1.

Write a note on homologous series.

Answer»

Homologous series:

  • A series of compounds of the same family in which each member has the same type of carbon skeleton and functional group, and differs from the next member by a constant difference of one methylene group (-CH2 -) in its molecular and structural formula is called as homologous series.
  • The individual members of the series are called homologues and they can be represented by a same general formula.
  • Two successive homologues differ by one – CH2 (methylene) unit (i.e., molecular weight of each successive member differs by 14 units).
  • Homologues show similar chemical properties.
  • Physical properties (like melting point, boiling point, density, solubility, etc.) of the homologues show a gradual change with increase in the molecular weight of the member.

Note: Consider the homologous series of straight chain aldehydes. The boiling point increases down the series as molecular weight increases.

NameMolecular formulaBoiling point
FormaldehydeHCHO-21 °C
AcetaldehydeCH3CHO21 °C
PropionaldehydeC2H5CHO48 °C
ButyraldehydeC3H7CHO75 °C
ValeraldehydeC4H9CHO103 °C



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