1.

The electronic spectrum of [Ti(H2O)6 ]3+ shows a single broad peak with a maximum at 20,300 cm–1. The crystal field stabilization energy (CFSE) of the complex ion, in kJ mol–1, is : (1) 242.5 (2) 83.7 (3) 145.5 (4) 97

Answer»

(4) 97

CFSE = 0.4 Δ0 

= 0.4 × 20300 / 83.7 

= 97 kJ/mol 



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