1.

Which of the following on heating with aqueous KOH, produces acetaldehyde: A. CH3CH2Cl B. CH2Cl.CH2Cl C. CH3CHCl2 (Correct Answer) D. CH3COCl give reason n reaction pl

Answer»

cThe geminal dihalides are boiled with AQUEOUS KOH or NaOH. It produces aldehydes and ketones. geminal dihalide (R-CHX2) having two halogen atoms situated on terminal carbon ATOM, are hydrolysed by aq. KOH or aq. NaOH FIRST produced a unstable dihydroxy compound. Then converts into an aldehyde by loss of water molecule. 1-1- dichloroethane is GERMINAL dihalide which REACT with KOH and produce unstable hydroxyl compound then loss of water molecule acetaldehyde produce See the attachment for reaction.



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