1.

The rate of first order reaction is 1.5*10^-2 molL-1/min-1 at 0.5 m .concentration of the reactant .the half life of the reaction is

Answer»

Answer : The half life of the reaction is, 23.1 minutes.

Solution : GIVEN,

RATE of first ORDER reaction = 1.5\times 10^{-2}molL^{-1}min^{-1}

Concentration of reactant = 0.5 m = 0.5 mole/L

  • For first order reaction,

A\rightarrow Product

The expression for rate of reaction is,

r=K[A]\\K=\frac{r}{[A]}

Now put all the given values in this formula, we get the value for rate constant.

K=\frac{1.5\times 10^{-2}mol L^{-1} min^{-1}}{0.5mole/L}=3\times 10^{-2}min^{-1}

The formula for half life for first order reaction is,

t_{1/2}=\frac{0.693}{K}

Now put the value of K, we get the value of half life.

t_{1/2}=\frac{0.693}{3\times 10^{-2}min^{-1}}=23.1min

Therefore, the half life of the reaction is, 23.1 minutes.



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