This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Assertion: The rate of a reaction is normally accelerated by the presence of a catalyst. Reason: The presence of a catalyst makes the value of DeltaG^(@) more negative. |
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Answer» If both assertion and reason are correct EXPLANATION for assertion. |
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| 2. |
Assertion : The rate of reaction is always negative . Reason : Minus sign used in expressing the rate shows that concentration of product is decreasing . |
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Answer» If both assertion and reason are true and the reason is the correct explanation of the assertion |
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| 3. |
Assertion : The radius of the first orbit of hydrogen atom is0.529Å Reason : NF_(3)ionizesto giveF^(-1) ions in aqueoussolution. |
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Answer» Assertionis correct, reason is correct, reason is a correct explanation for ASSERTION. |
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| 4. |
Assertion . The purple colour of KMnO_(4) is due to the charge transfer transition. Reason. The intensecolour of most of the transition metal complexesis due to d-d transition,. |
| Answer» Solution :Correct explanation.The INTENSE colourof `KMnO_(4)` is not DUE to d-d transition but due to charge transferfrom O to M ( Ligand to METAL) REDUCING the oxidation state of Mn from `+7`to `+6 ` temporarily. | |
| 5. |
Assertion :The purple colour of KMnO_4 is due to the charge transfer transition. Reason : The intense colour in most of the transition metal complexes is due to dd transition. |
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Answer» Both Assertion and REASON are TRUE and Reason is the CORRECT explanation of Assertion |
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| 6. |
Assertion : The presence ofnitro group facilitates nucleophilic substiution reactions in aryl halides. Reason : The intermediate carbanion is stabilised due to the presence of nitro group. |
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Answer» if both Assertion and Reason are TRUE andreason is the correct EXPLANATION of the assertion. Because of the positive charge, attack this carbon atom by the nucleophile is fecilitated.
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| 7. |
Assertion: The pressure exerted by the vapour of a liquid at equilibrium at a given temperature is called its vapour pressure. Reason:If a nonvolatile solute is added to a solvent to give a solution, the vapour pressure of the solution is found to be greater than the vapour pressure of the pure solvent. |
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Answer» Both ASSERTION and REASON are true and Reason is the correct explanation of Assertion |
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| 8. |
Assertion: The presence of nitro group facilitates nucleophilic substitution reaction in aryl halides. Reason: The intermediate carbanion is stabilized due to the presence of the nitro group. |
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Answer» If both ASSERTIONN and REASON are TRUE, and reason is the true EXPLANATION of the ASSERTION. |
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| 9. |
Assertion: The presence of a large number of Schottky defects in NaCl lowers its density. Reason: In NaCl, there are approximately 10^(6) Schottky pairs per cm^(3) at room temperature. |
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Answer» If both assertion and reason are true and the reason is the CORRECT explanantion of the assertion |
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| 10. |
Assertion : The pK_(a) of acetic acid is lower than that of phenol. Reason : Phenoxide ion is more resonance stabilized. |
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Answer» If both ASSERTION and REASON are TRUE and reason is the CORRECT EXPLANATION of the assertion |
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| 11. |
Assertion: The pK_(a) of acetic acid is lower than that of phenol. Reason: Phenoxide ion is more resonance stabilized than acetate ion. |
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Answer» if both ASSERTION and reson are true, and reason is the true explanation of the assertion. |
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| 12. |
Assertion : The physical properties of natural rubber can be improved by vulcanisation . Reason : Neoprene is the monomer of natural rubber . |
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Answer» If both assertion and reason are trueand reason is the correct EXPLANATIONOF assertion . |
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| 13. |
Assertion: The packing efficiency is maximum for the fcc structure. Reason: The co-ordination number is 12 in fcc structures. |
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Answer» Assertion and REASON both are correct STATEMENT and reason is correct EXPLANATION for assertion. |
