1.

Match the colour of precipitate listed in column-I with the reagent(s) listed in column II. `{:(Column-I,Column-II),((A)Bi^(3+)"gives black precipitate with",(p)"Saturated solution of" H_2S "in water"),((B)Cu^(2+)"gives black precipitate with",(q)"Potassium thiocyanate soluion"),((C )Zn^(2+)"gives white precipitate with",(r)"Potassium iodide solution"),((D)Ag^+"gives white precipitate with",(s)"Potassium ferrocyanide solution"),(,(t)"Potassium chloride"):}`

Answer» Correct Answer - A`to`p,r ; B`to`p,q ; C`to`p,s ; D`to`q,s,t
(A)`2Bi^(3+)+3H_2StoBi_2S_3darr(black)+6H^(+)`
`Bi^(3+)to3I^(-)toBiI_3darr` (black)
(B)`Cu^(2+)+H_2StoCuSdarr(black)+2H^(+)`
`Cu^(2+)+2SCN^(-)toCu(SCN)_2darr`(black)
which one standing slowly changes to white
`2Cu(SCN)_2to2Cu(SCN)darr(white)+(SCN)_2`
`Cu_2I_2` is white precipitate and `Cu_2[Fe(CN)_6]` brown precipitate
(C )`Zn^(2+)+H_2StoZnSdarr(white)+2H^+`
`2K^(+)+2Fe(CN)_6]^(4-)+3Zn^(2+)toK_2Zn_3[Fe(CN)_6]_2darr`(white)
`ZnI_2to`soluble
(D)`4Ag^(+)+[Fe(CN)_6]^(4-)toAg_4[Fe(CN)_6]darr`(white)
`Ag^(+)+SCN^(-)toAgSCNdarr`(white)
`Ag_2Sdarr` black , `AgIdarr` yellow


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