Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Gutta percha is

Answer»

trans-Polyisoprene
A SYNTHETIC POLYMER
A very hard MATERIAL
All STATEMENT are correct

Solution :Property of Gutta percha which is polymer of ISOPRENE .
2.

Gutta -Percha and natural rubber are :

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MADE up of same MONOMER
GEOMETRICAL ISOMERS
1,4-addition POLYMER
all of these

Solution :N//A
3.

Natural rubber is a:

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A TRANS 1,4-polyisoprene polymer
A very HARD meterial
A SYNTHETIC polymer
All of the STATEMENTS are correct

Answer :D
4.

Gutta parcha rubber is :

Answer»

A trans 1,4-polyisoprene polymer
A very hard MATERIAL
A natural polymer
All of these

ANSWER :D
5.

Gun shots are made of lead with a little arsenic. The function of as is to increase:

Answer»

RANGE of fire
Power of fire
Brittleness
Weight of fire

Answer :C
6.

Gun powder is:

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`KNO_3 + CHARCOAL + S`
`NaNO_3 + KNO_3` + S
`NaNO_3` + S
None of these

Answer :A
7.

Gun-cotton is obtained when conc. Nitric acid reacts with

Answer»

GLYCERINE
Glycol
Cellulose
Starch

ANSWER :C
8.

Gun-cotton is

Answer»

Nitrosucrose
NITROCELLULOSE
Nitroglucose
Nitropicrin

Solution :Gun cotton is a nitrocellulose or CELLULOSE trinitrate which is used in explosives and as a BINDER for SOLID rocket propellant.
9.

Gun metal is an alloy of

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Cu and AI
Cu,SN and Zn
Cu,Zn and Ni
Cu and Sn

Answer :B
10.

Gun metal is an alloy of .....

Answer»

Cu and FE
Cu, Sn & Zn
Ni, Fe and Cr
Al and Mg

Solution :Cu, Sn & Zn
11.

Guanidine, (NH_2)_2 C=NH is said to be the strongest nitrogen containing organic base because

Answer»

it has two `NH_2` groups
it has three nitrogen atoms that can be protonated
its amino GROUP is FIRST protonated
its conjugate acid is very MUCH stable due to three EQUIVALENT structures

Solution :
Unusual stability of the conjugate acid of GUANIDINE explains why guanidine is the strongest organic known base.
12.

Gum is

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disaccharide
monosaccharide
polysaccharide
trisaccharide

Answer :C
13.

gt C = O is converted into -CH_(2)- by

Answer»

Clemmenson reduction
`H_(2)//Ni`
Mendius reduction
`NaHg+H_(2)O` reaction .

SOLUTION :`GT C = O + 4H overset(ZnHg + HCl) to gt CH_(2) + H_(2)O`
14.

Gums are :

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POLYSACCHARIDES of more than
ONE TYPE of monosaccharides
USED as THICKENING agent
Used for improvement of texture
in food industry
All

Answer :D
15.

Guanine is held by three hydrogen bonds with the base :

Answer»

Thymine
ADENINE
CYTOSINE
URACIL.

Answer :C
16.

Growing more trees help to :

Answer»

REDUCE OXYGEN in the environment
INCREASE CARBON DIOXIDE only in the environment
Reduce carbon dioxide only in the environment
Reduce `CO_2` and increase `O_2` in the environment

Answer :D
17.

Basic structure of all Chlorophylls comprises

Answer»

`-CH_3,-C_2H_5,-CH=CH_2,-COOCH_3 and -CH_2CH_2COOC_20H_39`
`-CH_3,-C_2H_5, - CH = CH_2, - COCH_3 and -CH_2CH_2COOC_20H_39`
`-CHO, -C_2H_5, -CH = CH_2, -COCH_3 and -CH_2CH_2COOC_20H_39`
`-CHO, -C_2H_5, - CH=CH_2, - COOCH_3 and -CH_2CH_2COOC_20 H_39`

ANSWER :D
18.

Group VIII of Mendeleef's periodic table contains

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6 ELEMENTS
12 elements
3 elements
 9 elements

Answer :D
19.

Group reagent for group-1 basic radicals is

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DIL. HCL
CONC. `H_2 SO_4`
`HNO_3`
`H_2 S`.

ANSWER :A
20.

Group I filtrate is made moderately acidic before proceeding to group II. Expain.

Answer»

Solution :precipitation of the sulphide can occur only when the ionic product `[M^(2+)][S^(2)]` exceeds the solubility product of the sulphides. MS
In the presenc of acid, the ionisation of `H_(2)S` is suppressed due to the INCREASED concentration of `H^(o+)`. As a result, there are only few `S^(2-)` ions in solution which are enough to precipitate only group II cations as sulphides e.g., `Cus,PbS` etc. But for the precipitation of CDS, the concentration of `S^(2-)` is not enough. HENCE the concentration of `(H^(o+))` should be further decreased by diluting the solution so that the `H_(2)S` is ionised extensively As a result `S^(2-)` ions are made available in sufficient quantity which can precipitate thhe `Cd^(2+)` ions i.e., ionic product `[Cd^(2+)][S^(2-)]` exceeds solubility product of CdS.
21.