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| 14. |
Assertion (A) : The packing efficiency is maximum for the fcc structure. Reason ( R ) : The co-ordination number is 12 in fcc structure. |
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Answer» Both ASSERTION and REASON are true and reason is the CORRECT EXPLANATION of assertion. |
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| 15. |
Assertion. The order of a reaction can have fractional value. Reason. The order of reaction cannot be written from the balanced equation of the reactant. |
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Answer» If both assertion and reason are true and reason is the true explanation of the assertion. |
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| 16. |
Assertion. The oxidation number of platinum in Zeise's salt is + 4. Reason. Zeise's salt is non-ionic complex. |
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Answer» If both assertion and reason are true, but reason is not the true explanation of the assertion Correct R. Zeise's salt is ionic complex with the formula, `K[PtCl_(3)(C_(2)H_(4))]`. |
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| 17. |
Assertion : The order of reaction can have fractional value. Reason : Order cannot be determined from a stiochiometrically balance equation. |
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Answer» Both ASSERTION and reason are TRUE and reason is the CORRECT EXPLANATION of assertion. |
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| 18. |
Assertion : The order of a reaction can have fractional value . Reason : The order of a reaction cannot be written from balanced equation of a reaction |
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Answer» If both assertion and REASON are true and the reason is the correct explanation of the assertion . |
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| 19. |
Assertion: The number of unpaired electrons present in [CuCl_2]^(-)complex is zero Reason: The complex is linear in the solid state with sp- hybridization |
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Answer» Both ASSERTION & Reason are true ,Reason is the CORRECT explanation of Assertion |
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| 20. |
Assertion. The O-O bond length in H_(2)O_(2) is shorter than that of O_(2)F_(2). Reason. H_(2)O_(2) is an ionic compound. |
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Answer» If both assertion and REASON are true, and reason is the correct explanation of the assertion. Correct reason. The lone pairs of ELECTRONS on the O atoms are strongly attracted by the more electronegative F atoms. As a result, lone-PAIR-lone pair repulsion of the two O atoms in `O_(2)F_(2)` is far less than in `H_(2)O_(2)`. As a result, O-O bond length in `O_(2)F_(2) (1.22 Å)` is much SHORTER than in `H_(2)O_(2) (1.48 Å)`. |
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| 21. |
Assertion: The number of unpaired electrons in Ni(CO)_4 complex is zero. Reason :4s electrons of Ni atom enter the inner d-orbitals to facilitate the sp^3 hybridization in Ni atom. |
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Answer» Both Assertion & REASON are true ,Reason is the correct EXPLANATION of Assertion |
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| 22. |
Assertion : The number of spheres are eual to the number of octahedral voids as well as tetrahedral voids. Reason : octahedral void and tetrahedral void has equal size. |
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Answer» Both assertion and REASON are true and reason is the CORRECT EXPLANATION of assertion. |
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| 23. |
Assertion. The number 14.56pm0.01 has three significant figures. Reason. Number of significant figures is total number of digits except the last digit whose value is uncertain. |
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Answer» If both assertion and reason are true, and reason is the true EXPLANATION of the assertion. Correct R. Number of significant figures is total number of DIGITS including the last digit whose value is uncertain. |
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| 24. |
Assertion. The [Ni(en)_(3)]Cl_(2) (en = ethylenediamine) has lower stability than [Ni(NH_(3))_(6)]Cl_(2). Reason. In [Ni(en)_(3)]Cl_(2), the geometry of Ni is trigonal bipyramidal. |
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Answer» If both assertion and REASON are true, but reason is not the true explanation of the assertion Correct R. `[Ni(en)_(3)]Cl_(2)` has bidentate LIGAND, en, forming CHELATES. |
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| 25. |
Assertion : The neutrons are better initiators of nuclear reactions, than the protons, deutrons or alpha particles of the same energy. Reason :Neutrons are uncharged particles and hence, they are not repelled by positively charged nucleus. |
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Answer» If both ASSERTION and REASON are TRUE and the reason is the correct explanation of the assertion |
