1.

O-nitrophenol has _________ melting point than /j-nitrophenol.

Answer»

Explanation:            In p-nitrophenol, MOLECULAR association takes PLACE due to extensive hydrogen bonding between the molecules (intermolecular hydrogen bonding). Therefore, it has higher MELTING and boiling points. In o-nitrophenol, since the OH and NO2 are in close proximity to each other, intramolecular hydrogen bonding takes place.



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