The bromination of acetone that occurs in acid solution is represented by CH_(3)COCH_(3)(aq.)+Br_(2)(aq.)to CH_(3)COCH_(2)Br(aq.)+H^(+)(aq.)+Br^(-)(aq.) These kinetic data were obtained for given reaction concentration Initial concentration {:("Initial concentration",,,"Initial rate of"),(,,,"disappearance"),([CH_(3)COCH_(3)],[Br_(2)],[H^(+)],"of "Br_(2)),(0.30,0.05,0.05,5.0xx10^(-5)),(0.30,0.10,0.5,5.0xx10^(-5)),(0.30,0.10,0.10,1.0xx10^(-4)),(0.90,0.05,0.10,3.0xx10^(-4)):} Based on these data, order of reaction will be -

The bromination of acetone that occurs in acid solution is represented

1.	The bromination of acetone that occurs in acid solution is represented by CH_(3)COCH_(3)(aq.)+Br_(2)(aq.)to CH_(3)COCH_(2)Br(aq.)+H^(+)(aq.)+Br^(-)(aq.) These kinetic data were obtained for given reaction concentration Initial concentration {:("Initial concentration",,,"Initial rate of"),(,,,"disappearance"),([CH_(3)COCH_(3)],[Br_(2)],[H^(+)],"of "Br_(2)),(0.30,0.05,0.05,5.0xx10^(-5)),(0.30,0.10,0.5,5.0xx10^(-5)),(0.30,0.10,0.10,1.0xx10^(-4)),(0.90,0.05,0.10,3.0xx10^(-4)):} Based on these data, order of reaction will be -
Answer» Solution :From (1) and (2), `[CH_(3)COCH_(3)]` and `[H^(+)]` = constant `[Br_(2)]` = doubled RATE = UNCHANGED `therefore` Order w.r.t `Br_(2) = 0` POSSIBLE rate LAW (By option) `r = k [CH_(3)COCH_(3)][H^(+)]`