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| 26. |
Assertion : The nearly tetrahedral arrangement of the orbitals about the oxygen atoms allows each water molecule to form hydrogen bonds with as many as four neighbouring water molecules. Reason : In ice each water moleculesforms four hydrogen bonds as each molecules is fixed in the space. |
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Answer» If both the assertion and reason are TRUE statement andreason is correct explanation of the assertion . Waterhas highly value for ` EPSI`and thus screens the interactions between ions more effectively . |
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| 27. |
Assertion : The name of the complex [Co(NH_(3))_(6)]Cl_(3) is hexamminecobalt (III) chloride. Reason. When a prefix like hexa ends in 'a' and the ligand like 'ammonia' starts with 'a', only one 'a' is retained. |
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Answer» If both assertion and reason are TRUE, but reason is not the true explanation of the assertion Correct R. When prefix ends in 'a' and LIGAND starts with 'a', both 'a' are retained. |
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| 28. |
Assertion : The monomer of neoprene is 1, 3- butadiene . Reason : Neopren is highly inflammable . |
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Answer» If both ASSERTION and REASON are trueand reason is the correct explanationof assertion . |
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| 29. |
Assertion. The molecularity of the reaction H_(2)+Br_(2) to 2" HBr is "2. Reason. The order of the reaction is 3//2. |
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Answer» If both ASSERTION and REASON are true and reason is the true EXPLANATION of the assertion. |
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| 30. |
Assertion: The molecularity of the reaction H_(2) + Br_(2) rarr 2HBr is 2. Reason: The order of the reaction is 3//2. |
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Answer» If both assertion and reason are true and the reason is the correct EXPLANATION of the assertion. |
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| 31. |
Assertion. The molecular weight of acetic acid determined by depression in freezing point method in benzene and water is found to be different. Reason. Water is polar and benzene is non-polar. |
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Answer» If both assertion and reason are true, and reason is the true EXPLANATION of the assertion. |
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| 32. |
Assertion: The molecular weight of benzoic acid when dissolved in benzene is found to be higher than the theoretically calculated molecular weight from formula. Reason: Many organic solutes when dissolved in non-aqueous solvents undergo dissociation. |
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Answer» Both A and R are true and R is the CORRECT EXPLANATION of A |
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| 33. |
Assertion :- The molarity of a certain solution is always greater than molority. If density of solution is nearly 1gm//ml. Reason :- m=(1000M)/(1000M-MxxM_(solute)) |
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Answer» If both ASSERTION & REASON are TRUE & the Reason is a CORRECT explanation of the Assertion. |
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| 34. |
Assertion : The molar conductance of weak electrolytes at infinite dilution is equal to sum of the molar conductances of cation and anion. Reason : Kohlrausch's law is applicable to both strong and weak electrolytes. |
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Answer» If both assertion and reason are correct and reason is correct EXPLANATION for assertion. |
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| 35. |
Assertion. The micelle formed by sodium stearte inn water has -COO^(-) groups at the surface. Reason. Surface tension of water is reduced by addition of stearate. |
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Answer» If both ASSERTION and REASON are ture, and reason is the trure explanation of the assertion. |
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| 36. |
Assertion : The molality of the solution does not change with change in tempc- nature. : The molality is expressed in units of moles per 1000 g of solvent. Reason |
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Answer» Both A and R are true and R is the correct explanation of A |
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| 37. |
Assertion : The major products formed by heating C_6H_5CH_2-OCH_3 with conc. HI are C_6H_5CH_2I and CH_3OH. Reason : Benzyl cation is more stable than methyl cation. |
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Answer» BOTHA and B are true and R is the correct EXPLANATION of A. This is because `C_6H_5overset(+)CH_2` carbocation is MUCH more stable than `overset(+)CH_3` |
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| 38. |
