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What happens when thin copper leaves are thrown in jar containing chlorine? H2O is liquid while H2S is gas at room temperature. Explain. The conductivity of 0.02 M AgNO3 at 25°C is 2.428 x 10–3 Ω–1 cm–1. What is its molar conductivity? State Henry’s law.

Answer»

a. When thin copper leaves are thrown in a jar of chlorine they catch fire and form cupric chloride.

Cu (Copper) + Cl(Chlorine) → CuCl(Cupric chloride)

b. 1. Due to greater electronegativity of O than S, H2O undergoes extensive intermolecular H-bonding. As a result, H2O exists as an associated molecule in which each O is tetrahedrally surrounded by four water molecules. Large amount of energy is required to break these H-bonds. Therefore, H2O is a liquid at room temperature. 

2. In contrast, H2S does not undergo H-bonding. It exists as discrete molecules which are held together by weak van der Waals forces of attraction. To break these forces of attraction, only a small amount of energy is required. Therefore, H2S is a gas at room temperature.

c. Given: C = 0.02 M , k = 2.428 x 10-3  Ω-1 cm-1 

To find: Molar conductivity 

Formula: Molar conductivity = \(\frac{1000k}{C}\) 

Calculation: Molar conductivity = \(\frac{1000k}{C}\)\(\frac{1000\times2.428\times10^{-3}}{0.02}\)

= 121.4 Ω-1 cm2 mol-1

d. Henry’s law relates solubility of a gas with external pressure. The law states that, “the solubility of a gas in liquid at constant temperature is proportional to the pressure of the gas above the solution”.



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