Group 15 elements are commonly known as.

Answer»

Halogens
Chalcogens
Pnicogens
Normal elements

Answer :C
22.

Group 14 elements have general electronic configuration ________

Answer»

`NS^(2)`
`ns^(2)np^(4)`
`ns^(2)np^(6)`
`ns^(2)np^(2)`

Answer :D
23.

Group 15 elements exhibit + 3 and + 5 oxidation states + 3 oxidation state is more stable than + 5 in case of :

Answer»

N
P
As
Bi

Answer :D
24.

Group 14 elements exhibit +2 and +4 oxidation states. +2 oxidation states is more stable than +4 in case of :

Answer»

C
Pb
Sn
Si.

Solution :Heaviest ELEMENT of the GROUP EXHIBIT lower OXIDATION state.
25.

Group 11 or IB elements are commonly known

Answer»

COINAGE metals
Transition metals
Typical ELEMENTS
REPRESENTATIVE elements

ANSWER :A
26.

Grignared reagent on reaction with ketones forms

Answer»

TERTIARY alcohol
Secondary alcohol
acetic ACID
ACETALDEHYDE

ANSWER :A
27.

Grignards reagent may be obtained by reacting Mg metal with,

Answer»

ACETALDEHYDE
ALKYL HALIDE
ethly AMINE
haloform

Answer :B
28.

Grignard's reagent reacts with ethanal (acetaldehyde) and propanone to give

Answer»

Higher aldehydes with ethanal and higher ketones with propanone
Primary ALCOHOLS with ethanal and secondary alcohols with propanone
Ethers with ethanal and alcohols with propanone
Secondary alcohols with ethanal and tertiary alcohols with propanone

Solution :`CH_(3)-MgBr + CH_(3)-OVERSET(O)overset(||)(C )-H overset(H_(2)O)rarr CH_(3)-underset(" "CH_(3))underset(|)(CH)-OH+MgBr(OH)`
`CH_(3)MgBr + CH_(3)-underset(" "CH_(3))underset(|)(C )=O overset(H_(2)O)rarr`
29.

Grignard's reagent is prepared by the reaction between

Answer»

zinc and alkyl HALIDE
magnesium and alkyl halide
magnesium and ALKANE
magnesium and AROMATIC hydrocarbon

Answer :B
30.

Grignard regentgivesalkanewith :

Answer»

`H_(2)O`
`C_(2) H_(5)OH `
`C_(2) H_(5) NH_(2)`
allof these

ANSWER :D
31.

Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) Grignard reagent can't be prepared from

Answer»




ANSWER :A
32.

Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) The function of tetrahydrofuran in the preparation of Grignard reagent is that it

Answer»

acts as a solvent
helps in MAINTAINING the reaclivity of MAGNESIUM
both
none of the above

Answer :C
33.

Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) H_(2)N(CH_(2))_(3)Br can't be converted into corresponding Grignard reagent because

Answer»

reaction between `-NH_(2)andBr` GROUP present in the same molecule
of STRONG nucleophilic character of the Grignard reagent
of strong BASIC nuture of the Grignard reagent
all of the above

Answer :C
34.

Grignard reagents should be prepared under anhydrous conditions ?

Answer»

Solution :Grignard reagents are very reactive. They react with moisture present in the apparatus or the staring materials, i.e., R - X and MG.
`underset("Grignard reagent ") OVERSET(delta - delta + delta - ) (R - MgX + H ) - OH to R - H + Mg(OH) X `
Therefore, Grignard reagents MUST be prepared under anhydrous conditions.
35.

Grignard reagents (RMgX) are prepared by the reaction of an organic halide and magnesium metal in ether solvent. R-X+Mgoverset(R-O_R)toR-MgX The solvent (usually diethyl ether or tetrahydrofuran) plays a crucial role in the formation of a Grignard reagent. Alkyl halides are more reactive than art and vinyt halides, Indeed, aryl and vinyl halides. Indeed aryl and vinyl chlorides do not form Grignard reagents in dethyf other. However, an att ha de containing an alcoholic - OH group can be converted to Grignard reagent by graf protecting the - OH group to a tert-butytdimethytslyt ether which is not to Grignard reagent. The protecting group is finally liberated by treatment with lotion R-O-H+Cl-underset("Tert-Butylchlorodimethyilance")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-C(CH_(3))_(3)toR-O-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3)overset((C_(4)H_(9))N^(+)F^(-))toR-O-H+F-Si-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C(CH_(3))_(3) Griganrd reactions generally occur in dry ether because

Answer»

the stronger ACID diethly ether will DISPLACE the weaker RH acid from its salt
the stronger acid `H_(2)O` will displace the weaker acid RH from its salt
water slows down the REACTION
water mixes with ether preventing ether to PERFORM its function

Answer :B
36.

