1.

Urgentif 1.0 Kcal of heat is added to 1.2 L of O2 in a cylinder of constant pressure of 1 atm ,the volume increases to 1.5 L. calculate delta U delta H of the process.

Answer»

\Delta U=992.737cal\Delta H=1000calAnswer : and

Solution : Given,

Heat = 1 Kcal = 1000 CAL       (1 Kcal = 1000 cal)

Initial volume = 1.2 L

Final volume = 1.5 L

Pressure = 1 atm

Formula used :

\Delta U=q-w\\\Delta U=q-P\Delta V\\\Delta U=q-P(V_{final}-V_{initial})

Now PUT all the given VALUES in this formula, we get

\Delta U=1000cal-[1atm\times (1.5L-1.2L)]\times 24.21=992.737cal   (1Latm=24.21cal)

\Delta HNow we have to CALCULATE the .

At constant pressure, \Delta H=q_p

So, \Delta H=q_p=1000cal

\Delta U=992.737cal\Delta H=1000calTHEREFORE, and



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