1.

The reaction of `P_(4)` with X leads selectively to `P_(4)O_(6)` The X is :A. Dry `O_(2)`B. A mixture of `O_(2)` and `N_(2)`C. Moist `O_(2)`D. `O_(2)` in the presence of aqueous NaOH

Answer» Correct Answer - B
`P_(4)+3O_(2)overset`("In presence of"`N_(2))toP_(4)O_(6)`. "Here nitrogen acts as diluent".
Note:
"In dry" `O_(2)` "followintg reactions may take place".
`P_(4)+3O_(2)to P_(4)O_(6)`.
`P_(4)O_(6)to P_(4)2O_(2)to P_(4)O_(10)`.
"In moist" `O_(2)` the `P_(4)O_(6)` "gets hydrolysed forming" `H_(3)PO_(3)`.
`P_(4)O_(6)to 4H_(3)PO_(3)`.
"In presence of NaOH".
`P_(4)+3OH^(-)+3H_(2)O to PH_(3)+3H_(2)PO_(2)^(-)`


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