1.

The equilibrium constant for the following reactions are K1 and K2, respectively. 2P(g) + 3Cl2(g) ⇋ 2PCl3(g) PCl3(g) + Cl2(g) ⇋ PCl5(g) Then the equilibrium constant for the reaction 2P(g) + 5Cl2(g) ⇋ 2PCl5(g) is –(A) K1K2 (B) K1K22  (C) K12 K22  (D) K12 K2

Answer»

Correct :- (B) K1K22

Explanation :-

2P(g) + 3Cl2(g) 2PCl3(g) K1 

 2PCl3(g) + 2Cl2(g) 2PCl5(g) K2

 Net reaction : 2P(g) + 5Cl2(g) 2PCl5(g) K = K1K22



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