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Deep blue CuSO_(4).5H_(2)O is converted to a bluish white salt at 100^(@)C. At 250^(@)Cand 750^(@)C it is then transformed to a white powder (X) and black material (Y) respectively. Identify the salts.

Deduce the structures of Ni(CN)_(4)^(2-) and NiCl_(4)^(2-). Write their magnetic moments ?

Deduce the oxidation number of oxygen in hypofluorous acid -HOF.

Deduce the structure of [Nicl_(4)]^(2) and [Ni(Cl_(4)]^(2-) considering the hybridization of the metal. Calculate the magnetic moment (spin only) of the species.

Deduce the shape and magnetic behaviour of the complex ion [Co(NH_(3))_(5)NO_(2)]^(2+).

Deduce the oxidation number of oxygen in hypofluorousacid - HOF.

Deduce the molecular shape of BrF_(3) on the basis of VSEPR theory.

Deduce the identify of the missinig compounds in the following raction sequences. Show stereochemistry in parts (b) through (d).

Deduce from the following E^@values of half cells, what combination of two halt would resutlt in a cell with the largenstpotential : (i) Ararr A^+ +e ,E^@=+1.2V (ii) B^-rarrB+e,E^@=-2.1V (iii) CrarrC^(2+) +2e,E^@=-0.38V(iv)D^(2-) rarrD^- +e,E^@=-0.59V

Deduce from the following E^@values of half cells, what combination of two halt would resutlt in a cell with the largenstpotential : (i) A+e rarr A ,E^@=-0.24V (ii) B^- +e rarrB^(2-),E^@=+1.25V (iii) C^- +2erarrC^(3-),E^@=-1.25V(iv) D + 2e rarrD^(2-), E^@=+ 0.68V

Deduce from the following E^@ values of half cells , what combination of two half cells would result in a cell with largest potential :(i) A^(3-) rarr A^(2-) + e^- , E^@=1.5 V (ii) B^(2+) +e^- rarrB^+ ,E^@ =-2.1V (iii)C^(2+)+e^- rarrC^+,E^@=+0.5V(iv)DrarrD^2 +2e^-,E^@=-1.5V

Decresis order of reducing properties of Ln^(3+)

Decribe the action of the following on chlorobenzene : Acetyl chloride in the presence of anhydrousAlCl_(3)

Decreasing order of size of various hybrid orbitals is : (when principal quantum number 'n' will remains same)

Decreasing order of reducing property of dioxide of 16th group element is

Decreasing order of reducing power hydrogen halides is:

Decreasing order of reactivitytowards nucleophilic addition to carbon yl group among cyclopentanone , 3- pentanone and n- pentanal is

Decreasing order of reactivity in Williamson's ether synthesis of the following is: I. Me_(3)C CH_(2)Br II. CH_(3)CH_(2)CH_(2)Br III. CH_(3)=CHCH_(2)Cl IV. CH_(3)CH_(2)CH_(2)Cl

Decreasing order of reactivity of hydrogen halides towards cleavage of C-O bond in ether is

Decreasing order of reactivity in Williamson's ether synthesis of following :

Decreasing order of oxidising property of tetrapositive lanthanide is

Decreasingorder of nucleophilicity is-

Decreasing order of melting point of compound I-IV follows:

Decreasing order of ionic character of Ln (OH0_(3) is

Decreasing order of intermolecular forces of polymer is (i) Neoprene (ii) silk (iii) Buna-N (iv) melamine formaldehyde resin

Decreasing order of halogen to form oxide is

Decreasing order of calorific value is

Decreasing order of C-C bond length is (I)C_2H_6 (II)C_2H_2 (III)C_6H_6 (IV)C_2H_6

Decreasing order of acidic strengths of following compound is

Decreasing order of boiling points of n-pentanol (A) n-pentane (B), 3-pentanol (C ) and 2,2-dimethyl propanol (D) is :

Decreasing order of boiling points of n-Petanol (A), n-Pentane (B), Pentan-3-ol(C) and 2,2-Dimethylpropanol (D) is ________

Decreasing order of acidity of p-methoxy benzoic acid (A), p-nitrobenzoic acid (B) and benzoic acid (C) is-

Decreasing nucelophilic order of the following is: i. Me_(2)N - Nme_(2), ii. MeNH-NHMe iii. H_(2)N - NH_(2), iv. NH_(3)

Decrease in the pressure for the following equilibria : H_(2)O(s)hArrH_(2)O(l) result in the :

Decrease in vapour pressureof an aqueous solution of an electrolyteis4%. What would be the percentage increasein elevation in boiling point ? ( K_(b) = 0.512 K kg mol^(-1))

Decrease in free energy of a reacting system indicates to:

Decrease in atomic number is observed during

Decrease in atomic number is observed during :

Decomposition of urea into NH_3 and CO_2 is followed by the action of enzyme :

Decomposition of reaction 3A(g) rarr 2B(g) + 2C(s) follows first order kinetics. Starting with pure A(at 6 atm), the pressure developed after 20 minutes and after a long time are 5.05 atm and 4.05 atm, respectively. Identify the correct statement.

Decomposition of Ozone into Oxygen has

Decomposition of oxalic acid I presence of conc.H_(2) SO_(4) gives

Decomposition of NH_(3(g)) on platinum surface at high temperature is a zero order reaction. Explain.

Decomposition of NH_3 on Pt surface follows zero order kinetics. If the initial pressure is 4 atm, the product of t_(1//2)and k equals to

Decompositon of NH_(3) on gold surface follows zero order kinetics. If rate constant is 5xx10^(-4)Ms^(-1), rate of formation of N_(2) will be

Decomposition of M_(2)O_(2) becomes faster in presence of ........

Decomposition of hydrogen peroxide is retarded in the presence of_____.