_(3)NH_(2)

Answer»


Answer :The increasing order of basic STRENGTH is
`""(C_(6)H_(5))_(2)NH lt C_(6)H_(5)N(CH_(3))_(2) ltC_(6)H_(5)NH_(2) lt CH_(3)NH_(2)`
25.

Reason: Complex anion [Re_(2)Cl_(8)]^(2-) has one delta-bond, one sigma and one pi-bond. Reason: d_(z^(2)) orbital can never form delta-bond.

Answer»

If ASSERTION is true but the REASON is false
If assertion is false but reason is true
If both assertion and reason are true and the reason is the CORRECT EXPLANATION of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion

Solution :
26.

Rearrange the following in an increasing order of their basi strengths: C_(6)H_(5)NH_(2),C_(6)H_(5)N(CH_(3))_(2),(C_(6)H_(5))_(2)NH and CH_(3)NH_(2).

Answer»

Solution :(i) Due to delocalization of lone pair of electrons of the N-atom over the BENZENE ring, all aromatic amines are less basic than alkylamines, i.e., `CH_(3)NH_(2)`.
(ii) PRESENCE of electron donating grous (i.e., `CH_(3)`) on the N-atom increases the basicity of substituted aniline w.r.t. `C_(6)H_(5)NH_(2)`.
(iii) In `(C_(6)H_(5))_(2)NH`, th lone pair of electrons on the N-atom is delocalized over two benzene rings instead of one in `C_(6)H_(5)NH_(2)`, therefore, `(C_(6)H_(5))_(2)NH` is much less basic than `C_(6)H_(5)NH_(2)`.
Combining all the three trends together, the basicitiy of the four amines increases in the ORDER: `(C_(6)H_(5))_(2)NH lt C_(6)H_(5)NH_(2) lt C_(6)H_(5)N(CH_(3))_(2) lt CH_(3)NH_(2)`.
27.

Rearrange the following compounds in the increasing order of their boiling points : CH_(3)-CHO, CH_(3)-CH_(2)-OH, CH_(3)-CH_(2)-CH_(3)

Answer»

Solution :The compounds MAY be REARRANGED in increasing ORDER of theirboiling points as under :
`CH_(3)CH_(2)CH_(3) tl CH_(3)CHO LT CH_(3)CH_(2)OH`
28.

Rearrange the following compounds in increasing order of their boilig ponits: CH_(3)-CHO,CH_(3)CH_(2)-OH,CH_(3)-CH_(2)-CH_(3).

Answer»

Solution :Due to EXTENSIVE intermolecular H-bonding, the b.p. of `CH_(3)CH_(2)OH` is the highest. Now `CH_(3)CHO` is polar while `CH_(3)CH_(2)CH_(3)` is non-polar. THEREFORE, due to dipole-dipole interactions, the b.p. of `CH_(3)CHO` is higher than that of `CH_(3)CH_(2)CH_(3)`. thus, the b.ps. of the three compounds INCREASE in the order:
`CH_(3)CH_(2)CH_(3) LT CH_(3)CHO lt CH_(3)CH_(2)OH`.
29.

Rearrange the following compounds in an increasing order of their basic strengths : ""Aniline, p-nitroaniline, p-toluidine

Answer»


ANSWER :p-nitroaniline `LT` ANILINE `lt` p-toluidine
30.

Rearrange the compounds of each of the following sets in order of reactivity towards S_(N_(3)^(2)) displacement : (i) 2- Bromo-2-methylbutane, 1-Bromopentane, 2- Bromopentaure. (ii) 1- Bromo-3-methylbutance, 2-Bromo-2-methylbutance,3-Bromo-2- methybutane. (iii)1- Bromobutane, 1- Bromo-2, 2-dimethylbutane 1-Bromo -2- methylbutane.

Answer»

Solution :(i) 2-Bromo-2-methybutane,
1-Bromopentane , 2Bromopentane:
The reactivity is `SN^(2)` reaction depents uponsteric hindance, more thesteric hindence slower the reaction.

Sincedue to stericreasionthe order of reactivityin `SN^(2)`reactionfollowsthe order:
`1^(@) gt2^(@) GT3^(@)`, therefore, order of reactivityofthe givenalklyl BROMIDES is :
1-Bromopentane `gt 2`- Brompebtane `gt 2-` Bromo -2 Methylbutane.

