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The correct order of basictiies of the following compounds is : . 3. (CH_(3))_(2)NH. 4. CH_(3)-overset(O)overset(||)(C)-NH_(2) |
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Answer» `(2) GT (1) gt (3) gt (4)` 1.` (##KSV_CHM_ORG_P2_C15_E01_152_S01.png" width="80%"> LTBRGT More basci due to the presence of two ` LP overlinee^, s` on each (N). 2.` EtNH_2`, Due to `+I` effect of (Et) group , but `+ I` effect to two Me groups is greater than `+I` effect of `(Et)` group. Hence (3) is more basic than (2). 3.`(CH_3)_2 NH`. Due to `(+I)` effect of two Me groups. 4.` (##KSV_CHM_ORG_P2_C15_E01_152_S02.png" width="80%"> (Amides are resonance STABILISED , so they are the weakest base , Amides behalve as amphoteric ). |
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