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The central metal ion in the complex makes available a number of empty orbitals for the formation of co-ordinate bonds with suitable ligands. The inner d-orbitals or outer d-orbitals are involved. The empty hybrid orbitals of metal ion overlap with the filled orbitals of ligand to from metal ligand co-ordinate bonds. For co-ordination number 6 octahedral geometry and sp^(3),d^(2)ord^(2)sp^(2) hybridisation involved and for cordiantion number 4 tetrahedral geometry, square planar geometry and sp^(3).dsp^(2) hybridisation involved. Type of complex formed in [Fe(H_(2)O)_(6)]^(+3) ion |
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Answer» inner orbital complex `H_(2)O` s a WEAK field lignad, So no regrouping of electrons. Outer orbitals participate in `SP^(3)d^(2)` hybridization. |
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