Since due to steric reason, the order of reactivity of alkyl halides in `SN^(2)` reactionfollows
the order `1^(@) gt 2^(@) gt 3^(@)` therefore, the order ofreactivity of thegivenalkyl bromies is .
1-Bromo-3-Methylbutane`gt2`- Bromo -3-Methylbutane `gt 2`-Bromo -2-Methylbutane.

Since in CASE of `1^(@)` alkyl halides,steric hindrancein theorder : n-alkyl halides,
alkyl halide substituentsatthe `beta`-position, therefore , the reactivitydecrease in the sameorder- Thu, the reactivityof the givenalkyl bromides decrease in the order.
1-Bromobutance `gt 1`- Bromo - 3-Methybutane `gt 1`- Bromo-2- Methylbutane `GT1`- Bromo-2-Methylbutane`gt1`- Bromo-2-dimethylpropane.
31.

Rearrange the compounds of each of the following sets in order of reactivity towards S_(N)2displacement : (i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2 Bromopentane (ii) 1-Bromo-3-methylbutane, 2-Bromo-2 methylbutane, 3-Bromo-2-methylbutane (iii)1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane

Answer»

Solution :(i) `UNDERSET("TERTIARY halogencompound")(CH_(3) 0 CH_(2) - underset(CH_(3))underset(|)overset(Br)overset(|)C - CH_(3)) "" underset("Primary halogen compound ")(CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)Br) "" underset("Secondary halogen compound")(CH_(3)CH_(2)CH_(2)overset(Br)overset(|)CHCH_(3))` In `S_(N)2` reaction , the order of reactivity is: Primary ` gt` Secondary ` gt` Tertiary .
Therefore, the order of reactivity for the given COMPOUNDS will be
1-Bromopentane `gt`2-Bromopentane `gt`2-Bromo-2-methylbutane
(ii) `underset("Primary halide")(CH_(3) - overset(CH_(3))overset(|)(CH) - cH_(2) - CH_(2)Br ) "" underset("Tertiary halide")(CH_(3) - CH_(2) - underset(CH_(3))underset(|)overset(Br)overset(|)C - CH_(3)) "" underset("Secondary halide")(CH_(3) - overset(Br)overset(|)CH - underset(CH_(3))underset(|)CH - CH_(3))`
Therefore , the order of reactivitywill be
1-Bromo-3-methylbutane `gt`3-Bromo-2-methylbutane `gt ` 2-Bromo-2-methylbutane
(iii) `underset("Primary halide (I)")(CH_(3) - CH_(2) - CH_(2) - CH_(2)Br) "" underset(II) (CH_(3) - underset(CH_(3))underset(|)overset(CH_(3))overset(|)C - CH_(2)Br) "" underset(III)(CH_(3) - CH_(2) - overset(CH_(3))overset(|)(CH) - CH_(2)Br)`
All the three are primary halide. But the NUCLEOPHILE will face maximum hinderance with II followed by III followed by I. Hence, the order of reactivity towards `S_(N)2`is:
1-Bromobutane `gt`1-Bromo-2-methylbutane `gt` 1-Bromo-2,2-dimethylpropane.
32.

Real ggas show same behaviour as that of an ideal gas at

Answer»

LOW TEMPERATURE and HIGH pressure
High temperature and low pressure
Low temperature and low pressure
High temperature and high pressure

Answer :B
33.

Real gases show an ideal-like behaviour at

Answer»

HIGH PRESSURE and LOW temperatures
Low pressure and high temperatures
STANDARD pressure and standard temperature
High pressure and high temperatures

Answer :C
34.

Reagents which cannot be used to distinguish Allylbromide from n - propyl bromide are

Answer»

`Br_2//"CCl"_4`
Shaking with an aqueous solution of `AgNO_3`
Boiling with alcoholic KOH solution followed by acidification with `HNO_3`and ADDITION of `AgNO_3`solution
FUSION with sodium metal followed by acidification with dil `HNO_3`and addition of `AgNO_3` solution

Solution :a) `Br_2//"CCl"_4` can decolourise both allyl BROMIDE and n-propyl bromide as they contain double bond
b) Shaking with `AgNO_3` - Both can react with` AgNO_3`and can form AgBr an yellow ppt
c) Boiling with alcoholic KOH, followed by acidification with `HNO_3`and addition of `AgNO_3` gives same product of yellow ppt of AgBr
d) Fusion with sodium metal followed by acidification with dil `HNO_3`and addition of `AgNO_3`gives an yellow ppt of AgBr
35.

