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The freezing point of an aqueous solution of KCN containing 0.175molkg−1Kf was −0.7oCH2O=2kgmol−1K. On adding 0.095 mol of M(CN)2, the freezing point of the solution was –0.570C. Take the cryoscopic constant for water to be equal to 2 with the usual units. If the complex formation takes place according to the equation, M(CN)2+mKCN⇌Km[M(CN)m+2] what is the value of m (integral value) in the formula of the complex?

Answer» The freezing point of an aqueous solution of KCN containing 0.175molkg1Kf was 0.7oCH2O=2kgmol1K. On adding 0.095 mol of M(CN)2, the freezing point of the solution was 0.570C. Take the cryoscopic constant for water to be equal to 2 with the usual units. If the complex formation takes place according to the equation, M(CN)2+mKCNKm[M(CN)m+2] what is the value of m (integral value) in the formula of the complex?


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