1.

Write formal charges of the atoms in the nitrite ion.

Answer»

charge is by definition a formalism; it has no physical reality, but may nevertheless be USEFUL for calculation.We can write the Lewis representation of the NITRATE anion as, (O=)N+(−O−)2. The nitrogen centre is quaternized, and bears a positive charge. Why? Because it has a share in 4 bonding electrons: 2 from the the doubly bound oxygen, and 1 each from the 2 N−O bonds. So with the 2 inner core electrons, the nitrogen centre is associated with 6 electrons ONLY rather than the 7 it requires for electrical neutrality. The nitrogen centre THUS bears a positive charge.Compare this with ammonia, a neutral molecule. We write :NH3. The nitrogen centre OWNS (or has a share in) 5 electrons (2 from the lone pair are entirely associated with the nitrogen; and 3 electrons from the N−H bonds). Ammonia is rightly depicted as a neutral atom with no formal charges.So back to nitrate: nitrogen has dibs on only 6 electrons, and therefore bears a formal positive charge. The doubly bound oxygen has a share in or owns 8 electrons, and so is depicted as neutral. The SINGLY bound oxygen atoms have 9 electrons associated with them, and so each bears a negative charge. The overall charge on the nitrate ion is of course −1, which this representation is designed to suggest. Can you treat the sulfate anion, SO2−4 in the same way? Where does the formal charge lie?



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