1.

State the basic assumptions of the kinetic theory of gases.

Answer»

The basic assumptions of the kinetic theory of an ideal gas :

1. A gas of a pure material consists of an extremely large number of identical molecules. 

2. A gas molecule behaves as an ideal particle, i.e., it has mass but its structure and size can be ignored as compared with the intermolecular separation in a dilute gas and the dimensions of the container. 

3. The molecules are in constant random motion with various velocities and obey Newton’s laws of motion. 

4. Intermolecular forces can be ignored on the average so that the only forces between the molecules and the walls of the container are contact forces during collisions. It follows that between successive collisions, a gas molecule travels in a straight line with constant speed.

5. The collisions are perfectly elastic conserving total momentum and kinetic energy, and the duration of a collision is very small compared to the time interval between successive collisions.

Notes :

(1) The walls of the container holding the gas are assumed to be rigid and infinitely massive so that they do not move. 

(2) Assumption (2) allows us to ignore intermolecular collisions because if they are truly point like (i.e., of negligible extent) they cannot make contact with each other. Therefore, the only collisions we consider are those with the walls of the container. If these collisions are perfectly elastic [by assumption (5)], they only change the direction of the velocity of a gas molecule and a gas molecule possesses only kinetic energy by assumption

(4). The kinetic theory of gases was developed by Daniel Bernoulli (1700 – 82), Swiss mathematician, Rudolf Clausius (1822 – 88), German theoretical physicist, James Clerk Maxwell (1831-79), British physicist, Ludwig Eduard Boltzmann, Josiah Willard Gibbs (1839-1903), US physical chemist.]



Discussion

No Comment Found