1.

The compound (X) with M.F. C_(4)H_(11)N on treatment with HNO_(2) gives a tertiary alcohol with M.F.C_(4)H_(10)O. The compound (X) will give

Answer»

CARBYLAMINE reaction
Hofmann mustard oil reaction
Diazonium salt as intermediate with `HNO_(2)`
GIVES 2-methyl-2-nitropropane on oxidation with `KMnO_(4)`

Solution :Since the COMPOUND (X) with M.F. `C_(6)H_(11)N` on treatment with `HNO_(2)`. Give a tertiary alcohol, therefore, (X) must be a `1^(@)` amine andas such it must give carbylamine reaction. Hofmann mustard oil reaction underoges oxlation with `KMnO_(4)` to give 2-methyl-2-nitropropane and must form diazonium salt as an unstable intermediate during its reaction with `HNO_(2)`. Thus, all statements are correct.


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