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Which of the following equations are satisfied at azeotropic conditions?(a) A^v(v) + A^l(v) = 0(b) A^v(v) – A^l(v) = 0(c) A^v(v). A^l(v) = 0(d) A^v(v) =A^l(v)The question was posed to me during a job interview.The query is from Extractive Distillation in portion Azeotropic and Extractive Distillation of Distillation Design

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Correct ANSWER is (b) A^v(v) – A^l(v) = 0

For EXPLANATION: A^v(v) and A^l(v) are the Helmholtz energy of the vapor and LIQUID PHASES respectively, V, V^0 and V^l are the total molar volume.



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