1.

Work out the following empirical formulas using the values from the table(a)The smell of a pineapple is caused by ethyl butanoate. A sample is known to containonly 0.180 g of carbon, 0.030 g of hydrogen and 0.080 g of oxygen. What is theempirical formula of ethyl butanoate? (b)A 300 g sample is known to contain only carbon, hydrogen and oxygen. Thepercentage of carbon is found to be exactly the same as the percentage of oxygen.The percentage of hydrogen is known to be 5.99%. What is the empirical formula ofthe compound?c)All compositions are by mass. 29.4% Vanadium, 9.2% Oxygen, 61.4% Chlorine.

Answer»

Answer:

a) C3H6O   B) C4H6O3   c) VOCl3

Explanation:

a)   Carbon.                 Hydrogen               Oxygen

     0.180/12.0               0.030/1.0               0.080/16.0              

     = 0.015                    =0.030                   =0.005

     = 0.015/0.005          =0.030/0.005        =0.005/0.005

     = 3                            =6                           = 1

Therefore, the empirical formula is C3H6O

b) Hydrogen= 17.97g

   Oxygen= Carbon= (300-17.97)/2= 141.01g  

   Carbon.                 Hydrogen               Oxygen

     141.0/12.0               17.97/1.0               141.0/16.0              

     = 11.75                    =17.97                    =8.81

     =11.75/8.81              =17.97/8.81           =8.81/8.81

     = 1.33 X3                  =2.03  X 3           = 1

    = 4.                           =6.                        =3

Therefore, the empirical formula is C4H6O3

C) Hydrogen= 17.97g

   Oxygen= Carbon= (300-17.97)/2= 141.01g  

    VANADIUM                 Oxygen            Chlorine

     29.4/50.9               9.2/16.0               61.4/35.5              

     = 0.58                    =0.58                    =1.73

     =0.58/0.58            =0.58/0.58           =1.73/0.58

     = 1                           =1                          = 2.98 -> 3

    Therefore, the empirical formula is VOCl3



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