Grignard reagents and organolithium compounds on addition to dry ice separately, followed by hydrolysis gives

Answer»

KETONES and carboxylic acids respectively
carboxylic acids and ketones respectively
only carboxylic acids
only ketones

Solution :Grignard reagents (RMgX) react with dry ice followed by hydrolysis gives carboxylic acids.
`R-MgX+O=C=Oto[R-overset(O)overset(||)(C)-OMgX] underset(-Mg(OH)X)overset(H^(+)//H_(2)O)to underset("Carboxylic acids")(R-overset(O)overset(||)(C)-OH)`
Organolithium compounds being more nucleophilic add to C=O of addition product (I) to GIVE addition product (II) which upon SUBSEQUENT hydrolysis gives a ketone.
`R-Li+O=C=Otounderset((I))([R-overset(O)overset(||)(C)-Oli ]) overset(R-Li)to [R-underset(R)underset(|)overset(O" "Li)overset(|)(C)-OLi]overset(H^(+)//H_(2)O)to[R-underset(R)underset(|)overset(OH)overset(|)(C)-OH underset(-H_(2)O)to]underset("Ketone")(R-overset(O)overset(||)(C)-R)`.
37.

Grignard reagents are highly reactive and react with any source of__________to give hydrocarbons.

Answer»


ANSWER :PROTON
38.

Grignard reagents are prepared in

Answer»

Benzene
Chloroform
Alcohol
Ether

Answer :D
39.

Grignard reagent with hydrogen cyanide gives:

Answer»

ALDEHYDE
Ketone
Both (a) and(B)
NONE

ANSWER :A
40.

Grignard reagent undergoes :

Answer»

NUCLEOPHILIC substitution
Nucleophilic addition
BOTH (A) AND (B)
None

Answer :C
41.

Grignard reagent, PhMgBr on treatment with ethylene oxide followed by acid hydrolysis gives

Answer»

`C_6H_5CH_2CH_2OH`
`PhCHOHCH_3`
`C_6H_5CH_2CHO`
`PhCOCH_3`

SOLUTION :
42.

Grignard reagent on reaction with acetone forms

Answer»

TERTIARY alcohol
Secondary alcohol
Acetic acid
Acetaldehyde

Answer :A
43.

Grignard reagent of C_(6)H_(5)Cl can be prepared in THF but not in ether. Explain why?

Answer»

Solution :DUE to +R-effect of Cl, the C-Cl bond has some double bond character and hence little more difficult to break. In other WORDS,ENERGY of activation for cleavage of C-Cl bond is little higher which cannot be supplied by the low boiling point (b.p. 308 K) of ether but can be easily supplied by the little higher b.p. (340 K) of THF.
44.

Grignard reagent on addition with dry ice followed by hydrolysis gives _______.

Answer»

ALDEHYDES and acids
only ketones
aldehydes and ketones
only CARBOXYLIC acids

Answer :D
45.

Grignard reagent is prepared by the reaction between :

Answer»

ZINC and ALKYL halide
Magnesium and alkyl halide
Magnesium and alkane
Magnesium and AROMATIC hydrocarbon

Answer :B
46.

Grignard reagent is not prepared in aqueous medium but it is prepared in ether medium, because.

Answer»

the reagent FORMS complex with water
the reagent BECOMES inactive in water
it is INSOLUBLE in water
the reagent is highly reactive in water.

SOLUTION :
47.

Grignard reagent is not prepared in aqueous medium but prepared in ether mediumbecause the reagent

Answer»

REACTS with water
is insouble in water
is highly reactive in ETHER
becomes INACTIVE in water

Solution :We KNOW that Grignard reagent (R-MgX) react with water. That is why, Grignard REAGNET is not prepared in aqueous medium but prepared in equeous medium but prepared in ether medium
48.

Grignard reagent is not prepared in aqueous medium but prepared in ether medium because the reagent

Answer»

REACTS with water
Is INSOLUBLE in water
Is HIGHLY REACTIVE in ether
Becomes inactive in water

Answer :A
49.

Grignard reagent is not prepared in aqueous medium but prepared in ether medium. Because

Answer»

the reagent reacts with water
the reagent becomes inactive in water
it is insoluble in water
the reagent is highly reactive in water

SOLUTION :Grignard reagent is not prepared in AQUEOUS solution because the reagent produced reacts with the ACTIVE hydrogen of water to yield ALKANE.
50.

Grignard reagent gives carbonyl compounds with

Answer»

ROH
RCOCl
RCN
CO

Answer :C