Assertion: The ligands nitro and nitrito are called ambidentate ligands Reason:Nitro and nitrite ligands give linkage isomers. |
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Answer» Both Assertion & Reason are TRUE ,Reason is the CORRECT explanation of Assertion |
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| 39. |
Assertion : The IUPAC name of the complex compound [Co(H_2O)_4Cl_2]Cl. 2H_2Ois tetra aquadichlorocobalt (III) chloride. Reason:Tetrahedral complexes exhibit geometrical isomerism. |
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Answer» Both ASSERTION & Reason are true ,Reason is the correct explanation of Assertion |
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| 40. |
Assertion : The kinetics of the reaction - mA + nB + pC rarr m'X + n'Y + p'Z obeys the rate expression as - (dx)/(dt) = k[A]^(m) [B]^(n) Reason : The rate of reaction does not depend upon the concentration of C. |
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Answer» If both assertion and reason are true and reason is the correct explanation of assertion |
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| 41. |
Assertion : The K_(a) value of alpha-amino acids is very low. Reason : alpha-Amino acids have zwitterionic structure. |
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Answer» If both ASSERTION and reason are correct and reason is correct explanation for assertion. |
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| 42. |
Assertion. The hydrolysis of methyl acetate by dilute HCl is a pseudo first order reaction. Reason. HCl acts as a catalyst for the hydrolysis. |
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Answer» If both assertion and REASON are true and reason is the true EXPLANATION of the assertion. |
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| 43. |
Assertion : The highest oxidation state of osmium is +8. Reason : Osmiumis a 5d -block element. |
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Answer» Both assertion and REASON are true and reason is the correct explanation of the assertion . |
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| 44. |
Assertion : The hydrolysis of methyl acetate by dil. HCl is a pseudo first order reaction Reason : HCl acts as a catalyst for the hydrolysis . |
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Answer» If both assertion and reason are true and the reason is the CORRECT explanation of the assertion . |
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| 45. |
Assertion : The HF_(2)^(-) ion exists in the solid state & also in liquid state but not in aqueous state. Reason : The magniture of hydrogen bonds among HF molecules is weaker than that in between HF and H_(2)O. |
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Answer» If assertion is true but the REASON is FALSE |
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| 46. |
Assertion. The HF_(2)^(-) ion exists in the solid state and also in liquid state but not in aqueous solution. Reason. The magnitude of hydrogen bonds in between HF-HF molecule is weaker than that in between HF and H_(2)O molecules. |
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Answer» If both assertion and REASON are true, and reason is the CORRECT explanation of the assertion. |
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| 47. |
Assertion : The H-bond present in NH_(3) dissolved in water is best represented by : H-underset(|)underset(H)(N)-H--underset(|)underset(H)(O)-H and not by H-underset(|)underset(H)overset(|)overset(H)(N)---underset(|)underset(H)(H)-O Reason : The O-H bond polarity is more compared to that N-H bond. |
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Answer» If ASSERTION is true but the reason is FALSE `NH_(3)+H_(2)O to NH_(2)^(-)+H_(3)O^(+)` |
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| 48. |
Assertion: The geometrical isomers of the complex [M(NH_3)_4Cl_2] are optically inactive Reason: Both geometrical isomers of the complex [M(NH_3)_4Cl_2] possess axis of symmetry |
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Answer» Both ASSERTION & Reason are true ,Reason is the CORRECT explanation of Assertion |
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| 49. |
Assertion :- The freezing point is the temperature at which solid crystallizzes from solution. Reason :- The freezing point depression is the difference between that temperature and freezing point of pure solvent. |
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Answer» If both ASSERTION and reason are true and the reason is the CORRECT EXPLANATION of the assertion. |
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| 50. |
Assertion: The formation of F_((g))^(-) from F_((g)) is exothermic, whereas that of O_((g))^(2-) from O_((g)) is endotherrmic. Reason: The addition of second electron to a monovalent anion is difficult because both have the same charge and experience more repulsion. |
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Answer» If both ASSERTION and REASON are TRUE ANND the reason is the correct EXPLANATION of assertion |
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