| 1. |
Which one of the following are correctly arranged on the basis of the property indicated:(a) I2 < Br2 < F2 < Cl2 [increasing bond dissociation enthalpy](b) H2O > H2S < H2Te < H2Se [increasing acidic strength](c) NH3 < N2O < NH2OH < N2O5 [increasing oxidation state](d) BiH3 < SbH3 < AsH3 < PH3 < NH3 [increasing bondangle] |
|
Answer» Answer is (d) BiH3 < SbH3 < AsH3 < PH3 < NH3 [ increasing bond angle] (a) I2 < Br2 > F2 > CI2. [ increasing bond dissociation enthalpy]: incorrect order , correct order is Cl2 > Br2 > F2 > I2. (b) H2O > H2S < H2Te < H2Se [ increasing acidic strength]: incorrect order , correct order is H2O < H2S < H2Se < H2Te (c) NH3 < N2O < NH2OH < N2O5 [ increasing oxidation state ] : incorrect order NH3 (Oxidation state -3) N2O (Oxidation state +1) NH2OH(Oxidation state -1) N2O5 (Oxidation state +5) Correct answer is (d) BiH3<SbH3<AsH3<PH3 <NH3 [ increasing bond angle due to leaving ammonia other are drago molecules which donot show hybridization and thus from bond angle close to 90°]- correct order. |
|