Reagents which cannot be used to distinguish allyl bromide from n-propyl bromide are

Answer»

`Br_(2)//C Cl_(4`<BR>by SHAKING with an aqueous solution of `AgNO_(3)`
by boiling with aqueous KOH solution FOLLOWED by acidification with dil. `HNO_(3)` and addition of `AgNO_(3)` solution

Answer :C::D
36.

Reagents used in hydroboration oxidation reaction

Answer»

`B_2H_6+CrO_3 + NAOH`
`B_2H_6 + H_2O_2 + NaOH, THF`
`B_2H_6+ "ACIDIC" KMnO_4 + NaOH`
`B_2H_6`+ dil. `HNO_3` + NaOH

ANSWER :B
37.

Reagent which cannot be used to distinguish allyl bromide from n-propyl bromide are:

Answer»

`Br_(2)//C Cl_(4)`
SHAKING with an aqueous solution of `AgNO_(3)`
Boiling with alcoholic KOH solution followed by ACIDIFICATION wiith dilute `HNO_(3)` and addition of `AgNO_(3)` solution.
Fusion with sodium metal followed by acidification with dilute `HNO_(3)` and addition of `AgNO_(3)` solution.

Solution :yellow precipitate will be formed in both the cases therefore, both of them cannot be used for making distruction.
38.

Reagentused to test Ni^(2+) ionis (a)_____.

Answer»


ANSWER :DIMETHYL glyaxime
39.

Reagent used tp detect sulphate ion is ……………… .

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`BaCl_(2)`
`BaSO_(4)`
`(CH_(3)COO)_(2)PB`
Both (a) and (c )

SOLUTION :Both (a) and (c )
40.

Reagent used to distinguish H_2O_2 and O_3 is:

Answer»

`PBS`
STARCH and IODINE
`KMnO_4`
BLEACHING powder

Answer :C
41.

Reagent used to carry out following conversion from alkyne to alkene is

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`Pd-C//H_(2)`
`Na//NH_(3)`
`Pt//H_(2)`
`Ni//H_(2)`

ANSWER :B
42.

Reagent used in Reimer -Tiemann reaction are

Answer»

`CH_3Cl` and aq.NaOH
`CH_3Cl` and `POCl_3`
`CHCl_3` and aq.NaOH
`CHCl_3` and alc.NaOH

Answer :C
43.

Reagent used in Finkestein reaction is

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NAI in DRY acetone
HI in dry acetone
NaOI in dry acetone
NaI in dry ether

Answer :A
44.

Reagent used for detecting CHCI_3 is

Answer»

`AQ. AgNO_3`
`1^@` - AMINE
`1^@` amine + KOH (aq)
`1% C_2H_5OH`

ANSWER :A
45.

Reagent that candetect any of Fe^(3+),Co^(2+) and Cu^(2+) is (a) ____.

Answer»


ANSWER :`NH_(4)SCN`
46.

Reagent required to convert B to A is

Answer»

`K_(2) Cr_(2) O_7 //H^(+)`
PDC in `CH_2Cl_2`
Cu, `300^@C`
Both 2 and 3

Answer :D
47.

Reagent (s) used for the conversion of propanol into propane is

Answer»

`I_2//P`
(i) TsCl/Py (II) `LiAlH_4`
CONE. `H_2SO_4`
`CH_2N_2` /ether

Answer :B
48.

Reagent A used in this change is

Answer»

`B_(2)H_(6)`
`LiAlH_(4)`
`Sn//HC l`
`CH_(3)OH//Na`

ANSWER :B
49.

Reagent not stored in glass bottles?

Answer»

`HCL`
`HBR`
`HF`
`HI`

SOLUTION :`HCl`
50.

reagent not used to prepare an alkylhalide from an alcohol is:

Answer»

HCL + `ZnCl_2`
NACL
`PCl_5`
`SOCl_2`

ANSWER :B